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991.
Pesticide residues in ground water of the San Joaquin Valley, California   总被引:1,自引:0,他引:1  
A regional assessment of non-point-source contamination of pesticide residues in ground water was made of the San Joaquin Valley, an intensively farmed and irrigated structural trough in central California. About 10% of the total pesticide use in the USA is in the San Joaquin Valley. Pesticides detected include atrazine, bromacil, 2.4-DP, diazinon, dibromochloropropane, 1,2-dibromoethane, dicamba, 1,2-dichloropropane, diuron, prometon, prometryn, propazine and simazine. All are soil applied except diazinon.

Pesticide leaching is dependent on use patterns, soil texture, total organic carbon in soil, pesticide half-life and depth to water table. Leaching is enhanced by flood-irrigation methods except where the pesticide is foliar applied such as diazinon. Soils in the western San Joaquin Valley are fine grained and are derived primarily from marine shales of the Coast Ranges. Although shallow ground water is present, the fewest number of pesticides were detected in this region. The fine-grained soil inhibits pesticide leaching because of either low vertical permeability or high surface area; both enhance adsorption on to solid phases. Soils of the valley floor tend to be fine grained and have low vertical permeability. Soils in the eastern part of the valley are coarse grained with low total organic carbon and are derived from Sierra Nevada granites. Most pesticide leaching is in these alluvial soils, particularly in areas where depth to ground water is less than 30m. The areas currently most susceptible to pesticide leaching are eastern Fresno and Tulare Counties.

Tritium in water molecules is an indicator of aquifer recharge with water of recent origin. Pesticide residues transported as dissolved species were not detected in non-tritiated water. Although pesticides were not detected in all samples containing high tritium, these samples are indicative of the presence of recharge water that interacted with agricultural soils.  相似文献   

992.
The orientation of the straight internal foliation Si within large ( 5 mm) garnet porphyroblasts has been measured relative to the orientation of the external foliation Se around a single antiform of 0.5 m wavelength, which folds the dominant regional foliation. The internal foliation is not constant in orientation, but varies consistently both with position around the fold and with the porphyroblast ellipticity. The dip of Si (hinge dip taken as zero) is consistently less than the dip of Se; it increases with increasing dip of Se and with increasing ellipticity of the porphyroblasts. Si effectively defines a fold with an opening angle greater than that in the external foliation. The opening angle of this fold in Si decreases with increasing porphyroblast ellipticity. The observed variation in the orientation of Si can be explained qualitatively by a flattened flexural flow model for fold development, as could be expected for folding of a pre-existing, strongly anisotropic foliation. The measurements clearly demonstrate that rotation of porphyroblasts relative to geographical co-ordinates did occur during the development of this fold and that a model based on the classical theories of rotation of stiff inclusions in a weaker viscous matrix is most appropriate.  相似文献   
993.
Trace-Organics Biodegradation in Aquifer Recharge   总被引:1,自引:0,他引:1  
  相似文献   
994.
995.
The components of the NRM in Middle Siwalik red beds are carried by two phases of hematite, a red pigment phase and a specular hematite phase. We present evidence in the form of a conglomerate test that the specularite phase carries a remanence acquired during or shortly after deposition. The red pigment, however, post-dates deposition, in many cases by at least one reversal boundary. This secondary component has a higher coercivity but a lower blocking temperature in these rocks and can therefore be selectively removed by thermal demagnetization to reveal a primary magnetization useful for magnetostratigraphic studies.  相似文献   
996.
Hot springs and steam vents on the slopes of Nevado del Ruiz volcano provide evidence regarding the nature of hydrothermal activity within the summit and flanks of the volcano. At elevations below 3000 m, alkali-chloride water is discharged from two groups of boiling springs and several isolated warm springs on the western slope of Nevado del Ruiz. Chemical and isotopic geothermometers suggest that the boiling springs are fed by an aquifer having a subsurface equilibration temperature of at least 175°C, and the sampled warm spring is fed by an aquifer having a subsurface equilibration temperature near 150°C. Similarities in conservative solute ratios (e.g., B/Cl) indicate that the alkali-chloride waters may be related to a single reservoir at depth. Isotopic ratios of hydrogen and oxygen indicate that recharge for the alkali-chloride aquifers comes mostly from higher elevations on the volcano. Steam vents and steam-heated bicarbonate-sulfate springs at higher elevations, along a linear structural trend with the alkali-chloride springs, may be derived partly from the alkali-chloride water at depth by boiling. Steam from the vents (84°C) yields a gas geothermometer temperature of 209°C. Acid-sulfate-chloride and acid-sulfate waters are discharged widely from warm springs above 3000 m on the northern and eastern slopes of Nevado del Ruiz. Similarities in B/Cl and SO4/Cl ratios suggest that the acid waters are mixtures of water from an acid-sulfate-chloride reservoir with various proportions of shallow, dilute groundwater. The major source of sulfate, halogens, and acidity for the acid waters may be high-temperature magmatic gases. Available data on hot spring temperatures and compositions indicate that they have remained fairly stable since 1968. However, the eruption of November 13, 1985 apparently caused an increase in sulfate concentration in some of the acid springs that peaked about a year after the eruption. Long-term monitoring of hot spring compositions over many years will be required to better define the effects of volcanic activity on the Nevado del Ruiz hydrothermal system.  相似文献   
997.
This review of experimental work on the formation of sulphide ores shows how the development of geological thought on the genesis of these deposits influenced the direction of these investigations. The experimental work to date emphasises the necessity for the chemist and the physical chemist to work together with the geologist so that the complex processes that contribute to the formation of a metal sulphide deposit may be defined and their individual roles evaluated.
Zusammenfassung Diese Zusammenfassung von Arbeiten über die Bildung sulfidischer Erze zeigt, wie die Entwicklung geologischen Denkens die Forschungen über die Genese der Vorkommen beeinflußte. Moderne Experimentalarbeiten lassen die Notwendigkeit erkennen, daß Chemiker und Physiko-Chemiker mit den Geologen zusammenarbeiten müssen, damit die komplizierten Prozesse, die zur Bildung sulfidischer Ablagerungen führten, geklärt und ihre Einzelheiten verstanden werden können.


