In-situ hafnium and lead isotope analyses of detrital zircons from the Devonian sedimentary basin of NE Greenland: a record of repeated crustal reworking   总被引：14，自引：0，他引：14  

T.-L. Knudsen  W. Griffin  E. Hartz  A. Andresen  S. Jackson 《Contributions to Mineralogy and Petrology》2001,141(1):83-94

An intramontane collapse basin developed within the hanging wall above the large-scale extensional Fjord Regional Detachment of NE Greenland in middle to late Devonian times. The continental clastic sediments within the basin are derived locally from Laurentian source rocks, which makes them well suited for a study of the crustal evolution of the source terrain. This is the first integrated in-situ Pb and Hf isotope study to be presented, and zircon data on a selected sandstone from the basin are combined with Sm-Nd whole-rock data on sand/siltstones. Nd whole-rock ages of two samples of sandstones and a siltstone are 2.0-2.1 Ga. Peak frequencies of zircon ²⁰⁷Pb/²⁰⁶Pb ages at 1,764-1,912 Ma, and ¹⁷⁶Hf/¹⁷⁷Hf values at 0.28142-0.28163 (t_DM=2.47 to 2.06) for the sandstone suggest the generation of a considerable volume of juvenile continental crust in the ultimate zircon provenance at 1.9-2.0 Ga. The Hf isotopic compositions of Archaean zircons in the sandstone are distinct from those of the source materials of Proterozoic protocrust at 1.9-2.0 Ga, but zircons with elevated Hf-t_DM ages of up to 2.47 Ga can be related to a component of Archaean crust or reworked Archaean material in the ultimate zircon source area. Zircon ²⁰⁷Pb/²⁰⁶Pb ages are also recorded at 1,480-1,572, 1,318 and 1,014 Ma (Grenvillian). The Hf isotope compositions of these zircons are consistent with reworking of the Proterozoic protocrust at these times, with little or no juvenile input. The Proterozoic zircons form two distinct groups defined by ¹⁷⁶Yb/¹⁷⁷Hf>0.05055 and ¹⁷⁶Yb/¹⁷⁷Hf<0.03301, and the latter group overlaps with Yb-Hf isotope data on the Archaean zircons. The two groups may represent zircons derived from evolved granites and intermediate to mildly felsic rocks, respectively. The repeated reworking of the continental crust also comprised erosion and deposition of sediments in the Proterozoic (the Krummedal sequence and the Eleonore Bay Supergroup, EBS) and intrusion of Caledonian anatectic granites in the EBS, which both represent provenance components to the Devonian sediments. No discrete Caledonian Pb-Pb zircon ages are recorded, but Caledonian magmatism may be represented by strongly discordant zircons which form arrays with a lower intercept age at ca. 400 Ma and an upper intercept at 1,600-2,000 Ma. One undated zircon records a ¹⁷⁶Hf/¹⁷⁷Hf ratio of 0.282218, higher than that of the Proterozoic protocrust in Caledonian/late-Caledonian times (380-450 Ma) which may represent a Caledonian mantle contribution.  相似文献   

Indication of a geomagnetic low-inclination excursion in supposed Middle Weichselian interstadial marine clay at Rubjerg,Denmark     

Niels Abrahamsen  Karen Luise Knudsen 《Physics of the Earth and Planetary Interiors》1979,18(3):238-246

Palaeomagnetic measurements have been made on specimens from Late Pleistocene sediments of a piston boring at Rubjerg in Vendsyssel, northern Jutland. The stratigraphy of the deposits is based on content of foraminifera. A total of 70 relatively oriented specimens were investigated palaeomagnetically. Normal steep inclinations close to that of the axial dipole field were found in the Upper Saxicava Sand and in the Younger Yoldia Clay (radiocarbon dated at 14,650 ± 190?12,650 ± 180 B.P.), and a secular variation with an amplitude of 10–12° in the inclincation and a “period” roughly estimated at about 350–400 years was found in the Younger Yoldia Clay.Seventeen relatively oriented specimens from undisturbed older marine deposits revealed a stable low inclination of 11° with α₉₅ = 3°. The age of this apparent geomagnetic excursion falls somewhere between 23,000 and 40,000 B.P. (Older Yoldia Clay). Among other known geomagnetic excursions and events within this interval are Laschamp in France, Mono Lake in California and Lake Mungo in Australia. Until more definite ages have been obtained, the excursion is provisionally named the “Rubjerg Excursion”.  相似文献   

