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The ocean and atmosphere were largely anoxic in the early Precambrian, resulting in an Fe cycle that was dramatically different than today’s. Extremely Fe-rich sedimentary deposits—i.e., Fe formations—are the most conspicuous manifestation of this distinct Fe cycle. Rare Earth Element (REE) systematics have long been used as a tool to understand the origin of Fe formations and the corresponding chemistry of the ancient ocean. However, many earlier REE studies of Fe formations have drawn ambiguous conclusions, partially due to analytical limitations and sampling from severely altered units. Here, we present new chemical analyses of Fe formation samples from 18 units, ranging in age from ca. 3.0 to 1.8 billion years old (Ga), which allow a reevaluation of the depositional mechanisms and significance of Precambrian Fe formations. There are several temporal trends in our REE and Y dataset that reflect shifts in marine redox conditions. In general, Archean Fe formations do not display significant shale-normalized negative Ce anomalies, and only Fe formations younger than 1.9 Ga display prominent positive Ce anomalies. Low Y/Ho ratios and high shale-normalized light to heavy REE (LREE/HREE) ratios are also present in ca. 1.9 Ga and younger Fe formations but are essentially absent in their Archean counterparts. These marked differences in Paleoproterozoic versus Archean REE + Y patterns can be explained in terms of varying REE cycling in the water column.Similar to modern redox-stratified basins, the REE + Y patterns in late Paleoproterozoic Fe formations record evidence of a shuttle of metal and Ce oxides across the redoxcline from oxic shallow seawater to deeper anoxic waters. Oxide dissolution—mainly of Mn oxides—in an anoxic water column lowers the dissolved Y/Ho ratio, raises the light to heavy REE ratio, and increases the concentration of Ce relative to the neighboring REE (La and Pr). Fe oxides precipitating at or near the chemocline will capture these REE anomalies and thus evidence for this oxide shuttle. In contrast, Archean Fe formations do not display REE + Y patterns indicative of an oxide shuttle, which implies an absence of a distinct Mn redoxcline prior to the rise of atmospheric oxygen in the early Paleoproterozoic. As further evidence for reducing conditions in shallow-water environments of the Archean ocean, REE data for carbonates deposited on shallow-water Archean carbonate platforms that stratigraphically underlie Fe formations also lack negative Ce anomalies. These results question classical models for deposition of Archean Fe formations that invoke oxidation by free oxygen at or above a redoxcline. In contrast, we add to growing evidence that metabolic Fe oxidation is a more likely oxidative mechanism for these Fe formations, implying that the Fe distribution in Archean oceans could have been controlled by microbial Fe uptake rather than the oxidative potential of shallow-marine environments.  相似文献   
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As sediment accumulation indicates basin subsidence, erosion often is understood as tectonic uplift, but the amplitude and timing may be difficult to determine because the sedimentary record is missing. Quantification of erosion therefore requires indirect evidence, for example thermal indicators such as temperature, vitrinite reflectance and fission tracks in apatite. However, as always, the types and quality of data and the choice of models are important to the results. For example, considering only the thermal evolution of the sedimentary section discards the thermal time constant of the lithosphere and essentially ignores the temporal continuity of the thermal structure. Furthermore, the types and density of thermal indicators determine the solution space of deposition and erosion, the quantification of which calls for the use of inverse methods, which can only be successful when all models are mutually consistent. Here, we use integrated basin modelling and Markov Chain Monte Carlo inversion of four deep boreholes to show that the erosional pattern along the Sorgenfrei–Tornquist Zone (STZ) in the eastern North Sea is consistent with a tectonic model of tectonic inversion based on compression and relaxation of an elastic plate. Three wells in close proximity SW of the STZ have different data and exhibit characteristic differences in erosion estimates but are consistent with the formation of a thick chalk sequence, followed by minor Cenozoic erosion during relaxation inversion. The well on the inversion ridge requires ca. 1.7 km Jurassic-Early Cretaceous sedimentation followed by Late Cretaceous–Palaeocene erosion during inversion. No well demands thick Cenozoic sedimentation followed by equivalent significant Neogene exhumation. When data are of high quality and models are consistent, the thermal indicator method yields significant results with important tectonic and geodynamic implications.  相似文献   
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Humans colonized the Balearic Islands 5–4 ka ago. They arrived in a uniquely adapted ecosystem with the Balearic mountain goat Myotragus balearicus (Bovidae, Antilopinae, Caprini) as the only large mammal. This mammal went extinct rapidly after human arrival. Several hypotheses have been proposed to explain the extinction of M. balearicus. For the present study ancient DNA analysis (Sanger sequencing, Roche-454, Ion Torrent), and pollen and macrofossil analyses were performed on preserved coprolites from M. balearicus, providing information on its diet and paleo-environment. The information retrieved shows that M. balearicus was heavily dependent on the Balearic box species Buxus balearica during at least part of the year, and that it was most probably a browser. Hindcast ecological niche modelling of B. balearica shows that local distribution of this plant species was affected by climate changes. This suggests that the extinction of M. balearicus can be related to the decline and regional extinction of a plant species that formed a major component of its diet. The vegetation change is thought to be caused by increased aridity occurring throughout the Mediterranean. Previous hypotheses relating the extinction of M. balearicus directly to the arrival of humans on the islands must therefore be adjusted.  相似文献   
