Automated Time Series Measurement of Microbial Concentrations in Groundwater-Derived Water Supplies     

David W. Owens  Randall J. Hunt  Aaron D. Firnstahl  Maureen A. Muldoon  Mark A. Borchardt 《Ground water》2019,57(2):329-336

Fecal contamination by human and animal pathogens, including viruses, bacteria, and protozoa, is a potential human health hazard, especially with regards to drinking water. Pathogen occurrence in groundwater varies considerably in space and time, which can be difficult to characterize as sampling typically requires hundreds of liters of water to be passed through a filter. Here we describe the design and deployment of an automated sampler suited for hydrogeologically and chemically dynamic groundwater systems. Our design focused on a compact form to facilitate transport and quick deployment to municipal and domestic water supplies. We deployed a sampler to characterize water quality from a household well tapping a shallow fractured dolomite aquifer in northeast Wisconsin. The sampler was deployed from January to April 2017, and monitored temperature, nitrate, chloride, specific conductance, and fluorescent dissolved organic matter on a minute time step; water was directed to sequential microbial filters during three recharge periods that ranged from 5 to 20 days. Results from the automated sampler demonstrate the dynamic nature of the household water quality, especially with regard to microbial targets, which were shown to vary 1 to 2 orders of magnitude during a single sampling event. We believe assessments of pathogen occurrence and concentration, and related assessments of drinking well vulnerability, would be improved by the time-integrated characterization provided by this sampler.  相似文献   

Development of cloud detection methods using CFH,GTS1, and RS80 radiosondes   总被引：1，自引：0，他引：1  

张金强  陈洪滨  卞建春  宣越健  段云俊 《大气科学进展》2012,29(2):236-248

The accuracies of three instruments in measuring atmospheric column humidity were assessed during an upper troposphere and lower stratosphere observation campaign conducted from 7 to 13 August 2009 in ...  相似文献   

A lithium isotopic study of sub-greenschist to greenschist facies metamorphism in an accretionary prism,New Zealand     

Lin Qiu  Roberta L. Rudnick  Jay J. Ague  William F. McDonough 《Earth and Planetary Science Letters》2011,301(1-2):213-221

To investigate the behavior of Li during low-grade metamorphism and fluid flux in an accretionary prism we measured the Li concentrations ([Li]) and isotopic compositions (δ⁷Li) of sub-greenschist and greenschist-facies Otago Schist composites, as well as cross-cutting quartz veins, which are interpreted to have precipitated from slab-derived fluids. The average [Li] of sub-greenschist facies composites (41 ± 13 μg/g, 2σ) is statistically distinct (97% confidence level, student t test) to that of greenschist facies composites (34 ± 9 μg/g, 2σ), which have experienced mass addition of silica in the form of quartz veins having [Li] between 0.4–2.3 μg/g. A linear regression of the correlation between [Li] and calculated mass additions suggests that the depletion of [Li] in greenschist facies composites is due to both dilution from the addition of the quartz veins, as well as metamorphic dehydration. The [Li] of both groups of composites correlates with their CIA (Chemical Index of Alteration) values (50–58), which are low, consistent with the inferred graywacke protolith of the Otago Schist. The δ⁷Li of sub-greenschist and greenschist facies composites are remarkably constant, with an average δ⁷Li of 0.2 ± 1.7 (2σ) and ?0.5 ± 1.9 (2σ), respectively, and comparable to that of the average upper continental crust. Thus, metamorphism has had no discernable effect on δ⁷Li in these samples. The Li isotopic signature of the schists is similar to that seen in pelitic sedimentary rocks and likely reflects the δ⁷Li of the protoliths. The surprisingly light δ⁷Li of the quartz veins (?2.8 to ?1.4) likely records kinetic fractionation associated with Li ingress into the veins from surrounding wallrock.An isotopic equilibrium fluid flow model indicates that: 1) if the [Li] of slab-derived fluids is less than a few μg/g, the δ⁷Li of the overlying lithologies (i.e., the schists) is not significantly influenced by the fluid flux, regardless of the δ⁷Li of the fluids, 2) the slab-derived fluids will have heavy δ⁷Li of > + 10 after reacting with the prism sediments during their ascent, and 3) the [Li] of the slab-derived fluids is likely in the range of 0 < [Li] ≤ 41(μg/g). Thus, isotopically heavy slab-derived fluids that traverse sediments in accretionary prisms may leave little trace in the rocks and their surface compositional characteristics will reflect the net result of their interaction with the sediments of the prism.  相似文献   