Transient heat flow in a stratified medium     

Søren B. Nielsen  Niels Balling 《Tectonophysics》1985,121(1):1-10

The equation of heat conduction is solved for a horizontally stratified medium initially at constant temperature and subject to a step-function surface temperature change. The problem is solved by Laplace transformation and by applying a concept of further stratifications of the medium into unitary layers of constant ratio of thickness to the square root of thermal diffusivity. The solution takes the form of an infinite sum of complementary error functions, with coefficients given by recursion relations, is suitable for numerical applications and offers an attractive alternative to harmonic and quasi transient approaches in calculating the penetration of transient surface temperature variations into a layered medium. Use of the theorem of superposition yields a general expression for an arbitrary surface temperature function. The utility of the theory is illustrated by modelling examples of palaeoclimatically induced subsurface temperature and heat flow perturbations.  相似文献   

Palaeomagnetic distortion modelling and possible recovery by inversion     

Mads Faurschou Knudsen  Bo Holm Jacobsen Niels Abrahamsen 《Physics of the Earth and Planetary Interiors》2003,135(1):55-73

A robust finite-element technique is presented for computation of both the internal demagnetization effects and magnetic terrain effects in bodies with arbitrary shape and arbitrary susceptibility distribution. This method facilitates a flexible analysis of the palaeomagnetic deflection problem. Tests on geologically realistic settings of highly magnetic rocks demonstrate that deflections of several degrees may occur even for relatively simple two-dimensional models. Similarly, the magnetic intensity may well be biased by 5-15% by demagnetization effects. The present paper focuses on deflections and intensity variations inside the magnetized body, where we find a systematic shallowing of inclination for bodies with a horizontal elongation. Because the bodies sampled at a typical palaeomagnetic site will have a dominant direction of elongation, the magnetic deflection effect will tend to impose a systematic bias which doesn’t average out. An inversion-based procedure for elimination of the deflection effect is presented. It requires that the magnetic body is quite homogeneous and that its surface geometry is known, as may be the case for historical lava flows. Tests demonstrate that in order to recover both ambient palaeofield direction and the effective susceptibility at blocking temperature it is necessary to sample near strong topographic elements in the magnetic body. Since the surface geometry rarely is known it is proposed as an alternative to inversion that an effective susceptibility is assessed and a horizontal slab correction is applied for samples taken far from topographical features. When shape geometry is unknown and no correction applied, palaeomagnetic conclusions must take into account the possible bias from internal demagnetization and magnetic terrain effects.  相似文献   

Upper lithospheric seismic velocity structure across the Pripyat Trough and the Ukrainian Shield along the EUROBRIDGE'97 profile   总被引：1，自引：0，他引：1  

H. Thybo  T. Janik  V. D. Omelchenko  M. Grad  R. G. Garetsky  A. A. Belinsky  G. I. Karatayev  G. Zlotski  M. E. Knudsen  R. Sand  J. Yliniemi  T. Tiira  U. Luosto  K. Komminaho  R. Giese  A. Guterch  C. -E. Lund  O. M. Kharitonov  T. Ilchenko  D. V. Lysynchuk  V. M. Skobelev  J. J. Doody 《Tectonophysics》2003,371(1-4):41-79

