Paleogene carbon isotope excursions in the Bunkers Hill borehole: Hampshire Basin, UK     

Emma Hodgson  Stephen T. Grimes  Gregory D. Price  Meriel E.J. Fitzpatrick  Malcolm B. Hart  Melanie J. Leng 《Proceedings of the Geologists' Association. Geologists' Association》2011,122(3):460-471

This study demonstrates that the Bunkers Hill borehole, which is located within the Hampshire Basin, contains a carbon isotope excursion (CIE) in the Upnor Formation followed by a positive recovery from another CIE within the overlying Reading Formation. This study has also shown that the CIE in the Upnor Formation predates the Paleocene/Eocene Thermal Maximum (PETM), while the carbon isotope recovery at the base of the Reading Formation is most likely related to it. The positive carbon isotope trend, before a return to more negative values, seen throughout the majority of the Reading Formation can also be seen in coeval deposits in the Jubilee 404T borehole in the London Basin and in the Tienen Formation in the Doel and Kallo boreholes from the Belgium Basin. This indicates that this post-PETM carbon isotope signal may, therefore, be regional if not global in nature.  相似文献   

A 500 yr speleothem-derived reconstruction of late autumn–winter precipitation, northeast Turkey     

Catherine N. Jex  Andy Baker  Jonathan M. Eden  Warren J. Eastwood  Ian J. Fairchild  Melanie J. Leng  Louise Thomas  Hilary J. Sloane 《Quaternary Research》2011,75(3):399-405

A verified instrumental calibration of annually resolved δ¹⁸O for a stalagmite from Gümü?hane in northeast Turkey is presented and cross-validated using a ‘leave-one-out’ technique. The amount of late autumn to winter precipitation is negatively correlated with stalagmite δ¹⁸O between AD 1938 and 2004. The observed relationship is extrapolated back to ~ AD 1500 leading to the first long winter precipitation reconstruction for this region. Modern day October to January precipitation is linked to pressure fields in Western Russia. Anomalously lower reconstructed rainfall is recorded in AD 1540–1560 at which time higher pressure over the Caspian Sea region is inferred.  相似文献   

Inter-laboratory comparison of oxygen isotope compositions from biogenic silica     

Bernhard Chapligin  Melanie J. Leng  Anne Alexandre  Akira Ijiri  Aldo Shemesh  Ulrike Herzschuh  Hanno Meyer  Yusuke Okazaki  Zachary D. Sharp  Corinne Sonzogni  Florence Sylvestre  Ruth Yam 《Geochimica et cosmochimica acta》2011,75(22):7242-7256

Several techniques have been introduced in the last decades for the dehydration and release of O₂ from biogenic silica (opal-A) for oxygen-isotope analysis. However, only one silica standard is universally available: a quartz standard (NBS28) distributed by the IAEA, Vienna. Hence, there is a need for biogenic silica working standards. This paper compares the existing methods of oxygen-isotope analyses of opal-A and aims to characterize additional possible working standards to calibrate the δ¹⁸O values of biogenic silica. For this purpose, an inter-laboratory comparison was organized. Six potential working standard materials were analysed repeatedly against NBS28 by eight participating laboratories using their specific analytical methods. The materials cover a wide range of δ¹⁸O values (+23 to +43‰) and include diatoms (marine, lacustrine), phytoliths and synthetically-produced hydrous silica. To characterize the proposed standards, chemical analyses and imaging by scanning electron microscopy (SEM) were also performed. Despite procedural differences at each laboratory, all methods are in reasonable agreement with a standard deviation (SD) for δ¹⁸O values between 0.3‰ and 0.9‰ (1σ). Based on the results, we propose four additional biogenic silica working standards (PS1772-8: 42.8‰; BFC: 29.0‰; MSG60: 37.0‰; G95-25-CL leaves: 36.6‰) for δ¹⁸O analyses, available on request through the relevant laboratories.  相似文献   

Core lithologies and their constraints on gas-hydrate occurrence in the East Sea, offshore Korea: Results from the site UBGH1-9     

Jang-Jun Bahk  In-Kwon Um  Melanie Holland 《Marine and Petroleum Geology》2011,28(10):1943-1952

Drilling at the site UBGH1-9, offshore Korea in 2007, revealed varied gas-hydrate saturation with depth and a wide variety of core litholgies, demonstrating how the variations in the lithology are linked with those in gas-hydrate saturation and morphology. Discrete excursions to low chlorinity values from in situ background chlorinity level occur between 63 and 151 mbsf. In this occurrence zone, gas-hydrate saturations estimated from the low chlorinity anomalies range up to 63.5% of pore volume with an average of 9.9% and do not show a clear depth-dependent trend. Sedimentary facies analysis based on grain-size distribution and sedimentary structures revealed nine sediment facies which mainly represent hemipelagic muds and fine- to medium-grained turbidites. According to the sedimentary facies distribution, the core sediments are divided into three facies associations (FA): FA I (0–98 mbsf) consisting mainly of alternating thin- to medium-bedded hemipelagic mud and turbidite sand or mud beds, FA II (98–126 mbsf) dominated by medium- to very thick-bedded turbidite sand or sandy debris flow beds, and FA III (126–178 mbsf) characterized by thick hemipelagic mud without intervening discrete turbidite sand layers. Thermal anomalies from IR scan, mousse-like and soupy structures on split-core surfaces, non-destructive measurements of pressure cores, and comparison of gas-hydrate saturations with sand contents of corresponding pore-water squeeze cakes, collectively suggest that the gas hydrate at the site UBGH1-9 generally occurs in two different types: “pore-filling” type preferentially associated with thin- to medium-turbidite sand beds in the FA I and “fracture-filling” type which occurs as hydrate veins or nodules in hemipelagic mud of the FA III. Gas-hydrate saturation in the FA II is generally anomalously low despite the dominance of turbidite sand or sandy debris flow beds, suggesting insufficient methane supply.  相似文献   