Mineral–fluid partitioning of lithium and implications for slab–mantle interaction     

N. Caciagli  J.M. Brenan  W.F. McDonough  D. Phinney 《Chemical Geology》2011,280(3-4):384-398

  相似文献   

Editorial     

Phil Potts  Michel Grégoire  Bill McDonough  Thomas Meisel  Jon Woodhead 《Geostandards and Geoanalytical Research》2011,35(1):5-5

  相似文献   

Damming Knowledge Flows: POWER as a Constraint on Knowledge Pluralism in River Flow Decision-making in the Saskatchewan River Delta     

Evan J. Andrews  Maureen G. Reed  Timothy D. Jardine  Toddi A. Steelman 《社会与自然资源》2018,31(8):892-907

Rivers and dams are increasingly contested venues where knowledge pluralism is critical for effective governance. To navigate change, decision-makers can adopt culturally-sensitive interventions to address the needs of diverse stakeholders and rights holders. Calls for Indigenous flows have become important as dam operators seek to renew their legal and social licenses to operate. Knowledge pluralism is needed to enhance decision-making about flows that better address complexity and change to Indigenous livelihoods and cultural practices. However, leveraging diverse knowledge types to inform these interventions is not simply a matter of changing management practice. Power relations can constrain knowledge pluralism. We contribute an empirical example that links power in a decision-making process about a dam in Saskatchewan, Canada, to the losses experienced by downstream Indigenous communities. This paper operationalizes power to illustrate its methodological utility and documents the interconnected losses, experienced by resources users, resultant from the marginalization of Indigenous knowledge.  相似文献   

Aerosol Optical Properties and Radiative Impacts in the Pearl River Delta Region of China during the Dry Season     

Boru MAI  Xuejiao DENG  Zhanqing LI  Jianjun LIU  Xiang'ao XIA  Huizheng CHE  Xia LIU  Fei LI  Yu ZOU  Maureen CRIBB 《大气科学进展》2018,35(2):195-208

Aerosol optical properties and direct radiative effects on surface irradiance were examined using seven years(2006–2012)of Cimel sunphotometer data collected at Panyu—the main atmospheric composition monitoring station in the Pearl River Delta(PRD) region of China. During the dry season(October to February), mean values of the aerosol optical depth(AOD)at 550 nm, the ?ngstr?m exponent, and the single scattering albedo at 440 nm(SSA) were 0.54, 1.33 and 0.87, respectively.About 90% of aerosols were dominated by fine-mode strongly absorbing particles. The size distribution was bimodal, with fine-mode particles dominating. The fine mode showed a peak at a radius of 0.12 μm in February and October(~0.10μm~3μm~(-2)). The mean diurnal shortwave direct radiative forcing at the surface, inside the atmosphere(FATM), and at the top of the atmosphere, was-33.4 ± 7.0, 26.1 ± 5.6 and-7.3 ± 2.7 W m~(-2), respectively. The corresponding mean values of aerosol direct shortwave radiative forcing per AOD were-60.0 ± 7.8, 47.3 ± 8.3 and-12.8 ± 3.1 W m~(-2), respectively. Moreover,during the study period, FATMshowed a significant decreasing trend(p 0.01) and SSA increased from 0.87 in 2006 to 0.91 in 2012, suggesting a decreasing trend of absorbing particles being released into the atmosphere. Optical properties and radiative impacts of the absorbing particles can be used to improve the accuracy of inversion algorithms for satellite-based aerosol retrievals in the PRD region and to better constrain the climate effect of aerosols in climate models.  相似文献   

Modeling fractional crystallization of group IVB iron meteorites     

Richard J. Walker  William F. McDonough  Nancy L. Chabot  Richard D. Ash 《Geochimica et cosmochimica acta》2008,72(8):2198-2216