We present new results on the structure resulting from Palaeoproterozoic terrane accretion and later formation of one of the aulacogens in the East European Platform. Seismic data has been acquired along the 530-km-long, N–S-striking EUROBRIDGE'97 traverse across Sarmatia, a major crustal segment of the East European Craton. The profile extends across the Ukrainian Shield from the Devonian Pripyat Trough, across the Palaeoproterozoic Volyn Block and the Korosten Pluton, into the Archaean Podolian Block. Seismic waves from chemical explosions at 18 shot points at approximately 30-km intervals were recorded in two deployments by 120 mobile three-component seismographs at 3–4 km nominal station spacing. The data has been interpreted by use of two-dimensional tomographic travel time inversion and ray trace modelling. The high data quality allows modelling of the P- and S-wave velocity structure along the profile. There are pronounced differences in seismic velocity structure of the crust and uppermost mantle between the three main tectonic provinces traversed by the profile: (i) the Pripyat Trough is a ca. 4-km-deep sedimentary basin, fully located in the Osnitsk–Mikashevichi Igneous Belt in the northern part of the profile. The velocity structure is typical for a Precambrian craton, but is underlain by a ca. 5-km-thick lowest crustal layer of high velocity. The development of the Pripyat Trough appears to have only affected the upper crust without noticeable thinning of the whole crust; this may be explained by a rheologically strong lithosphere at the time of formation of the trough. (ii) Very high seismic velocity and Vp/Vs ratio characterise the Volyn Block and Korosten Pluton to a depth of 15 km and probably also the lowest crust. The values are consistent with an intrusive body of mafic composition in the upper crust that formed from bimodal melts derived from the mantle and the lower crust. (iii) The Podolian Block is close to a typical cratonic velocity structure, although it is characterised by relatively low seismic velocity and Vp/Vs ratio. A pronounced SW-dipping mantle reflector from Moho to at least 70 km depth may represent the Proterozoic suture between Sarmatia and Volgo–Uralia, the structure from terrane accretion, or a later shear zone in the upper mantle. The sub-Moho P-wave seismic velocity is high everywhere along the profile, with the exception of the area above the dipping reflector. This velocity change further supports a plate tectonic origin of the dipping mantle reflector. The profile demonstrates that structure from Palaeoproterozoic plate tectonic processes are still identifiable in the lithosphere, even where younger metamorphic equilibration of the crust has taken place.  相似文献   

New paleomagnetic pole and magnetostratigraphy of Faroe Islands flood volcanics, North Atlantic igneous province     

Peter Riisager  Janna Riisager  Niels AbrahamsenRegin Waagstein 《Earth and Planetary Science Letters》2002,201(2):261-276

A paleomagnetic sampling was carried out along four sections (altogether 86 lava flows, 548 samples) in the North Atlantic Igneous Province outcropping in Faroe Islands, Denmark. The four polarity zones in the 700-m-thick exposed part of the Faroes lower formation can be correlated with the geomagnetic polarity time scale as C26n-C25r-C25n-C24r. The seven lava flows erupted during C25n indicate a very low eruption rate in the upper part of the Faroes lower formation of ∼1/70 kyr. The Faroes middle and upper formations (composite thickness ∼2300 m) are all reversely magnetized corresponding to C24r. The eruption rate at the onset of middle formation volcanism was very high as evidenced by several thick lava sequences recording essentially spot readings of the paleomagnetic field. The shift in eruption rate between the Faroes lower and middle formations and evidence that onset of the Faroes middle formation volcanism took place in C24r are of particular importance, placing onset of middle formation volcanism in close temporal relation to North Atlantic continental break-up and the late Paleocene thermal maximum. After grouping flows recording the same field directions, we obtained 43 independent readings of the paleomagnetic field, yielding a paleomagnetic pole with coordinates 71.4°N, 154.7°E (A₉₅=6.0°, K=14, N=43); age 55-58 Ma. The pole is supported by a positive reversal test. Paleosecular variation, estimated as the angular standard deviation of the virtual geomagnetic pole distribution 21.7°+3.9°/−2.8°, is close to expected for the given age and paleolatitude. Our new Faroes paleomagnetic pole is statistically different from the majority of previously published poles from the British and Faroes igneous provinces, and we suggest that these older data should be used with care.  相似文献   

Geochemistry of lead contaminated wetland soils amended with phosphorus     

Daniel G. Strawn  Patrick Hickey  Andrew Knudsen  Leslie Baker 《Environmental Geology》2007,52(1):109-122