New OSL dating of UK loess: indications of two phases of Late Glacial dust accretion in SE England and climate implications     

Michèle L. Clarke  Antoni E. Milodowski  Jon E. Bouch  Melanie J. Leng  Kevin J. Northmore 《第四纪科学杂志》2007,22(4):361-371

Windblown dust deposits or loess, locally known in the UK as brickearth, blanket many parts of southern England outside the limits of the British and Irish Ice Sheet. The best‐studied loess exposures occur in Kent, southeast England, where the deposits are believed to be Late Glacial in age. New sedimentological evidence is presented for phases of accretion with two distinct units, a calcareous brickearth exhibiting periglacial cryoturbation and a non‐calcareous, massive brickearth. Optically stimulated luminescence (OSL) dating has been applied to chemically isolated modal quartz silts to derive a chronology for sediment accretion and to better understand the palaeoclimatic significance of these deposits. © British Geological Survey/Natural Environment Research Council copyright 2007. Reproduced with the permission of BGS/NERC. Published by John Wiley & Sons, Ltd.  相似文献   

Integrated stratigraphy and palaeoenvironment of the P/E boundary interval, Rakhi Nala section, Indus Basin (Pakistan)     

Muhammad Hanif  Malcolm B. Hart  Stephen T. Grimes  Melanie J. Leng 《Arabian Journal of Geosciences》2014,7(1):323-339

Marine sedimentary section across the Paleocene/Eocene (P/E) boundary interval is preserved in the Dungan Formation (Lower Indus Basin), Pakistan. Four dinoflagellate zones in the P/E interval of the Rakhi Nala section (Lower Indus Basin) are identified and correlated. The quantitative analysis of the dinoflagellate cyst assemblages together with geochemical data are used to reconstruct the palaeoenvironment across the P/E interval. The dinocyst assemblages allow the local correlation of the Dungan Formation (part) of the Sulaiman Range with the Patala Formation (part) of the Upper Indus Basin and global correlation of the Zone Pak-DV with the Apectodinium acme Zone of the Northern and Southern hemispheres. The onset of the carbon isotopic excursion (CIE) associated with Paleocene Eocene Thermal Maximum (PETM) is used globally to identify the P/E boundary. The CIE for the total organic carbon (fine fraction) δ¹³C_FF is of a magnitude of ?1.7‰ is recorded for the first time in the Indus Basin. The Apectodinium acme precedes and straddles the onset of the CIE in the Indus Basin. This Apectodinium acme is also accompanied by a planktonic and benthonic foraminifera “barren zone.” The CIE in the Indus Basin, coupled with the changes in the dinocyst distribution and the benthonic and planktonic foraminifera assemblages, provides evidence of the changes associated with the PETM in this little-known part of the world. The benthonic foraminiferal assemblage indicates bathyal environment of deposition at the time of P/E boundary interval; the presence of dominantly open marine dinoflagellates and high planktonic foraminiferal ratio suggest that the water column at this site was well connected with the rest of the Tethys.  相似文献   

The Purpose and Age of Underwater Walls in the Bay of Elaia of Western Turkey: A Multidisciplinary Approach     

Martin Seeliger  Dominik Brill  Stefan Feuser  Melanie Bartz  Ercan Erkul  Daniel Kelterbaum  Andreas Vtt  Christina Klein  Felix Pirson  Helmut Brückner 《Geoarchaeology》2014,29(2):138-155

Pergamum (modern: Bergama) was operating an important harbour used by military forces and merchants at the city of Elaia during Hellenistic and Roman Imperial times. Harbour‐related facilities such as warehouses, breakwaters and wharfs document the importance of this harbour site not only for the Pergamenians. This paper focuses on the purpose and age of six submerged wall structures situated approximately 1 km south of the ancient closed harbour basin of Elaia. Geoelectric cross‐sections and semi‐aquatic coring near these walls failed to detect any solid basement under the walls which excludes their possible use as breakwaters or wharfs. Instead, the walls were most likely delineating and separating evaporation ponds of salt works, which compares well with similar structures from other periods and places around the Mediterranean. Combined OSL and ¹⁴C‐dating determined the construction age of the installation between the 4th and 6th centuries A.D. Subsequent (re‐)uses are likely and are in agreement with findings from archaeological surveys.  相似文献   