A ¹⁸⁷Re-¹⁸⁷Os isochron including data for all twelve IVB irons gives an age of 4579 ± 34 Ma with an initial ¹⁸⁷Os/¹⁸⁸Os of 0.09531 ± 0.00022, consistent with early solar system crystallization. This result, along with the chemical systematics of the highly siderophile elements (HSE) are indicative of closed-system behavior for all of the HSE in the IVB system since crystallization.Abundances of HSE measured in different chunks of individual bulk samples, and in spot analyses of different portions of individual chunks, are homogeneous at the ±10% level or better. Modeling of HSE in the IVB system, therefore, is not impacted by sample heterogeneities. Concentrations of some other elements determined by spot analysis, such as P, Cr and Mn, however, vary by as much as two orders of magnitude and reflect the presence of trace phases.Assuming initial S in the range of 0 to 2 wt.%, the abundances of the HSE Re, Os, Ir, Ru, Pt, Rh, Pd and Au in bulk IVB irons are successfully accounted for via a fractional crystallization model. For these elements, all IVB irons can be interpreted as being representative of equilibrium solids, liquids, or mixtures of equilibrium solids and liquids.Our model includes changes in bulk D values (ratio of concentration in the solid to liquid) for each element in response to expected increases in S and P in the evolving liquid. For this system, the relative D values are as follow: Os > Re > Ir > Ru > Pt > Rh > Pd > Au. Osmium, Re, Ir and Ru were compatible elements (favor the solid) throughout the IVB crystallization sequence; Rh, Pd and Au were incompatible (favor the liquid). Extremely limited variation in Pt concentrations throughout the IVB crystallization sequence requires that D(Pt) remained at unity.In general, D values derived from the slopes of logarithmic plots, compared with those calculated from recent parameterizations of D values for metal systems are similar, but not identical. Application of D values obtained by the parameterization method is problematic for comparisons of the compatible elements with similar partitioning characteristics. The slope-based approach works well for these elements. In contrast, the slope-based approach does not provide viable D values for the incompatible elements Pd and Au, whereas the parameterization method appears to work well. Modeling results suggest that initial S for this system may have been closer to 2% than 0, but the elements modeled do not tightly constrain initial S.Consistent with previous studies, our calculated initial concentrations of HSE in the IVB parent body indicate assembly from materials that were fractionated via high temperature condensation processes. As with some previous studies, depletions in redox sensitive elements and corresponding high concentrations of Re, Os and Ir present in all IVB irons are interpreted as meaning that the IVB core formed in an oxidized parent body. The projected initial composition of the IVB system was characterized by sub-chondritic Re/Os and Pt/Os ratios. The cause of this fractionation remains a mystery. Because of the refractory nature of these elements, it is difficult to envision fractionation of these elements (especially Re-Os) resulting from the volatility effects that evidently affected other elements.  相似文献   

Named entity recognition goes to old regime France: geographic text analysis for early modern French corpora     

Katherine McDonough  Ludovic Moncla  Matje van de Camp 《International journal of geographical information science》2013,27(12):2498-2522

ABSTRACT

Geographic text analysis (GTA) research in the digital humanities has focused on projects analyzing modern English-language corpora. These projects depend on temporally specific lexicons and gazetteers that enable place name identification and georesolution. Scholars working on the early modern period (1400–1800) lack temporally appropriate geoparsers and gazetteers and have been reliant on general purpose linked open data services like Geonames. These anachronistic resources introduce significant information retrieval and ethical challenges for early modernists. Using the geography entries of the canonical eighteenth-century Encyclopédie, we evaluate rule-based named entity recognition (NER) systems to pinpoint areas where they would benefit from adjustments for processing historical corpora. As we demonstrate, annotating nested and extended place information is one way to improve early modern GTA. Working with Enlightenment sources also motivates a critique of the landscape of digital geospatial data.  相似文献   

Understanding and Managing the Potential By-Products of PFAS Destruction     

John Horst  Jeffrey McDonough  Ian Ross  Erika Houtz 《Ground Water Monitoring & Remediation》2020,40(2):17-27

  相似文献