Natural Biological Attenuation of Benzene in Ground Water Beneath a Manufacturing Facility   总被引：2，自引：0，他引：2  

John W. Davis  Nancy J. Klier  Constance L. Carpenter 《Ground water》1994,32(2):215-226

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Gases and water isotopes in a geochemical section across the Larderello,Italy, geothermal field     

Alfred H. Truesdell  Nancy L. Nehring 《Pure and Applied Geophysics》1978,117(1-2):276-289

Steam samples from six wells (Colombaia, Pineta, Larderello 57, Larderello 155, Gabbro 6, and Gabbro 1) in a south to north section across the Larderello geothermal field have been analyzed for inorganic and hydrocarbon gases and for oxygen-18 and deuterium of steam. The wells generally decrease in depth and increase in age toward the south. The steam samples are generally characterized by

1. Total gas contents increasing south to north from 0.003 to 0.05 mole fraction;
2. Constant CO₂ (95±2 percent); near constant H₂S (1.6±0.8), N₂ (1.2±0.8), H₂ (2±1), CH₄ (1.2±1), and no O₂ in the dry gas;
3. Presence of numerous, straight chain and branched C₂ to C₆ hydrocarbons plus benzene in amounts independent of CH₄ contents with highest concentrations in the deeper wells;
4. Oxygen-18 contents of steam increasing south to north from ?5.0‰ to ?0.4‰ with little change in deuterium (?42±2‰).

These observations are interpreted as showing:

1. Decreasing gas contents with amount of production because the proportion of steam boiled from liquid water increases with production;
2. Synthesis of CH₄ from H₂ and CO₂ with CO₂ and H₂ produced by thermal metamorphism and rock-water reactions;
3. Extraction of C₂ to C₆ hydrocarbons from rock organic matter;
4. Either oxygen isotope exchange followed by distillation of steam from the north toward the south (2 plates at ～220°C) or mixture of deeper more-exchange waters from the north with shallow, less-exchanged recharging waters from the south.

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Regional investigations of vertical crustal movements in the U.S., using precise relevelings and mareograph data     

Sandford R. Holdahl  Nancy L. Morrison 《Tectonophysics》1974,23(4):373-390

In the past two years, the National Geodetic Survey has been creating a data base of vertical crustal movement information. The data elements are relative elevation changes along lines of releveling which are used to produce graphic displays on microfilm. In separate studies, the releveling data, together with information extracted from mareograph records, have been used to create two networks of velocity differences. The two networks, one in the vicinity of Chesapeake Bay and the other covering the Gulf Coast states, have been adjusted in order to prepare maps showing the velocities of elevation change. In the adjustments, the velocities derived from mareograph records were treated as observations. The results indicate annual subsidence ranging between −1.2 mm and −4.0 mm in the Chesapeake Bay area, with significant local variation. In the Gulf Coast region there is generally slight subsi'dence along the coast, ranging between 0.0 and −1.5 mm/year. Stability and slight uplift is indicated to the north where bedrock reaches the terrain surface. Anomalous subsidence of −7.0 mm/year occurs at New Orleans, La., and at Houston, Texas, there has been several decimeters change in the last ten years.  相似文献   

The importance of grain size and shape in controlling the dispersion of the Vedde cryptotephra     

Jennifer Saxby  Alison Rust  Katharine Cashman  Frances Beckett 《第四纪科学杂志》2020,35(1-2):175-185

Volcanic ash is dispersed in the atmosphere according to meteorology and particle properties, including size and shape. However, the multiple definitions of size and shape for non-spherical particles affect our ability to use physical particle properties to understand tephra transport. Moreover, although particles are often excluded from operational ash dispersion model setups, ash in tephra deposits 1000 km from source can exceed . Here we measure the shape and size of samples of Vedde ash from Iceland, an exceptionally widespread tephra layer in Europe, collected in Iceland and Norway. Using X-ray computed tomography and optical microscopy, we show that distal ash is more anisotropic than proximate ash, suggesting that shape exerts an important control on tephra dispersion. Shape also impacts particle size measurements. Particle long axis, a parameter often reported by tephrochronologists, is on average greater than geometric size, used by dispersion modellers. By using geometric size and quantifying shape, we can explain the transport of Vedde ash particles more than 1200 km from source. We define a set of best practices for measuring the size and shape of cryptotephra shards and discuss the benefits and limitations of using physical particle properties to understand cryptotephra transport.  相似文献   

Chemical equilibrium model of solution behavior and solubility in the H-Na-K-OH-Cl-HSO₄-SO₄-H₂O system to high concentration and temperature     

