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21.
An integrated study has been carried out to elucidate the distribution and occurrence of arsenic in selected groundwater samples in the area of Sherajdikhan, Bangladesh. Arsenic and other parameters (T, pH, EC, Na+, K+, Ca2+, Mg2+, Cl, NO3 , SO4 2−, HCO3 , PO4 3−, Fe, Mn and DOC) have been measured in groundwater samples collected from shallow/deep tube wells at different depths. Hydrogeochemical data suggest that the groundwaters are generally Ca–Mg–HCO3 and Mg–Ca–HCO3 types with bicarbonate (HCO3 ) as the dominant anion, though the other type of water has also been observed. Dissolved arsenic in groundwater ranged from 0.006 to 0.461 mg/l, with 69% groundwater samples exceeded the Bangladesh limit for safe drinking water (0.05 mg/l). Correlation and principal component analysis have been performed to find out possible relationships among the examined parameters in groundwater. Low concentrations of NO3 and SO4 2−, and high concentrations of DOC, HCO3 and PO4 3− indicate the reducing condition of subsurface aquifer where sediments are deposited with abundant organic matter. Distinct relationship of As with Fe and Mn, and strong correlation with DOC suggests that the biodegradation of organic matter along with reductive dissolution of Fe–Mn oxyhydroxides has being considered the dominant process to release As in the aquifers studied herein.  相似文献   
22.
The Straits of Malacca is subjected to a great variety of environmental stresses due to its strategic location as a major international shipping lane and the concentration of agriculture, industry and urbanisation which predominate on the west coast of Peninsular Malaysia. This paper gives an overview of the study conducted in the Malacca Straits as part of the GEF/UNDP/IMO Regional Programme on the Prevention and Management of Marine Pollution in the East Asian Seas, in particular pertaining to the identification of land and sea-based sources of pollution in Malaysia which contributes to the pollution load in the Straits, as well as the assessment of the relative contribution of each source.  相似文献   
23.
The Strait of İstanbul (SoI) (Bosphorus) is a narrow valley, which has evolved tectonically from a stream, and in which thick sediment deposits have accumulated in the course of its evolution. Detailed seismic and multi-beam bathymetric data have revealed that the upper parts of the deeper channel deposits consist of parallel strata, which have mostly been eroded subsequently to their deposition. The resulting erosion surface is represented by the present channel floor in the strait, the estimated volume of the eroded material being approximately 2×108 m3 . Erosion rate and seafloor morphology indicate that the flow direction was from the south to the north. This inner channel may have been formed by an abrupt flooding of the Black Sea by Mediterranean waters at the beginning of the latest connection between the Marmara and the Black seas. Subsequently, the Mediterranean bottom current of the modern two-way flow system, which was established at about 5–4 ka b.p., has given the latest shape to the strait floor.  相似文献   
24.
We investigate the helium, carbon and oxygen–hydrogen isotopic systematics and CO2/3He ratios of 8 water and 6 gas samples collected from 12 geothermal fields in western Anatolia (Turkey). 3He/4He ratios of the samples (R) normalized to the atmospheric 3He/4He ratio (RA = 1.39 × 10? 6) range from 0.27 to 1.67 and are significantly higher than the crustal production value of 0.05. Fluids with relatively high R / RA values are generally found in areas of significant heat potential (K?z?ldere and Tuzla fields). CO2/3He ratios of the samples, ranging from 1.6 × 109 to 2.3 × 1014, display significant variation and are mostly higher than values typical of an upper mantle source (2 × 109). The δ13C (CO2) and δ13C (CH4) values of all fluids vary from ? 8.04 to + 0.35‰ and ? 25.80 to ? 23.92‰ (vs. PDB), respectively. Stable isotope values (δ18O–δD) of the geothermal waters are conformable with the Mediterranean Meteoric Water Line and indicate a meteoric origin. The temperatures calculated by gas geothermometry are significantly higher than estimates from chemical geothermometers, implying that either equilibrium has not been attained for the isotope exchange reaction or that isotopic equilibration was disturbed due to gas additions en route to the surface.Evaluation of He–CO2 abundances indicates that hydrothermal degassing and calcite precipitation (controlled probably by adiabatic cooling due to degassing) significantly fractionate the elemental ratio (CO2/3He) in geothermal waters. Such processes do not affect gas phase samples to anywhere near the same extent. For the gas samples, mixing between mantle and various crustal sources appears to be the main control on the observed He–C systematics: however, crustal inputs dominate the CO2 inventory. Considering that limestone is the main source of carbon (~ 70 to 97% of the total carbon inventory), the carbon flux from the crust is found to be at least 20 times that from the mantle. As to the He-inventory, the mantle-derived component is found to vary up to 21% of the total He content and is probably transferred to the crust by fluids degassed from deep mantle melts generated in association with the elevated geotherm and adiabatic melting accompanying current extension. The range of 3He/enthalpy ratios (0.000032 to 0.19 × 10? 12 cm3 STP/J) of fluids in western Anatolia is consistent with the release of both helium and heat from contemporary additions of mantle-derived magmas to the crust. The deep faults appear to have facilitated the deep circulation of the fluids and the transport of mantle volatiles and heat to the surface.  相似文献   
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26.
