Geochemistry of groundwater in the alluvial plain of Tucumán province, Argentina   总被引：3，自引：0，他引：3  

Gabriela M. García  Margarita del V. Hidalgo  Miguel A. Blesa 《Hydrogeology Journal》2001,9(6):597-610

The Salí River hydrogeological basin is one of the most productive artesian basins in Argentina. It is located in the southeastern part of the province of Tucumán, northwestern Argentina, and its groundwater resources are developed for water supply and irrigation. The chemical composition of the water is strongly influenced by the interaction with the basinal sediments and by hydrologic characteristics such as the flow pattern and time of residence. Three hydrochemical zones are defined in the study area and the processes that control the chemical composition of the water are manifestly different in each zone. The dissolution of halite, sodium sulphate, and gypsum explains part of the contained Na⁺, K⁺, Cl^–, SO₄ ^2–, and Ca²⁺, but other processes, such as cation exchange, calcite precipitation, weathering of aluminosilicates, and gas exchange with the atmosphere, also contribute to the water composition. The assessment of contamination indicators, such as pH, dissolved organic matter, dissolved oxygen, phosphate, and nitrate, indicates that the groundwater is suitable for human consumption. However, biological contamination has been detected in samples from some wells, especially those near the Salí River. Electronic Publication  相似文献   

A summary of sulfur dioxide emission rate measuremnts from Guatemalan volcanoes     

RJ Andres  WI Rose  RE Stoiber  SN Williams  O Matías  R Morales 《Bulletin of Volcanology》1993,55(5):379-388

Measurements of the sulfur dioxide (SO₂) emission rate from three Guatemalan volcanoes provide data which are consistent with theoretical and laboratory studies of eruptive and shallow magma chamber processes. In particular, unerupted magma makes a major contribution to the measured SO₂ emission rates at Santiaguito, a continuously erupting dacitic volcanic dome. Varying shallow magma convection rates can explain the variations in SO₂ emission rates at Santiaguito. At Fuego, a basaltic volcano currently in repose, SO₂ emission rate measurements are consistent with a high level magma body that is crystallizing and releasing volatiles. At Pacaya, a continuously erupting basaltic volcano, recent SO₂ emission rate measurements support laboratory simulation studies of strombolian eruptions; these studies indicate that the majority of gas escapes during eruptions and little gas escapes between eruptions.Average SO₂ emission rates over the last 20 years for Santiaguito, Fuego and Pacaya are 80, 160 and 260 Mg/d, respectively. On a global scale, these three volcanoes account for 1% of the annual global volcanic output of SO₂. Santiaguito and Pacaya, together, emit 6% of the total annual SO₂ emitted by continuously erupting volcanoes.Even though SO₂ measurements at these volcanoes have been made infrequently and by different investigators, the collective data help to establish a useful baseline by which to judge future changes. A more complete record of SO₂ emission rates from these volcanoes could lead to a better understanding of their eruption mechanisms and reduce the impact of their future eruptions on Guatemalan society.  相似文献   

Synoptic and mesoaerological study of radiation fog     

Morales  C. 《Meteorology and Atmospheric Physics》1958,10(4):387-409

Summary The present study was for the purpose of determining the conditions necessary to the formation of radiation fog. The temperature and relative humidity of the lowest stratum of the troposphere were sounded with a tethered balloon and radiosonde during a number of nights when the conditions were considered favourable for the formation of radiation fog: clear weather with effective net radiation, light wind, and high relative humidity at ground level. Advection fog was also studied on some occasions for comparison. The measurements were carried out in Uppsala. Meteorological phenomena of possible importance to the study were recorded concurrently with the measurements. The weather was analyzed synoptically and aerologically also on each occasion.The results of the investigation suggest that the conditions necessary to the formation of radiation fog are not only an effective net radiation, light wind, and high relative humidity at ground level, but also that the wind must be light and the relative humidity high at some distance above the ground. This permits the more or less marked surface inversion to leave ground level and to rise as a layer of rapid temperature transition. This is brought about by the radiation gradually emitting from the upper surface of the layer of mist or fog, formed in the lowest and chilled air strata, which are subsequently cooled from above until an unstable lapse rate develops. As a results, the layer of rapid temperature transition is maintained rather intact as it rises. If the radiation continues without obstruction and the wind is ligh aloft, this layer migrates upwards until it reaches a level at which the relative humidity is so low that the cooling necessary for condensation does not occur by radiation, limiting the extension of the underlying fog. If the relative humidity is high only in the undermost air strata, the surface inversion cannot leave ground level and no fog will be formed aloft. If the wind is strong aloft, the process is hindered by the increased turbulent exchange occurring between the high and low strata.