Remote sensing of Carhuarazo volcanic complex using ASTER imagery in Southern Peru to detect alteration zones and volcanic structures – a combined approach of image processing in ENVI and ArcGIS/ArcScene     

Melanie Brandmeier 《国际地球制图》2013,28(8):629-648

A combined approach to detect hydrothermal alteration zones and their mineral distribution is proposed for a relatively remote area around the Carhuarazo volcanic complex in southern Peru encompassing 2222 km². In this region, tertiary volcanic structures associated with hydrothermal alteration are well known to host epithermal ore deposits. We make an attempt to detect and to quantify alteration minerals based on spectral analysis using ASTER reflectance data product provided by LP-DAAC. Besides commonly used ratio images, mineral indices (MI) and relative band depth images (RBD), we also extracted endmember spectra using Pixel-Purity-Processing preceded by minimum noise fraction transformation. These spectra are thought to represent the spectrally purest pixel of the image and show the typical absorption features of the main constituents. Based on this assumption, we used different spectral analysis methods in order to extract the most important alteration minerals for such an environment. These minerals were then used for matched filter processing in areas showing high values in MIs and RBDs. Using this method, we detected and mapped argillic alteration and variations in the distribution of important minerals like alunite, kaolinite or nacrite. There were no indications for the presence of propilitization at ASTER spatial resolutions. Our method can be applied easily to any ASTER scene and provides information about the intensity of alteration and the character of alteration zones. The intensity is highest in the centre of the Carhuarazo volcanic complex and is mostly argillic with a high content of alunite, dickite and other clay minerals.  相似文献   

Diatom-inferred late Pleistocene and Holocene palaeolimnological changes in the Ioannina basin, northwest Greece     

Timothy D. Jones  Ian T. Lawson  Jane M. Reed  Graham P. Wilson  Melanie J. Leng  Merle Gierga  Stefano M. Bernasconi  Rienk H. Smittenberg  Irka Hajdas  Charlotte L. Bryant  P. C. Tzedakis 《Journal of Paleolimnology》2013,49(2):185-204

The character and impact of climate change since the last glacial maximum (LGM) in the eastern Mediterranean region remain poorly understood. Here, two new diatom records from the Ioannina basin in northwest Greece are presented alongside a pre-existing record and used to infer past changes in lake level, a proxy for the balance between precipitation and evaporation. Comparison of the three records indicates that lake-level fluctuations were the dominant driver of diatom assemblage composition change, whereas productivity variations had a secondary role. The reconstruction indicates low lake levels during the LGM. Late glacial lake deepening was underway by 15.0 cal kyr BP, implying that the climate was becoming wetter. During the Younger Dryas stadial, a lake-level decline is recorded, indicating arid climatic conditions. Lake Ioannina deepened rapidly in the early Holocene, but long-term lake-level decline commenced around 7.0 cal kyr BP. The pattern of lake-level change is broadly consistent with an existing lake-level reconstruction at Lake Xinias, central Greece. The timing of the apparent change, however, is different, with delayed early Holocene deepening at Xinias. This offset is attributed to uncertainties in the age models, and the position of Xinias in the rain shadow of the Pindus Mountains.  相似文献   

Tidal and Groundwater Fluxes to a Shallow, Microtidal Estuary: Constraining Inputs Through Field Observations and Hydrodynamic Modeling     

Neil K. Ganju  Melanie Hayn  Shih-Nan Chen  Robert W. Howarth  Patrick J. Dickhudt  Alfredo L. Aretxabaleta  Roxanne Marino 《Estuaries and Coasts》2012,35(5):1285-1298

Increased nutrient loading to estuaries has led to eutrophication, degraded water quality, and ecological transformations. Quantifying nutrient loads in systems with significant groundwater input can be difficult due to the challenge of measuring groundwater fluxes. We quantified tidal and freshwater fluxes over an 8-week period at the entrance of West Falmouth Harbor, Massachusetts, a eutrophic, groundwater-fed estuary. Fluxes were estimated from velocity and salinity measurements and a total exchange flow (TEF) methodology. Intermittent cross-sectional measurements of velocity and salinity were used to convert point measurements to cross-sectionally averaged values over the entire deployment (index relationships). The estimated mean freshwater flux (0.19?m³/s) for the 8-week period was mainly due to groundwater input (0.21?m³/s) with contributions from precipitation to the estuary surface (0.026?m³/s) and removal by evaporation (0.048?m³/s). Spring?Cneap variations in freshwater export that appeared in shorter-term averages were mostly artifacts of the index relationships. Hydrodynamic modeling with steady groundwater input demonstrated that while the TEF methodology resolves the freshwater flux signal, calibration of the index?Csalinity relationships during spring tide conditions only was responsible for most of the spring?Cneap signal. The mean freshwater flux over the entire period estimated from the combination of the index-velocity, index?Csalinity, and TEF calculations were consistent with the model, suggesting that this methodology is a reliable way of estimating freshwater fluxes in the estuary over timescales greater than the spring?Cneap cycle. Combining this type of field campaign with hydrodynamic modeling provides guidance for estimating both magnitude of groundwater input and estuarine storage of freshwater and sets the stage for robust estimation of the nutrient load in groundwater.  相似文献