Evidence for the depletion of ammonia in the Uranus atmosphere     

Samuel Gulkis  Michael A. Janssen  Edward T. Olsen 《Icarus》1978,34(1):10-19

The theoretical disk brightness temperature spectra for Uranus are computed and compared with the observed microwave spectrum. It is shown that the emission observed at short centimeter wavelengths originates deep below the region where ammonia would ordinarily begin to condense. We demonstrate that this result is inconsistent with a wide range of atmospheric models in which the partial pressure of NH₃ is given by the vapor-pressure equation in the upper atmosphere. It is estimated that the ammonia mixing ratio must be less than 10^?6 in the 150 to 200°K temperature range. This is two orders of magnitude less than the expected mixing ratio based on solar abundances. The evidence for this depletion and a possible explanation are discussed.  相似文献   

An estimate of the temperature and abundance of CH₄ and other molecules in the atmosphere of Uranus     

Michael J.S. Belton  S.H. Hayes 《Icarus》1975,24(3):348-357

We present a preliminary analysis of CH₄ absorptions near 6800 Å in new high resolution spectra of Uranus. A curve of growth analysis of the data yields a rotational temperature near 100 K and a CH₄/H₂ ratio that is 1 to 3 times that expected for a solar type composition. The long pathlengths of CH₄, apparently demanded by absorptions near 4700 Å, are qualitatively shown to be the result of line formation in a deep, predominantly Rayleigh scattering atmosphere in which continuum absorption is a strong function of wavelength. The analysis of the CH₄ also yields a minimum value for the effective pressure of line formation (～ 2 atm). This value is shown to be twice that expected on Uranus if the atmosphere were predominantly H₂. It is speculated that large amounts of some otherwise optically inert gas is present in the Uranus atmosphere. N₂ is suggested as a possible candidate since there are cosmogonic reasons why Uranus should contain large amounts of N relative to C, He, and H, and also because the pressure-induced pure rotation spectrum of N₂ could possibly account for the low brightness temperatures that have recently been observed at 33 and 350 μm. If N₂ is present the planet probably possesses a surface at the 10–100 atmosphere level.  相似文献   

Large-scale ionization fronts and the nature and distribution of light scattering particles in the orion nebula     

Michael A. Dopita  Syuzo Isobe  John Meaburn 《Astrophysics and Space Science》1975,34(1):91-121

Image-tube filter photographs calibrated against photoelectric filter photometry have been used to give maps of M42 in absolute flux units over the central 15 arc min of the nebula in Hα, [Nii] (λ 6584 Å), Hβ and continuum at λ 4700 Å. Maps of the ratios Hα/[Nii] and (for the first time) of continuum/Hβ have been produced with unprecedented spatial resolution. These show that the gas to dust ratio is high near the exciting stars and falls strongly in the vicinity of large scale ionization fronts marked by minima in the Hα/[Nii] ratio. These results are interpreted in terms of detailed shell models containing either ice or graphite or silicate scattering particles. In all models there must be a central hole in the distribution of scattering particles. The effect of neutral globules and intrusions is investigated. It is found that all types of grain are trapped inside neutral intrusions near the centre of the nebula by the pressure of the Lα light surrounding the globule, but in the early evolution of the nebula particles can escape into the ionized medium when fronts are R-type. Ice grains escaping at this time will be destroyed for distances to the exciting stars less than 1 pc. These results can explain both the central hole in dust and the underabundance of oxygen in the ionized gas observed earlier. Arguments depending on colour index of the scattered light indicate that mixtures of scattered light from ice in the globules and from ice in the ionized medium can explain the observations, but that the graphite and silicate particles fail. A schematic model of the Orion Nebula is presented to attempt to explain the large scale phenomena observed here. It demonstrates that simple shell models for this nebula are dubious.  相似文献   

Observations of Jupiter at 26.3 MHz using a large array     

Michael D. Desch  Thomas D. Carr  Jorge Levy 《Icarus》1975,25(1):12-17

A 640 element phase-steerable dipole array has been used to make highly sensitive observations of the planet Jupiter during the 1973 apparition. The satellite Io is found to have very little influence at the low flux levels, whereas the definition of sources A and B appears to be relatively flux independent. A two-dimensional analysis of the data in the Jupiter-Io plane has revealed considerable source B activity at low intensities which is not influenced by Io.  相似文献   

Response to the Comment by G. Druschel and M. Borda on “Pyrite dissolution in acidic media”     

Michael Descostes  Pierre Vitorge 《Geochimica et cosmochimica acta》2006,70(20):5251-5252

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Acid leaching of ash and coal: Time dependence and trace element occurrences     

Mehtap Paul  Meryem Seferinoğlu  Gul Asiye Ayçık  Åke Sandström  Michael L. Smith  Jan Paul 《International Journal of Mineral Processing》2006

The leaching of coal and coal/asphaltite/wood-ashes in sulfuric acid (pH 1.0, 25 °C, S/L, 1:10) was studied as a function of time; acid consumption and extracted metal concentrations are presented. Whole coals consumed acid rapidly during the first few minutes, followed by slow acid consumption. Wood-, lignite-, and asphaltite-ashes consumed acid in two stages, the rapid phase extending < 30 min and the slow phase extended up to 10 days. The rapid phase was dominated by the dissolution of Ca, K and Mg ions for wood-ash, by Ca, Al and Mg ions for lignite-ash and Ca and Mg ions for asphaltite-ash. The sulfur concentration in solution and the concentrations of Ca, Fe, K, Mg, Na, P, Al and Mn in the aqueous phase verified the neutralizing capacity of the untreated ashes as well as the formation of insoluble sulfates in the residues. The slow phase kinetics differed for different fuels and exhibited leaching of several abundant elements—Fe, Al, K, Na and Mn. Trace elements (Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb, Th, U, V, Zn) sometimes required up to 32 h for maximal extraction from ashes. Suggestions are presented regarding the chemical nature of trace elements in the untreated coals and ashes and suitable residence times for economical industrial processes. We think it possible to combine bacteriological oxidation of sulfidic concentrates of acid leaching from ash of various qualities or even whole coals.  相似文献   