Christomir Christov  Nancy Moller 《Geochimica et cosmochimica acta》2004,68(6):1309-1331

This paper describes a chemical model that calculates solute and solvent activities and solid-liquid equilibria in the H-Na-K-OH-Cl-HSO₄-SO₄-H₂O system from dilute to high solution concentration within the 0° to 250°C temperature range. All binary and ternary subsystems are included in the model parameterization. The model is validated by comparing predictions with experimental data, primarily in higher order systems, not used in the parameterization process. Limitations of the model due to data insufficiencies are discussed.The Harvie and Weare (GCA44, 981, 1980) solubility modeling approach, incorporating their implementation of the concentration-dependent specific interaction equations of Pitzer (J. Phys. Chem.77, 268, 1973), is employed. This model expands the variable temperature Na-K-Cl-SO₄-H₂O model of Greenberg and Moller (GCA53, 2503, 1989) by including acid (H₂SO₄, HCl) and base (NaOH, KOH) species. Temperature functions for the chemical potentials of 5 acidic (sodium bisulfate, sodium sesquisulfate, mercallite, potassium sesquisulfate and misenite) and 6 basic (4 sodium hydroxide hydrates and 2 potassium hydroxide hydrates) solid phases are determined.  相似文献   

Effect of iron type on kinetics and carbon isotopic enrichment of chlorinated ethylenes during abiotic reduction on Fe(0)     

VanStone NA  Focht RM  Mabury SA  Lollar BS 《Ground water》2004,42(2):268-276

Four samples of two commercially available iron brands used as substrate for iron permeable reactive barriers (PRBs) were tested for suitability for remediation of perchloroethylene (PCE), trichloroethylene (TCE), cis-dichloroethylene (cDCE) and vinyl chloride (VC). Kinetic studies indicate that rates of reaction are enhanced for cDCE and VC on Connelly iron (2.8 x 10(-4) to 6.9 x 10(-4) L/m2/hr and 2.0 x 10(-4) to 9.0 x 10(-4) L/m2/hr, for cDCE and VC, respectively) vs. Peerless iron (3.1 x 10(-5) to 4.6 x 10(-5) L/m2/hr and 2.4 x 10(-5) to 4.1 x 10(-5) L/m2/hr, for cDCE and VC, respectively). Carbon isotopic analyses of the residual chlorinated ethylene (CE) during degradation indicate significant fractionation occurs during reductive dechlorination, with, for example, up to 70% enrichment in carbon isotopic values observed when VC is more than 99% degraded. Comparison of fractionation factors (epsilon) indicates significant differences in carbon isotopic fractionation for different iron types and for different CEs. For the lower CEs (cDCE and VC) in particular, both slower reaction rates and larger fractionation are observed for degradation on Peerless vs. Connelly iron. This is the first study to establish a correlation between the rate of abiotic degradation on Fe(0) and the extent of isotopic fractionation, and the first to confirm consistent differences in these two parameters as a function of iron type. The possibility that these differences in kinetics and carbon isotopic fractionation for cDCE and VC are related to differences in branching ratios between competing hydrogenolysis and beta-elimination reactions during reductive dechlorination on the iron surfaces is discussed.  相似文献   

Planning for El Niño: The Stages of Natural Hazard Mitigation and Preparation*     

Nancy Beller‐Simms 《The Professional geographer》2004,56(2):213-222

This study examines mitigation and preparation activities selected by four county and state governments in anticipation of the 1997–1998 El Niño. It expands the knowledge of how state and local governments plan short‐term projects and mitigate with longer‐term activities in anticipation of a natural hazard. It also provides a preliminary understanding of divergent responses and plans under similar disaster warnings. It outlines stages that governments follow in determining their natural hazard mitigation and preparedness activities. This model should provide hazard planners, particularly those planning for slower onset hazards, with insights into their own local circumstances, allowing them to choose appropriate strategies.  相似文献   

Habitat requirements for submerged aquatic vegetation in Chesapeake Bay: Water quality, light regime, and physical-chemical factors   总被引：1，自引：0，他引：1  

W. Michael Kemp  Richard Batleson  Peter Bergstrom  Virginia Carter  Charles L. Gallegos  William Hunley  Lee Karrh  Evamaria W. Koch  Jurate M. Landwehr  Kenneth A. Moore  Laura Murray  Michael Naylor  Nancy B. Rybicki  J. Court Stevenson  David J. Wilcox 《Estuaries and Coasts》2004,27(3):363-377