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Zusammenfassung Die vorliegende Untersuchung, die in Uppsala durchgeführt wurde, hat zum Zweck, die für die Bildung von Strahlungsnebel notwendigen Bedingungen festzulegen. Temperatur und relative Feuchtigkeit der untersten Troposphärenschicht wurden mit Fesselballon und Radiosonde während einer Anzahl Nächte ausgemessen, in denen die Bedingungen für die Bildung von Strahlungsnebel günstig erschienen, somit bei klarem Wetter mit effektiver Ausstrahlung, leichtem Wind und hoher relativer Feuchtigkeit am Boden. Zum Vergleich wurden auch einige Fälle von Mischungsnebel (Advektionsnebel) untersucht. Die Bestimmungen wurden in Uppsala durchgeführt. Gleichzeitig wurden auch weitere meteorologische Vorgänge, die für diese Untersuchung von Bedeutung sein konnten, aufgezeichnet. Zudem wurde das Wetter synoptisch und aerologisch bei jeder Gelegenheit un tersucht.Die Ergebnisse dieser Untersuchung legen die Annahme nahe, daß die für die Bildung von Strahlungsnebel not wendigen Bedingungen nicht nur in effektiver Ausstrahlung, leichtem Wind und hoher relativer Feuchtigkeit am Boden bestehen, sondern daß auch in gewisser Entfernung über dem Boden der Wind schwach und die Feuchtigkeit hoch sein muß. Dadurch wird es der mehr oder weniger ausgesprochenen Bodeninversion ermöglicht, das Bodenniveau zu verlassen und als Schicht eines schnellen Temperaturüberganges in die Höhe zu steigen. Dies wird bewirkt durch die Ausstrahlung, die allmählich von der Oberseite der Nebelschicht ausgeht, welche sich in den untersten und ausgekühlten Luftschichten bildet, die sich nach und nach von oben her abkühlen, bis sich ein instabiler Temperaturgradient entwickelt. Infolgedessen wird die Schicht des schnellen Temperaturübergangs beim Emporsteigen nahezu unverändert aufrechterhalten. Falls die Ausstrahlung ungehindert andauert und der Wind auch in der Höhe schwach ist, wandert diese Schicht aufwärts, bis sie ein Niveau erreicht, wo die relative Feuchtigkeit so niedrig ist, daß die für Kondensation notwendige Abkühlung nicht mehr durch die Ausstrahlung hervorgerufen wird, wodurch die Ausdehnung des darunter liegenden Nebels begrenzt wird. Wenn dagegen die relative Feuchtigkeit nur in den alleruntersten Luftschichten hoch ist, kann die Bodeninversion die Höhe des Erdbodens nicht verlassen und es bildet sich haher in der Höhe kein Nebel. Falls in der Höhe starker Wind weht, wird der Prozeß der Nebeldung durch die verstärkten Austauschvorgänge zwischen den hohen und den niederen Schichten verhindert.