Effects of Hurricane Ivan on water quality in Pensacola Bay, Florida     

James D. Hagy  John C. Lehrter  Michael C. Murrell 《Estuaries and Coasts》2006,29(6):919-925

Pensacola Bay, Florida, was in the strong northeast quadrant of Hurricane Ivan when it made landfall on September 16, 2004 as a category 3 hurricane on the Saffir-Simpson scale. We present data describing the timeline and maximum height of the storm surge, the extent of flooding of coastal land, and the magnitude of the freshwater inflow pulse that followed the storm. We computed the magnitude of tidal flushing associated with the surge using a tidal prism model. We also evaluated hurricane effects on water quality using water quality surveys conducted 20 and 50 d after the storm, which we compared with a survey 14 d before landfall. We evaluated the scale of hurricane effects relative to normal variability using a 5-yr monthly record. Ivan's 3.5 m storm surge inundated 165 km² of land, increasing the surface area of Pensacola Bay by 50% and its volume by 230%. The model suggests that 60% of the Bay's volume was flushed, initially increasing the average salinity of Bay waters from 23 to 30 and lowering nutrient and chlorophylla concentrations. Additional computations suggest that wind forcing was sufficient to completely mix the water column during the storm. Freshwater discharge from the largest river increased twentyfold during the subsequent 4 d, stimulating a modest phytoplankton bloom (chlorophyll up to 18 μg l⁻¹) and maintaining hypoxia for several months. Although the immediate physical perturbation was extreme, the water quality effects that persisted beyond the first several days were within the normal range of variability for this system. In terms of water quality and phytoplankton productivity effects, this ecosystem appears to be quite resilient in the face of a severe hurricane effect.  相似文献   

Spatial and temporal variability of Holocene temperature in the North Atlantic region   总被引：1，自引：0，他引：1  

Michael R. Kaplan  Alexander P. Wolfe 《Quaternary Research》2006,65(2):223-231

The early Holocene climate of the North Atlantic region was influenced by two boundary conditions that were fundamentally different from the present: the presence of the decaying Laurentide Ice Sheet (LIS) and higher than present summer solar insolation. In order to assess spatial and temporal patterns of Holocene climate evolution across this region, we collated quantitative paleotemperature records at sub-millennial resolution and synthesized their temporal variability using principal components analysis (PCA). The analysis reveals considerable spatial variability, most notably in the time-transgressive expression of the Holocene thermal maximum (HTM). Most of the region, but especially areas peripheral to the Labrador Sea and hence closest to the locus of LIS disintegration, experienced maximum Holocene temperatures that lagged peak summer insolation by 1000-3000 years. Many sites from the northeastern North Atlantic sector, including the Nordic Seas and Scandinavia, either warmed in phase with maximum summer insolation (11,000-9000 years ago) or were less strongly lagged than the Baffin Bay-Labrador Sea region. These spatially complex patterns of Holocene climate development, which are defined by the PCA, resulted from the interplay between final decay of the LIS and solar insolation forcing.  相似文献   

Holocene climate and cultural evolution in late prehistoric-early historic West Asia   总被引：2，自引：0，他引：2  

Michael Staubwasser  Harvey Weiss 《Quaternary Research》2006,66(3):372-387

The precipitation climatology and the underlying climate mechanisms of the eastern Mediterranean, West Asia, and the Indian subcontinent are reviewed, with emphasis on upper and middle tropospheric flow in the subtropics and its steering of precipitation. Holocene climate change of the region is summarized from proxy records. The Indian monsoon weakened during the Holocene over its northernmost region, the Ganges and Indus catchments and the western Arabian Sea. Southern regions, the Indian Peninsula, do not show a reduction, but an increase of summer monsoon rain across the Holocene. The long-term trend towards drier conditions in the eastern Mediterranean can be linked to a regionally complex monsoon evolution. Abrupt climate change events, such as the widespread droughts around 8200, 5200 and 4200 cal yr BP, are suggested to be the result of altered subtropical upper-level flow over the eastern Mediterranean and Asia.The abrupt climate change events of the Holocene radically altered precipitation, fundamental for cereal agriculture, across the expanse of late prehistoric-early historic cultures known from the archaeological record in these regions. Social adaptations to reduced agro-production, in both dry-farming and irrigation agriculture regions, are visible in the archaeological record during each abrupt climate change event in West Asia. Chronological refinement, in both the paleoclimate and archaeological records, and transfer functions for both precipitation and agro-production are needed to understand precisely the evident causal linkages.  相似文献   

Is the Greenland Ice Sheet in a state of collapse?     

Poul Christoffersen  Michael J. Hambrey 《Geology Today》2006,22(3):98-103

The Greenland Ice Sheet is thinning at an accelerating pace and the ice sheet's contribution to sea-level rise has doubled in less than a decade. New data show rapid and widespread changes in the behaviour of the ice sheet, particularly along the coastal margin. These changes coincide with a decade of sustained Arctic warming of up to 3 °C. Decay of the Greenland Ice Sheet in response to global warming will not only be governed by increased surface melting during longer and warmer summers but also by a speed-up of coastal glaciers that drain the interior ice sheet. A precise estimate of sea-level rise in the twenty-first century relies on improved theoretical treatment of these glaciers in computer models.  相似文献