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Increased melting on glaciers and ice sheets and rising sea level are often mentioned as important aspects of the anticipated greenhouse warming of the earth's atmosphere. This paper deals with the sensitivity of Greenland's ice mass budget and presents a tentative projection of the Greenland component of future sea level rise for the next few hundred years. To do this, the ‘Villach II temperature scenario’ is prescribed,output from a comprehensive mass balance model is used to drive a high-resolution 3-D thermomechanic model of the ice sheet.The mass balance model consists of two parts: the accumulation part is based on presently observed values and is forced by changes in mean anr tempeerature. The ablation model is based on the degree-day method and accounts for daily and annual temperature cycle, a different degree-day factor for ice and snow melting and superimposed ice formation. Under present-day climatic conditions, the following total mass balance results (in ice equivalent per years): 599.3 × 109 m3 of accumulation, 281.7 × 109m3 of runoff assuming a balanced budget, 317.6 × 109m3 of iceberg calving. A 1K uniform warming is then calculated to increase the runoff by 119.5 × 109 m3. Since accumulation also increases by 32 × 109 m3, this leads to reduction of the total mass balance by 887.5 × 109 m3 of ice, corresponding to a sea level rise of 0.22 mm/yr. For temperature increase larger than 2.7 K, runoff, exceeds accumulation, and if ice sheet dynamics were to remain unchanged, this would add an extra amount of 0.8 mmyr to the worl's oceans.Imposing the Villach II scenario (warming up to 4.23 K) and accumulating mass balance changes forward in time (static response) would then result in a global sea level rise of 7.1 cm by 2100 AD, but this figure may go up to as much as 40 cm per century in case the warming is doubled. In a subsequent dynamic model involving the ice flow, the ice sheet is found to produce a counteracting effect by dynamically producing steeper slopes at the margin, thereby reducing the area over which runoff can take place. This effect is particularly apparent in the northeastern part of the ice sheet, and is also more pronounced for the smaller temperature perturbations. Nevertheless, all these experiments certainly highlight the vulnerability of the Greenland ice sheet with respect to a climatic warming.  相似文献   
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Using a quasi-two-dimensional model of the Venus ionosphere, we calculated the ion number densities and horizontal ion bulk velocities expected for a range of solar zenith angles near the terminator (80 to 100°), and compared them with data obtained from the Pioneer Venus Orbiter retarding potential analyzer. The calculated ion bulk velocity arises entirely from the solar EUV-induced plasma pressure gradient and has a magnitude consistent with observations; ionization by suprathermal electrons is neglected in those computations. We find that while photoionization is the dominant source of ionospheric plasma for solar zenith angles less than 92°, plasma transport from the dayside is the dominant plasma source for solar zenith angles greater than 95°. We also show that the main nightside plasma peak at approximately 140 km altitude is of the F2 type (i.e., is diffusion controlled). Its altitude and shape are thus quite insensitive to the altitude of the ion source.  相似文献   
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The influence of an internal boundary layer and a roughness sublayer on flux–profile relationships for momentum and sensible heat have been investigated for a closed beech forest canopy with limited fetch conditions. The influence was quantified by derivation of local scaling functions for sensible heat flux and momentum (h and m) and analysed as a function of atmospheric stability and fetch. For heat, the influences of the roughness sublayer and the internal boundary layer were in agreement with previous studies. For momentum, the strong vertical gradient of the flow just above the canopy top for some wind sectors led to an increase in m, a feature that has not previously been observed. For a fetch of 500 m over the beech forest during neutral atmospheric conditions, there is no height range at the site where profiles can be expected to be logarithmic with respect to the local surface. The different influence of the roughness sublayer on h and m is reflected in the aerodynamic resistance for the site. The aerodynamic resistance for sensible heat is considerably smaller than the corresponding value for momentum.  相似文献   
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We examined small-scale shear zones in drillcore samples of abyssal peridotites from the Mid-Atlantic Ridge. These shear zones are associated with veins consisting of chlorite + actinolite/tremolite assemblages, with accessory phases zircon and apatite, and they are interpreted as altered plagiogranite melt impregnations, which originate from hydrous partial melting of gabbroic intrusion in an oceanic detachment fault. Ti-in-zircon thermometry yields temperatures around 820°C for the crystallization of the evolved melt. Reaction path modeling indicates that the alteration assemblage includes serpentine of the adjacent altered peridotites. Based on the model results, we propose that formation of chlorite occurred at higher temperatures than serpentinization, thus leading to strain localization around former plagiogranites during alteration. The detachment fault represents a major pathway for fluids through the oceanic crust, as evidenced by extremely low δ18O of altered plagiogranite veins (+3.0–4.2‰) and adjacent serpentinites (+ 2.6–3.7‰). The uniform oxygen isotope data indicate that fluid flow in the detachment fault system affected veins and adjacent host serpentinites likewise. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   
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