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Résumé Le but de la présente étude faite à Uppsala est de déterminer les conditions de formation du brouillard de rayonnement. On a mesuré à cet effet la température et l'humidité relative des couches basses de la troposphère à l'aide de ballons captifs et de radiosondes pendant un certain nombre de nuits apparement favorables à la formation de brouillard, done par temps clair, vent faible et forte humidité au sol. Quelques cas de brouillard d'advection ont été aussi retenus à titre de comparaison. En même temps on a relevé d'autres processus météorologiuqes pouvant être utiles; la situation météorologique fit l'objet d'une analyse synoptique et aérologique dans chaque cas.Les résultats obtenus font penser que ce ne sont pas seulement le rayonnement, la faible agitation de l'air et la forte humidité relative au sol qui sont déterminants dans la formation du brouillard; le vent doit être faible et l'humidité élevée également à une certaine hauteur au-dessus du sol: c'est alors que l'inversion plus ou moins prononcée peut s'élever. Cela résulte du refroidissement par rayonnement de la surface du brouillard bas; la couche froide au sol augmente alors d'épaisseur jusqu'à ce qu'un gradient vertical instable apparaisse. La couche de décroissance rapide de température se maintient tout en gagnant vers le haut, et le processus ne s'arrête que lorsqu'un niveau à faible humidité est atteint; la couche de brouillard a alors acquis son épaisseur maximum. Si l'humidité relative n'est forte que dans les couches les plus basses, l'inversion ne peut par contre quitter le sol et il ne se forme pas de brouillard plus haut. S'il y a du vent fort a une certaine hauteur, le processus de formation du brouillard est rendu impossible par le brassage des couches basses et moyennes.

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With 12 Figures

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Dedicated to Dr.Anders K. Ångström on the occasion of his 70th birthday.  相似文献   

On solution of the inverse problem for confined aquifer flow via maximum likelihood     

Hugo A. Loaiciga  Miguel A. Mariño 《Mathematical Geology》1986,18(7):677-692

Joint estimation of transmissivity (T) and storativity (S) in a confined aquifer is done via maximum likelihood (ML). The differential equation of groundwater flow is discretized by the finite-element method, leading to equation _t+x _t=u _t. Elements of matrices and , as well as estimated covariance matrix of noise termu _t, are functions of T and S. By minimizing the negative loglikelihood function corresponding to discretized groundwater flow equation with respect to T and S, ML estimators are obtained. The ML approach is found to yield accurate estimates of T and S (within 9 and 10% of their actual values, respectively) and showed quadratic convergence in Newton's search technique. Prediction of aquifer response, using ML estimators, results in estimated piezometric heads accurate to ±0.5 m from their actual, exact values. Statistical properties of ML estimators are derived and some basic results for statistical inference are given.  相似文献   

A description of how metal pollution occurs in the Tinto-Odiel rias (Huelva-Spain) through the application of cluster analysis   总被引：3，自引：0，他引：3  

Grande JA  Borrego J  Morales JA  de la Torre ML 《Marine pollution bulletin》2003,46(4):475-480

In the last few decades, the study of space-time distribution and variations of heavy metals in estuaries has been extensively studied as an environmental indicator. In the case described here, the combination of acid water from mines, industrial effluents and sea water plays a determining role in the evolutionary process of the chemical makeup of the water in the estuary of the Tinto and Odiel Rivers, located in the southwest of the Iberian Peninsula.Based on the statistical treatment of the data from the analysis of the water samples from this system, which has been affected by processes of industrial and mining pollution, the 16 variables analyzed can be grouped into two large families. Each family presents high, positive Pearson r values that suggest common origins (fluvial or sea) for the pollutants present in the water analyzed and allow their subsequent contrast through cluster analysis.  相似文献   

Adakite-like signature of Late Miocene intrusions at the Los Pelambres giant porphyry copper deposit in the Andes of central Chile: metallogenic implications   总被引：7，自引：0，他引：7  

Martin?Reich  Miguel?A.?ParadaEmail author  Carlos?Palacios  Andreas?Dietrich  Frank?Schultz  Bernd?Lehmann 《Mineralium Deposita》2003,38(7):876-885

