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111.
Abstract– The Moss meteorite is the first CO chondrite fall after a time period of 70 yr and the least terrestrially contaminated member of its group. Its cosmic‐ray exposure (CRE) age (T3 ~ 13.5 Ma; T21 ~ 14.6 Ma) is distinct among CO chondrites and, within witnessed falls is the shortest after Lancé, which we have reanalyzed. Gas retention ages are approximately 3.95 × 109 yr (U/Th‐He) and approximately 4.43 × 109 yr (K/Ar), respectively. Trapped Ar, Kr, and Xe are present in Moss in abundances typical for CO chondrites, with “planetary” elemental and isotopic compositions. Presence of HL‐xenon from presolar diamonds is observed in the stepwise release analysis of Lancé. It may also be present in Moss, but it is difficult to ascertain in single‐step bulk analyses. It follows from our new data combined with a survey of the literature that the abundance of trapped gases in CO chondrites is not a good indicator of their petrological subtype.  相似文献   
112.
This study investigates U-series, Sr isotopes, major and trace elements in a chalk aquifer system located in Eastern France. Soil and rock samples were collected along depth profiles down to 45 m in four localities as an attempt to investigate the weathering processes in the soil, the unsaturated zone and the saturated zone of the aquifer. Interstitial water was extracted from soils and rocks by a centrifugation technique. U-series offer a powerful tool to calculate weathering rates because the relative mobility of the U- and Th-isotopes can be precisely measured and it does not require the determination of a reference state as in other approaches. As expected, the data show very large mobile element depletion in the soil with large 230Th excess relative to 238U, while the rocks show more limited but not insignificant mobile element depletion. The U-series data have been used to constrain weathering rates based on a 1-D reactive transport model. Weathering rates in the near surface are about 10–100 times faster than at depth. However, when integrated over the depth of the cores, including the unsaturated and the saturated zones, this underground weathering represents more than 30% of the total weathering flux, assuming congruent dissolution of carbonates. The (234U/238U) ratios in interstitial water are consistent with solid samples showing 234U depletion near the surface and an excess 234U at depth. A leaching experiment performed on chalk shows that the excess 234U in natural waters percolating through carbonate rocks results both from preferential 234U leaching and direct recoil in the interstitial water. A new approach was used to derive the recoil ejection factor based on BET measurements and the fractal dimension of chalk surface. Consideration of preferential leaching and recoil allows a more accurate modeling of weathering rates.  相似文献   
113.
The daughter to parent (234U/238U) activity ratio in natural waters is often out of secular radioactive equilibrium. The major reason for this disequilibrium is related to the energetic α-decay of 238U and differential release of 234U relative to 238U. This disequilibrium originates from (1) preferential release of more loosely bound 234U from damaged mineral lattice sites or; (2) direct recoil of 234Th into surrounding media from near mineral surface boundaries, however, it is unclear which of the two mechanisms is most important in nature. To better quantify the effects of preferential release of 234U, two continuous laboratory granite leaching experiments conducted over 1100 h were performed. The leachates were characterized by declining U concentrations with time and (234U/238U) initially greater than unity (up to 1.15), which changed to below unity during leaching (∼0.95). The early elevated (234U/238U) suggests that additional 234U is released into solution by preferential release of 234U from mineral phases. However, the excess 234U constitutes a finite pool of easy leachable 234U and the (234U/238U) values become lower than unity when this pool is used up. A model based on first-order kinetics, dissolution rates and preferential release of 234U from damaged lattice sites was developed and is able to quantitatively predict the observed pattern of (234U/238U) values and U concentrations for the two granite leaching experiments. Extending the modeling to longer time scales more comparable to natural systems shows that the production of waters with high (234U/238U) ratios can be achieved in two distinct regimes (1) slow weathering where the rate of directly recoiled 234U near mineral surfaces into waters is high; (2) fast weathering where the role of incipient chemical weathering and preferential release of loosely bound 234U are important. The model is able to explain apparent opposite correlations between physical erosion rates and (234U/238U) in waters and it provides a new framework that will be useful for examining weathering regimes, their timescales and their coupling with physical erosion.  相似文献   
114.