Published by permission of the Director, Bureau of Mineral Resources, Geology and Geophysics, Canberra, Australia.  相似文献   
998.
This study addresses gaps in understanding the relative roles of sea‐level change, coastal geomorphology and sediment availability in driving beach erosion at the scale of individual beaches. Patterns of historical shoreline change are examined for spatial relationships to geomorphology and for temporal relationships to late‐Holocene and modern sea‐level change. The study area shoreline on the north‐east coast of Oahu, Hawaii, is characterized by a series of kilometre‐long beaches with repeated headland‐embayed morphology fronted by a carbonate fringing reef. The beaches are the seaward edge of a carbonate sand‐rich coastal strand plain, a common morphological setting in tectonically stable tropical island coasts. Multiple lines of geological evidence indicate that the strand plain prograded atop a fringing reef platform during a period of late‐Holocene sea‐level fall. Analysis of historical shoreline changes indicates an overall trend of erosion (shoreline recession) along headland sections of beach and an overall trend of stable to accreting beaches along adjoining embayed sections. Eighty‐eight per cent of headland beaches eroded over the past century at an average rate of ?0·12 ± 0·03 m yr?1. In contrast, 56% of embayed beaches accreted at an average rate of 0·04 ± 0·03 m yr?1. Given over a century of global (and local) sea‐level rise, the data indicate that embayed beaches are showing remarkable resiliency. The pattern of headland beach erosion and stable to accreting embayments suggests a shift from accretion to erosion particular to the headland beaches with the initiation of modern sea‐level rise. These results emphasize the need to account for localized variations in beach erosion related to geomorphology and alongshore sediment transport in attempting to forecast future shoreline change under increasing sea‐level rise.  相似文献   
999.
This introductory paper lays the basis for this supplementary issue by briefly presenting the state of knowledge on the KwaZulu-Natal (KZN) Bight at the start of this multi-disciplinary, multi-institutional, ship-based research project that ran from 2009 to 2013. The rationale and aims of the project are also described. The project was a major component of the South African Department of Science and Technology’s African Coelacanth Ecosystem Programme (ACEP), which has been prominent in supporting research on the east coast of South Africa and the wider South-West Indian Ocean. Pivotal to this was the RS Algoa, which was made available for two 30-day surveys (winter and summer) in the KZN Bight by the Department of Environmental Affairs. Although some aspects of the bight ecology are known, much of the research is dated and fragmented, and required refreshing and consolidation in order to produce a platform upon which the understanding of the region’s ecosystem functioning could be established. Much of the oceanographic knowledge is also dated, with no dedicated surveys and significant measurements undertaken since 1989. The overarching theme of the KZN Bight project was to examine the relative importance of sources of nutrients to the central KZN coast and how these are taken up and recycled in the ecosystem, and to describe aspects of the benthic biodiversity, which is poorly described in much of this region. An ambitious project, its accessibility to a ship-based research platform and the diverse scientific skills of the participating scientists allowed considerable success, as reflected in the papers that follow.  相似文献   
1000.
Global change is expected to result in worldwide increases in temperature and alteration of rainfall patterns. Such changes have the potential to modify stability of slopes, both natural and constructed. This paper discusses the potential effect of global climate change on reactivation of landslides through examination of predicted changes in rainfall pattern on the active landslide at Mam Tor, Derbyshire, UK. This landslide is of Pleistocene origin and is crossed by a road that is now abandoned. Damaging winter movement is known to occur when precipitation reaches both 1-month triggering and 6-month antecedent thresholds. Return periods for threshold exceedence is modelled statistically, and the climate change data from the UKCIP 2002 report (Hulme et al. 2002) is applied to this model. For the predicted changes in precipitation, it is shown that the instability threshold could decrease from 4 to 3.5 years by the 2080s for the medium–high climate change scenario. However, predicted temperature changes could influence the response of the landslide through increased evapotranspiration leading to a change in the triggering precipitation thresholds, and this will help counter the impact of changes in precipitation. Analysis of sources of uncertainty in the model has been used to establish the factors that contribute to the predicted changes in stability. Assessment of these factors can provide an indication of the potential impact of climate change on landslides in other areas of the UK.  相似文献   
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