Adakite-like features are recognized in the Late Miocene (~10 Ma) porphyritic intrusions of the Los Pelambres giant porphyry copper deposit, central Chile (32°S). Located within the southern portion of the flat-slab segment (28–33°S) of the Chilean Andes, the Al- and Na-rich porphyries of Los Pelambres display distinctly higher Sr/Y (~100–300) and La_N/Yb_N (~25–60) ratios than contemporaneous and barren magmatic units (e.g., La Gloria pluton, Cerro Aconcagua volcanic rocks) of the same Andean magmatic belt. Strong fractionation of heavy rare earth elements (HREE), absence of Eu anomalies, high Sr/Y and Zr/Sm and low Nb/Ta ratios suggest melt extraction from a garnet-amphibolite source. The Late-Miocene adakite-like porphyritic intrusions at Los Pelambres formed closely related in time and space to the subduction of the Juan Fernández Ridge (JFR) hotspot chain along the Chilean margin. Current tectonic reconstructions reveal that, at the time of formation of the Los Pelambres rocks, a W-E segment of the JFR started to subduct beneath them, producing a slow-down of a previously rapid southward migration of a NE-ridge—trench collision. These particular tectonic conditions are favorable for the origin of the Los Pelambres porphyry suite by melting of subducting young hotspot rocks under flat-slab conditions. The incorporation of crustal components into the oceanic lithopheric magma source by subduction erosion is evidenced by the Sr-Nd isotope composition of the Los Pelambres rocks different from the MORB signatures of true adakites. A close relationship apparently exists between the origin of this adakite-like magmatism and the source of the mineralization in the Los Pelambres porphyry copper deposit.Editorial handling: R.J. Goldfarb  相似文献   

Heavy metals in molluscs from the Basque Coast (Northern Spain): results from an 11-year monitoring programme   总被引：1，自引：0，他引：1  

Franco J  Borja A  Solaun O  Pérez V 《Marine pollution bulletin》2002,44(9):973-976

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The relation of meridional pressure gradients to North Atlantic deep water volume transport in an ocean general circulation model     

Alexa Griesel  Miguel Angel Morales Maqueda 《Climate Dynamics》2006,26(7-8):781-799

We use a coarse resolution ocean general circulation model to study the relation between meridional pressure and density gradients in the Southern Ocean and North Atlantic and the Atlantic meridional overturning circulation. In several experiments, we artificially modify the meridional density gradients by applying different magnitudes of the Gent–McWilliams isopycnal eddy diffusion coefficients in the Southern Ocean and in the North Atlantic and investigate the response of the simulated Atlantic meridional overturning to such changes. The simulations are carried out close to the limit of no diapycnal mixing, with a very small explicit vertical diffusivity and a tracer advection scheme with very low implicit diffusivities. Our results reveal that changes in eddy diffusivities in the North Atlantic affect the maximum of the Atlantic meridional overturning, but not the outflow of North Atlantic Deep Water into the Southern Ocean. In contrast, changes in eddy diffusivities in the Southern Ocean affect both the South Atlantic outflow of North Atlantic Deep Water and the maximum of the Atlantic meridional overturning. Results from these experiments are used to investigate the relation between meridional pressure gradients and the components of the Atlantic meridional overturning. Pressure gradients and overturning are found to be linearly related. We show that, in our simulations, zonally averaged deep pressure gradients are very weak between 20°S and about 30°N and that between 30°N and 60°N the zonally averaged pressure grows approximately linearly with latitude. This pressure difference balances a westward geostrophic flow at 30–40°N that feeds the southbound deep Atlantic western boundary current. We extend our analysis to a large variety of experiments in which surface freshwater forcing, vertical mixing and winds are modified. In all experiments, the pycnocline depth, assumed to be the relevant vertical scale for the northward volume transport in the Atlantic, is found to be approximately constant, at least within the coarse vertical resolution of the model. The model behaviour hence cannot directly be related to conceptual models in which changes in the pycnocline depth determine the strength of Atlantic meridional flow, and seems conceptually closer to Stommel’s box model. In all our simulations, the Atlantic overturning seems to be mainly driven by Southern Ocean westerlies. However, the actual strength of the Atlantic meridional overturning is not determined solely by the Southern Ocean wind stress but as well by the density/pressure gradients created between the deep water formation regions in the North Atlantic and the inflow/outflow region in the South Atlantic.  相似文献   

Uncertainties in projected impacts of climate change on European agriculture and terrestrial ecosystems based on scenarios from regional climate models     