A genetic algorithm rainfall intensity (GARI) model has been developed and used to predict the intensities for given return period. It is a one‐step solution procedure that may not require any mathematical transformation. The problem formulation is given and the genetic algorithm solution of the problem is presented. The results show that the proposed GARI model can be used to solve the rainfall intensity–duration–frequency relations with lowest mean‐squared error between measured and predicted intensities. Predicted intensities are in good agreement between measured and predicted values for given return periods. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
27.
Trace metals were analyzed in water and sediment samples from Barapukuria coal mine area of Bangladesh in order to evaluate their mobility and possible environment consequences. Cadmium is the most mobile element with an average partition coefficient (log K d ) of 2.95 L/kg, while V is the least mobile element with a mean log K d of 5.50 L/kg, and their order of increasing mobility is: V < As < Pb < Fe < Cr < Se < Mn < Ni < Zn < Cu < Ba < Sr < Cd. Contents of organic carbon in sediment samples shows strong positive correlations with most trace metals as revealed by the multivariate geostatistical analysis. The overall variation in concentration is mainly attributed to the discharge of effluents originating from the coal mining activities around the study area. Compared to their background, Ni and Cu are the most enriched while significant enrichment of As, Mn, Ba, Sr, Cr, and Pb is also observed in the sediments. Geoaccumulation indices (I geo ) suggest sediments are moderately to heavily polluted with respect to Ni and Cu. The metal pollution index (MPI) varied from 91.91 to 212.01 and the highest value is found at site CM03 that is close to discharge point. The sediment quality guideline index (SQG-I Intervention ) values (0.56–1.52) suggest that the sediments at the study area have moderate to high ecotoxicological risk.  相似文献   
28.
Various hydrological and meteorological variables such as rainfall and temperature have been affected by global climate change. Any change in the pattern of precipitation can have a significant impact on the availability of water resources, agriculture, and the ecosystem. Therefore, knowledge on rainfall trend is an important aspect of water resources management. In this study, the regional annual and seasonal precipitation trends at the Langat River Basin, Malaysia, for the period of 1982–2011 were examined at the 95 % level of significance using the regional average Mann–Kendall (RAMK) test and the regional average Mann–Kendall coupled with bootstrap (RAMK–bootstrap) method. In order to identify the homogeneous regions respectively for the annual and seasonal scales, firstly, at-site mean total annual and separately at-site mean total seasonal precipitation were spatialized into 5 km?×?5 km grids using the inverse distance weighting (IDW) algorithm. Next, the optimum number of homogeneous regions (clusters) is computed using the silhouette coefficient approach. Next, the homogeneous regions were formed using the K-mean clustering method. From the annual scale perspective, all three regions showed positive trends. However, the application of two methods at this scale showed a significant trend only in the region AC1. The region AC2 experienced a significant positive trend using only the RAMK test. On a seasonal scale, all regions showed insignificant trends, except the regions I1C1 and I1C2 in the Inter-Monsoon 1 (INT1) season which experienced significant upward trends. In addition, it was proven that the significance of trends has been affected by the existence of serial and spatial correlations.  相似文献   
29.
A new look is focused in this study on the analysis of mean temperatures for Bahrain, as observed at its International Airport for the 59 years extending from 1947 to 2005. The temporal trends indicate significant warming of the dry-season temperatures of 0.166°C decade?1. In particular, the summer months of May to July and October demonstrate statistically significant trends of 0.172 to 0.247°C decade?1. There is a tendency for the wet season months to show both decreases and increases in their temperatures though the temporal trends are not significant. The decade of 1991-2000 emerged as a period of conspicuous warming as well as increase in the occurrence of unusual mean temperatures and the number of months per year with above-average temperature. No significant trend in intraannual and intraseasonal temperature variabilities is discerned, but the wet season shows predominantly higher within-season variability in temperatures as compared to the dry season. Further analyses have been carried out on the available extreme temperature data for the period 1981-2005 in an attempt to search for a possible source of climatic and/or non-climatic factors, such as intensifying desertification and rapid urbanization. By and large, the rates of diurnal temperature ranges have increased due to significantly higher rates of increasing maximum in comparison to increasing minimum temperatures. The warming rate of the overall dry season during the day is seven times that during night. However, the nocturnal temperature for the overall wet season has warmed significantly at a rate more than three times that of the overall dry season. There is a sufficient evidence that sources of rapid urbanization around the area of records seem to be a major contributor to the observed rates of temperature. Both the urbanization and the effect of the large water body of the Gulf surrounding the Island of Bahrain seem to have offset the effect of desertification on temperature changes.  相似文献   
30.
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