We developed an algorithm for calculating habitat suitability for seagrasses and related submerged aquatic vegetation (SAV) at coastal sites where monitoring data are available for five water quality variables that govern light availability at the leaf surface. We developed independent estimates of the minimum light required for SAV survival both as a percentage of surface light passing though the water column to the depth of SAV growth (PLW _min) and as a percentage of light reaching reaching leaves through the epiphyte layer (PLL _min). Value were computed by applying, as inputs to this algorithm, statistically dervived values for water quality variables that correspond to thresholds for SAV presence in Chesapeake Bay. These estimates ofPLW _min andPLL _min compared well with the values established from a literature review. Calcultations account for tidal range, and total light attenuation is partitioned into water column and epiphyte contributions. Water column attenuation is further partitioned into effects of chlorophylla (chla), total suspended solids (TSS) and other substances. We used this algorithm to predict potential SAV presence throughout the Bay where calculated light available at plant leaves exceededPLL _min. Predictions closely matched results of aerial photographic monitoring surveys of SAV distribution. Correspondence between predictions and observations was particularly strong in the mesohaline and polythaline regions, which contain 75–80% of all potential SAV sites in this estuary. The method also allows for independent assessment of effects of physical and chemical factors other than light in limiting SAV growth and survival. Although this algorithm was developed with data from Chesapeake Bay, its general structure allows it to be calibrated and used as a quantitative tool for applying water quality data to define suitability of specific sites as habitats for SAV survival in diverse coastal environments worldwide.  相似文献   

Cusp geometry in MHD simulations   总被引：2，自引：0，他引：2  

George Siscoe  Nancy Crooker  Keith Siebert  Nelson Maynard  Daniel Weimer  Willard White 《Surveys in Geophysics》2005,26(1-3):387-407

The MHD simulations described here show that the latitude of the high-altitude cusp decreases as the IMF swings from North to South, that there is a pronounced dawn–dusk asymmetry at high-altitude associated with a dawn–dusk component of the IMF, and that at the same time there is also a pronounced dawn–dusk asymmetry at low-altitude. The simulations generate a feature that represents what has been called the cleft. It appears as a tail (when the IMF has a B_y component) attached to the cusp, extending either toward the dawn flank or the dusk flank depending on the dawn–dusk orientation of the IMF. This one-sided cleft connects the cusp to the magnetospheric sash. We compare cusp geometry predicted by MHD simulations against published observations based on Hawkeye and DMSP data. Regarding the high-altitude predictions, the comparisons are not definitive, mainly because the observations are incomplete or mutually inconsistent. Regarding the low-altitude prediction of a strong dawn–dusk asymmetry, the observations are unambiguous and are in good qualitative agreement with the prediction.  相似文献   

Conditions of core formation in the earth: Constraints from Nickel and Cobalt partitioning     

Nancy L. Chabot 《Geochimica et cosmochimica acta》2005,69(8):2141-2151

The abundances of Ni and Co in the Earth’s mantle are depleted relative to chondrites due to terrestrial core formation. Recently, the observed mantle depletions of these elements have been explained by liquid metal-liquid silicate equilibrium during core formation in a high pressure, high temperature magma ocean on the early Earth. However, different magma ocean models, which would be expected to give consistent results, have proposed vastly different pressures (24 to 59 GPa), temperatures (2200 to >4000 K) and oxygen fugacities (−0.15 to −2.4 ΔIW) for the Earth’s magma ocean. In an attempt to resolve the contradictory results from different magma ocean models and determine the thermodynamic conditions appropriate for core formation in the Earth, experiments were conducted to better constrain the influences of temperature and C on the partitioning behaviors of Ni and Co. Results of experiments at 7 GPa with temperatures of 1923-2673 K show that the metal-silicate partition coefficients for both Ni and Co decrease with increasing temperature, with the effect being more significant for Ni. Little change in the partitioning behaviors of either Ni or Co with varying C-content of the metallic liquid was found. By combining the new temperature data with previous results from pressure and oxygen fugacity studies, we parameterized the partitioning behavior of Ni and Co and applied the parameterizations to core formation in a terrestrial magma ocean. Multiple combinations of pressure, temperature, and oxygen fugacity can explain the observed mantle depletions of Ni and Co, and all of the very different previously proposed magma ocean conditions are generally consistent with valid solutions. By using the FeO content of the Earth’s mantle as an additional constraint on the oxygen fugacity, magma ocean conditions of 30-60 GPa, > 2000 K, and −2.2 ΔIW are suggested. Similar systematic approaches and studies of other moderately siderophile elements could further constrain the magma ocean conditions on the early Earth.  相似文献