Late Holocene palaeoceanography in Van Mijenfjorden, Svalbard   总被引:2,自引:0,他引:2  
Based on detailed stratigraphical analysis of sediment cores spanning the last ca. 4000 calendar years, we reconstruct the palaeoceanograhic changes in the fiord Van Mijenfjorden, western Svalbard. Benthic foraminiferal δ18O indicate a gradual reduction in bottom water salinities between 2200 BC and 500 BC. This reduction was probably mainly a function of reduced inflow of oceanic water to the fiord, due to isostatic shallowing of the outer fiord sill. Stable salinity conditions prevailed between 500 BC and. 1300 AD. After the onset of a major glacial surge of the tidewater Paulabreen (Paula Glacier) system (PGS) around 1300 AD, there was a foraminiferal faunal change towards glacier proximal conditions, associated with a slight bottom water salinity depletion. During a series of glacial surges occuring from 1300 AD up the present salinity in the fiord has further decreased, corresponding to a δ18O depletion of 0.5 %o. This salinity decrease corresponds to the period when the PGS lost an equivalent of 30 – 40 % of its present ice volume, mainly through calving in the fiord.  相似文献   
115.
Summary In this part II of the reanalysis of the global data, we present an interpretation of the transient motion of the winter monsoon over Asia and the India Ocean. This includes an analysis of the surface layer meridional flow channels that are important for the transport of pollutants for the land mass of Asia towards the ITCZ, which is located near 10° S. We have also examined the scales of the space-time variability of the near surface flows of the winter monsoon of the 1992–1993 season. Sample forecasts of these inflow features, using a very high resolution model, are illustrated to show that the field phase of the proposed Indian Ocean Experiment (INDOEX) can receive guidance from real time numerical experimentation. The final part of this paper addresses four dimensional trajectories and passive tracer addresses four dimensional trajectories and passive tracer transports with integration over a winter monsoon domain covering several samples of 10 day periods.With 21 Figures  相似文献   
116.
Summary This study entails a reanalysis of the TOGA-COARE, CEPEX period covering the months December 1992 through March 1993. Four times daily data sets were reanalyzed for the period. The unique aspect of this reanalysis is that (i) it incorporates physical initialization i.e. assimilation of rainfall from raingauge and satellite (OLR and microwave radiometric data), (ii) this reanalysis is carried out at a very high resolution, T170, global spectral model (space resolution of roughly 70 km at equator) and (iii) ECMWF reanalysis is used as a first guess field for this study.This analysis is global and is carried out at 15 vertical levels using the FSU global spectral model. In this study we have analyzed a large number of meterological variables such as wind, temperature, humidity, surface pressure, vertical velocity, cloud, rainfall, surface fluxes and diabatic heating. In this part of the paper we present the monthly mean and samples of daily fields of the reanalysis. Some of the major results of the reanalysis include the relationships among the flow fields and the ITCZ convection; the shallow northeast monsoon current and its rapid turning towards westerlies with height; an overabundance of middle clouds over the region of the ITCZ; and the distribution of heat sources and sinks. A motivation for this reanalysis is the forthcoming Indian Ocean Experiment (INDOEX), which is an international field experiment to be conducted during the winter monsoon time frame in 1999.With 25 Figures  相似文献   
117.
The Norwegian Ecological Model (NORWECOM) biophysical model system implemented with the ROMS ocean circulation model has been run to simulate conditions over the last 25 years for the North Atlantic. Modeled time series of water volume fluxes, primary production, and drift of cod larvae through their modeled ambient temperature fields have been analyzed in conjunction with VPA estimated time series of 3-year-old cod recruits in the Barents Sea. Individual time series account for less than 50% of the recruitment variability; however, a combination of simulated flow of Atlantic water into the Barents Sea and local primary production accounts for 70% of the variability with a 3-year lead. The associated regression predicts increased recruitment between 2007 and 2008 from about 450–700 million individuals with a standard error of nearly 150 million.  相似文献   
118.
Kinematics of extreme waves in deep water   总被引:2,自引:0,他引:2  
The velocity profiles under crest of a total of 62 different steep wave events in deep water are measured in laboratory using particle image velocimetry. The waves take place in the leading unsteady part of a wave train, focusing wave fields and random wave series. Complementary fully nonlinear theoretical/numerical wave computations are performed. The experimental velocities have been put on a nondimensional form in the following way: from the wave record (at a fixed point) the (local) trough-to-trough period, TTT and the maximal elevation above mean water level, ηm of an individual steep wave event are identified. The local wavenumber, k and an estimate of the wave slope, ε are evaluated from ω2/(gk)=1+ε2, where ω=2π/TTT and g denotes the acceleration of gravity. A reference fluid velocity, is then defined. Deep water waves with a fluid velocity up to 75% of the estimated wave speed are measured. The corresponding kηm is 0.62. A strong collapse of the nondimensional experimental velocity profiles is found. This is also true with the fully nonlinear computations of transient waves. There is excellent agreement between the present measurements and previously published Laser Doppler Anemometry data. A surprising result, obtained by comparison, is that the nondimensional experimental velocities fit with the exponential profile, i.e. eky, y the vertical coordinate, with y=0 in the mean water level.  相似文献   
119.
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