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141.
Regional metamorphic zones, based on mineral assemblages in pelites, are presented for the Dalradian rocks of Aberdeenshire and Banffshire, in the type area of Buchan metamorphism; electron microprobe analyses of cordierite (C), staurolite (S), chlorite (Chl), biotite (B) and white mica (Ms) are reported for rocks from the classic sections of the Banffshire coast and the valley of the Ythan.A low grade biotite zone, separates two NE-SW trending sets of higher grade zones, in which the sequence s defined by the entry of cordierite, andalusite (A) and (in the west only) staurolite. The zones are characterised by the assemblages (with quartz and muscovite) B-Chl, C-B-Chl, A-C-B and S-A-B.The western sequence contains a transition towards higher pressure, Barrovian type, metamorphism. The isograds arise from continuous reactions affecting rocks of restricted bulk composition (M/FM). With increasing grade, there is a regular trend towards more magnesian ranges of composition for the assemblages C-B-Chl, A-C-B and finally (as P increases in the west), S-A-B. The isograds form when these assemblages intersect the most Fe++-rich rock compositions present which occurs in each case when the biotite M/FM=40. A complex of divariant equilibria, derived for the system KFMASH, is used to model the natural reactions.  相似文献   
142.
The effects of applied filtration vacuum and incubation time on the release of dissolved organic carbon (DOC) by natural phytoplankton populations dominated by diatoms were examined. The rate of primary production and release of DOC remained reasonably constant during a 5 hour incubation period. The measured release of DOC was found to be quite sensitive to the applied filtration vacuum, ranging from near 2 percent of fixed carbon (neglecting respiration) for gravity-filtered samples to 36 percent for samples filtered at 40 cm Hg vacuum.  相似文献   
143.
Polycyclic aromatic hydrocarbons (PAH) in sediment cores from Lake Lucerne, Lake Zürich, and Greifensee, Switzerland, and Lake Washington, northwest U.S.A., have been isolated, identified and quantified by glass capillary gas chromatography and gas chromatography/mass spectrometry. Surface sediment layers are greatly enriched in PAH—up to 40 times—compared to deeper layers. In addition, concentration increases in upper sediments generally correspond to increasing industrialization and urbanization in the catchment basins of the lakes. Few PAH could be detected in pre-industrial revolution sediments, indicating that background levels for most PAH in aquatic sediments are extremely low.These results are consistent with an anthropogenic source for most of the aromatic hydrocarbons present in the modern sediments. A comparison of PAH distributions in the sediments and in possible source materials shows that urban runoff of street dust may be the most important PAH input to these lacustrine sediments. There is evidence that a significant contribution to the PAH content of street dust comes from material associated with asphalt.  相似文献   
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The extent of hydrogen and oxygen isotope exchange between clay minerals and water has been measured in the temperature range 100–350° for bomb runs of up to almost 2 years. Hydrogen isotope exchange between water and the clays was demonstrable at 100°. Exchange rates were 3–5 times greater for montmorillonite than for kaolinite or illite and this is attributed to the presence of interlayer water in the montmorillonite structure.Negligible oxygen isotope exchange occurred at these low temperatures. The great disparity in D and O18 exchange rates observed in every experiment demonstrates that hydrogen isotope exchange occurred by a mechanism of proton exchange independent of the slower process of O18 exchange.At 350° kaolinite reacted to form pyrophyllite and diaspore. This was accompanied by essentially complete D exchange but minor O18 exchange and implies that intact structural units in the pyrophyllite were inherited from the kaolinite precursor.  相似文献   
146.
Hydrocarbon distribution in sediments from three lakes are related to the level of human activity in the respective drainage basins. Petroleum hydrocarbon contamination is found in surface sediments of a lake surrounded by a major city, compared to no detectable contamination in a lake located in a National Park.  相似文献   
147.
We have analyzed the effects that differential rotation and a hypothetical meridional flow would have on the evolution of the Sun's mean line-of-sight magnetic field as seen from Earth. By winding the large-scale field into strips of alternating positive and negative polarity, differential rotation causes the mean-field amplitude to decay and the mean-field rotation period to acquire the value corresponding to the latitude of the surviving unwound magnetic flux. For a latitudinally broad two-sector initial field such as a horizontal dipole, the decay is rapid for about 5 rotations and slow with a t –1/2 dependence thereafter. If a poleward meridional flow is present, it will accelerate the decay by carrying the residual flux to high latitudes where the line-of-sight components are small. The resulting decay is exponential with an e-folding time of 0.75 yr (10 rotations) for an assumed 15 m s–1 peak meridional flow speed.E.O. Hulburt Center for Space Research.Laboratory for Computational Physics.  相似文献   
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