To remediate Pb contaminated soils it is proposed that phosphorus can be amended to the soils to transform the Pb into poorly soluble Pb-phosphate mineral phases. However, remediation strategies must account for variable Pb speciation and site-specific factors. In this study soil mineralogy and Pb speciation in soils from P-amended field trials at sites within the Coeur d’Alene River Basin in Idaho, USA were investigated. The soils are contaminated from mining activities and are enriched with Fe and Mn. Selective extraction of the soils indicated that the Fe oxides are poorly crystalline. XRD of the soil clay size fractions identified quartz, muscovite, kaolinite, siderite, lepidocrocite, and chlorite minerals. Amendment with P fertilizer dissolved the siderite. No Pb–phosphate minerals were detected by XRD. Electron microprobe analysis showed direct correlations between Pb, Fe, and Mn in the unamended soils, and negative correlations between Pb and Si. Lead and Mn were strongly correlated. In the amended soils Fe and P were strongly correlated. Results indicate that the Pb is associated with poorly crystalline Fe and Mn oxides, and that added P is primarily associated with Fe oxide phases. Comparisons of pore water Pb concentrations with chloropyromorphite and plumbogummite solubility suggest that in the phosphate-amended soils the pore waters are undersaturated in these phases, whereas several of the control soil pore waters were oversaturated, indicating the added phosphate suppressed the Pb solubility. Results from this research provide insight into the geochemistry occurring in the P-remediated soils that will help in making management and remediation decisions.  相似文献   

Electrical Monitoring of In Situ Chemical Oxidation by Permanganate     

Lisa Cavé  Niels Hartog  Tom Al  Beth Parker  K. Ulrich Mayer  Steven Cogswell 《Ground Water Monitoring & Remediation》2007,27(2):77-84

  相似文献   

Dissolved organic matter (DOM) export to a temperate estuary: seasonal variations and implications of land use   总被引：1，自引：0，他引：1  

Colin A. Stedmon  Stiig Markager  Morten Søndergaard  Torben Vang  Anker Laubel  Niels Henrik Borch  Anders Windelin 《Estuaries and Coasts》2006,29(3):388-400

Inputs of dissolved carbon, nitrogen, and phosphorus were assessed for an estuary and its catchment (Horsens, Denmark). Seasonal patterns in the concentrations of DOM in the freshwater supply to the estuary differed depending on the soil and drainage characteristics of the area. In streams draining more natural areas the, patterns observed were largely driven by seasonal temperature fluctuations. The material exported from agricultural areas was more variable and largely controlled by precipitation events. Positive exponential relationships were found between the nitrogen and phosphorus loading, and the percentage of catchment area used for agriculture. Colored DOM (CDOM) loading measurements were found to be a good predictor of dissolved organic carbon (DOC) loading across the different subcatchments, offering a rapid and inexpensive alternative of operationally monitoring DOC export. For all the dissolved nutrient inputs to the estuary, dissolved inorganic nitrogen (DIN) and dissolved organic phosphorus dominated the loadings. Although 81% of the nitrogen annually supplied to the estuary was DIN, 83% of the nitrogen exported from the estuary was dissolved organic nitrogen (DON). Results show that increasing the area of the catchment covered by forest and natural pastures would have a positive effect on the trophic status of the estuary, leading to a considerable decrease in the phosphorus loading and a shift in the nitrogen loading from DIN to DON. Such a change in land use would also increase the export of DOC and CDOM to the estuary having the potential to increase oxygen consumption and reduce the photic depth.  相似文献   

A multiply imaged, submillimetre-selected ultraluminous infrared galaxy in a galaxy group at z∼ 2.5     

Jean-Paul Kneib  Paul P. van der Werf  Kirsten Kraiberg Knudsen  Ian Smail  rew Blain  Dave Frayer  Vicki Barnard  Rob Ivison 《Monthly notices of the Royal Astronomical Society》2004,349(4):1211-1217

  相似文献