Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

Ghosts of the Milky Way: a search for topology in new quasar catalogues     

S. J. Weatherley  S. J. Warren  S. M. Croom  R. J. Smith  B. J. Boyle  T. Shanks  L. Miller  M. P. Baltovic 《Monthly notices of the Royal Astronomical Society》2003,342(1):L9-L13

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Isolation of resonance in acoustic backscatter from elastic targetsusing adaptive estimation schemes     

Azimi-Sadjadi  M.R. Wilbur  J. Dobeck  G.J. 《Oceanic Engineering, IEEE Journal of》1995,20(4):346-353

It has been shown that at certain frequencies the acoustic backscatter from elastic targets exhibits certain resonance behavior which closely relates to the physical properties of the target such as dimension, thickness, and composition. The purpose of this paper is to develop an automated approach for identifying the presence of resonance in the acoustic backscatter from an unknown underwater target by isolating the resonance part from the specular contribution. An adaptive transversal filter structure is used to estimate the specular part of the backscatter and consequently the error signal would provide an estimate of the resonance part. An important aspect of this scheme lies in the fact that it does not require an underlying model for the elastic return. The adaptation rule is based upon fast recursive least squares (RLS) learning. The approach taken in this paper is general in the sense that it can be applied to targets of unknown geometry and thickness and, further, does not require any a priori information about the target and/or the environment. Test results on acoustic data are presented which indicate the effectiveness of the proposed approach  相似文献   

A robust sample of submillimetre galaxies: constraints on the prevalence of dusty, high-redshift starbursts     

R. J. Ivison  Ian Smail  J. S. Dunlop  T. R. Greve  A. M. Swinbank  J. A. Stevens  A. M. J. Mortier  S. Serjeant  T. A. Targett  F. Bertoldi  A. W. Blain  S. C. Chapman 《Monthly notices of the Royal Astronomical Society》2005,364(3):1025-1040

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Book reviews     

Howard  R. F.  van den Oord  G. H. J.  Švestka  Z. 《Solar physics》1996,169(1):225-227

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Controlled Direction Reception Filtering of P- and S-Waves In τ-P Space     

S. A. Greenhalgh  I. M. Mason  E. Lucas  D. Pant  R. T. Eames 《Geophysical Journal International》1990,100(2):221-234

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Source rates and ion recycling rates for Na and K in Mercury's atmosphere     

R.M. Killen  M. Sarantos  P. Reiff 《Icarus》2004,171(1):1-19

The supply rates of Na and K to the atmosphere of Mercury by processes acting on the extreme surface—thermal vaporization, photon-stimulated desorption (PSD), and ion-sputtering—are limited by the rates at which atoms can be supplied to the extreme surface by diffusion from inside the regolith grains. Supply rates to the atmosphere are further regulated by ion retention and by gardening rates that supply new grains to the surface. We consider the limits on supply of sodium and potassium atoms to the atmosphere, and rates of photoion recycling to the surface. Thermal vaporization rates are severely limited by the ability of atoms to diffuse to the surface of the grain. Therefore, the diffusion-limited thermal vaporization rates on Mercury's surface are comparable to or less than the PSD rates. Ion sputtering is primarily due to highly ionized heavy ions, even though they represent a small fraction of the solar wind. We have shown that up to 60% of the Na photoions are deposited on the surface of Mercury. Ion recycling to the surface can have a long-term effect on the regolith abundance if an average recycling pattern persists such that more ions return to a particular area than are launched there. It is unknown whether the formation of latitude bands of >100% ion retention persist on average despite a rapidly changing magnetosphere. The total exospheric column of sodium observed at Mercury between 1997 to 2003 varied by a factor of 2-3 from perihelion to aphelion.  相似文献   

Accretion and evolution in close binaries     

A. R. King 《Astrophysics and Space Science》1996,237(1-2):169-184

The discovery of X-ray binary systems in the 1960's opened up stellar evolution theory by revealing further endpoints in addition to white dwarfs. This review summarises recent progress in studies of stellar-evolutionary processes that lead to X-ray binaries themselves, the mass transfer rates that power them, and the accretion processes which convert this into electromagnetic radiation. Particular attention is paid to the topics of mass transfer fluctuations and of the accretion by magnetic compact stars.  相似文献   

The first and second order moments of the polarization profiles of hydrogen lines     

R. HCasini  E. Landi Degl'Innocenti 《Solar physics》1996,164(1-2):91-96

The main properties of the first- and second-order moments of polarized hydrogen lines, forming in the presence of stationary electric and magnetic fields, are reviewed. The analytical results presented here apply directly to the case of optically-thin emission lines in the LTE regime. Some applications of such results to electric- and magnetic-field diagnostics in (solar) plasmas are then briefly considered.On leave from the Dipartimento di Astronomia e Scienza dello Spazio, Università di Firenze, Largo E. Fermi 5, I-50125 Firenze, Italy  相似文献   

The virial method and the classical ellipsoids     

Norman R. Lebovitz 《Journal of Astrophysics and Astronomy》1996,17(3-4):167-182

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