J. E. Olesen  T. R. Carter  C. H. Díaz-Ambrona  S. Fronzek  T. Heidmann  T. Hickler  T. Holt  M. I. Minguez  P. Morales  J. P. Palutikof  M. Quemada  M. Ruiz-Ramos  G. H. Rubæk  F. Sau  B. Smith  M. T. Sykes 《Climatic change》2007,81(1):123-143

The uncertainties and sources of variation in projected impacts of climate change on agriculture and terrestrial ecosystems depend not only on the emission scenarios and climate models used for projecting future climates, but also on the impact models used, and the local soil and climatic conditions of the managed or unmanaged ecosystems under study. We addressed these uncertainties by applying different impact models at site, regional and continental scales, and by separating the variation in simulated relative changes in ecosystem performance into the different sources of uncertainty and variation using analyses of variance. The crop and ecosystem models used output from a range of global and regional climate models (GCMs and RCMs) projecting climate change over Europe between 1961–1990 and 2071–2100 under the IPCC SRES scenarios. The projected impacts on productivity of crops and ecosystems included the direct effects of increased CO₂ concentration on photosynthesis. The variation in simulated results attributed to differences between the climate models were, in all cases, smaller than the variation attributed to either emission scenarios or local conditions. The methods used for applying the climate model outputs played a larger role than the choice of the GCM or RCM. The thermal suitability for grain maize cultivation in Europe was estimated to expand by 30–50% across all SRES emissions scenarios. Strong increases in net primary productivity (NPP) (35–54%) were projected in northern European ecosystems as a result of a longer growing season and higher CO₂ concentrations. Changing water balance dominated the projected responses of southern European ecosystems, with NPP declining or increasing only slightly relative to present-day conditions. Both site and continental scale models showed large increases in yield of rain-fed winter wheat for northern Europe, with smaller increases or even decreases in southern Europe. Site-based, regional and continental scale models showed large spatial variations in the response of nitrate leaching from winter wheat cultivation to projected climate change due to strong interactions with soils and climate. The variation in simulated impacts was smaller between scenarios based on RCMs nested within the same GCM than between scenarios based on different GCMs or between emission scenarios.  相似文献   

Importance of geochemical transformations in determining submarine groundwater discharge-derived trace metal and nutrient fluxes     

Aaron J. Beck  Yoko Tsukamoto  Antonio Tovar-Sanchez  Miguel Huerta-Diaz  Henry J. Bokuniewicz  Sergio A. Sañudo-Wilhelmy 《Applied Geochemistry》2007

Seasonal (Spring and Summer 2002) concentrations of dissolved (<0.22 μm) trace metals (Ag, Al, Co, Cu, Mn, Ni, Pb), inorganic nutrients (NO₃, PO₄, Si), and DOC were determined in groundwater samples from 5 wells aligned along a 30 m shore-normal transect in West Neck Bay, Long Island, NY. Results show that significant, systematic changes in groundwater trace metal and nutrient composition occur along the flowpath from land to sea. While conservative mixing between West Neck Bay water and the groundwaters explains the behavior of Si and DOC, non-conservative inputs for Co and Ni were observed (concentration increases of 10- and 2-fold, respectively) and removal of PO₄ and NO₃ (decreases to about half) along the transport pathway. Groundwater-associated chemical fluxes from the aquifer to the embayment calculated for constituents not exhibiting conservative behavior can vary by orders of magnitude depending on sampling location and season (e.g. Co, 3.4 × 10²– 8.2 × 10³ μmol d⁻¹). Using measured values from different wells as being representative of the true groundwater endmember chemical composition also results in calculation of very different fluxes (e.g., Cu, 6.3 × 10³ μmol d⁻¹ (inland, freshwater well) vs. 2.1 × 10⁵ μmol d⁻¹(seaward well, S = 17 ppt)). This study suggests that seasonal variability and chemical changes occurring within the subterranean estuary must be taken into account when determining the groundwater flux of dissolved trace metals and nutrients to the coastal ocean.  相似文献