The relationship between maximum concentration and longitudinal distance, independent of time, can determine the size of the area to be contaminated, under well-defined conditions of injection and flow in a saturated medium. The envelope curve for maximal concentrations is easily obtained as a function of the axial distance in non-dimensional variables in the cases of one- and two-dimensional uniform flow, as well as in those of radially symmetric converging or diverging flow.
Graphs providing relations between dimensionless variables (as described in the text) are given for the following cases:
1. (1) uniform flow with instantaneous discharge of a pollutant; measurement downstream of the injection point, no transverse dispersion;
2. (2) uniform flow with continuous injection of a pollutant; measurement downstream of the injection point, influence of transverse dispersion included;
3. (3) convergent radial flow towards a well; pollution caused by an instantaneous pointsource at some distance; and
4. (4) divergent radial flow from an injection point; pollution caused by instantaneous injection of a pollutant.
Résumé
L'expression de la concentration maximale en fonction de la distance et indépendamment du temps permet de déterminer l'extension d'une zone susceptible d'être contaminée lors de conditions bien définies d'injection d'un produit dangereux et d'écoulement en milieu saturé. La courbe enveloppe des maxima de concentration en fonction de la distance axiale est facilement exprimable sous forme adimensionnelle (abaques) dans le cas d'écoulements uniformes mono- et bi-dimensionnels (réponse dans l'axe), comme dans ceux d'écoulements purement cylindriques convergent ou divergent. 相似文献
Several years of measurements of ozone, hydrocarbons, sulphate and meteorological parameters from Spitsbergen in the Norwegian Arctic are presented. Most of the measurements were taken on the Zeppelin Mountain at an altitude of 474 m a.s.l. The focus is the episodes of ozone depletion in the lower troposphere in spring, which are studied in a climatological way. Episodes of very low ozone concentrations are a common feature on the Zeppelin Mountain in spring. The low ozone episodes were observed from late March to the beginning of June. When the effect of transport direction was subtracted, the frequenty of the low ozone episodes was found to peak in the beginning of May, possibly reflecting the seasonal cycle in the actual depletion process. Analyses based on trajectory calculations show that most of the episodes occurred when the air masses were transported from W-N. Ozone soundings show that the ozone depletion may extend from the surface and up to 3–4 km altitude. The episodes were associated with a cold boundary layer beneath a thermally stable layer, suppressing mixing with the free troposphere. The concentration of several individual hydrocarbons was much lower during episodes of low ozone than for the average conditions. The change in concentration ratio between the hydrocarbons was in qualitative agreement with oxidation of hydrocarbons by Br and Cl atoms rather than by OH radicals. 相似文献
Two years of individual nonmethane hydrocarbon (NMHC) measurements at a rural site close to the south coast of Norway show that there was a distinct annual cycle with a late winter maximum and late summer minimum in the slowly reacting NMHCs acetylene, ethane, propane and i- and n-butane. The average January—March concentrations were a factor 2–4 higher than the July-September concentrations. Also ethene, propene and the pentanes show a similar annual cycle, but the individual scatter in the measurements in particular of propene, is large. The highest concentrations of NMHC were found in winter for easterly transport on a regional scale (out to 1500 km from the site), and for southeasterly transport in the summer. 相似文献
A fossil geothermal area is hosted by the Carboniferous, Permian and Bunter sandstones of the Offenburg intramontane trough in the central Black Forest. The hydrothermal alteration is identified on the basis of newly formed sericites, which appear as pseudomorphs after feldspar and filling of pore spaces. According to K–Ar dating of sericite, serititization occurred about 145 Ma ago (Jurassic). On the basis of 18O analyses of sericite, sericite composition and vitrinite reflectance, the hydrothermal fluids had temperatures of 150–210 °C. Because their electrolyte content was low, these fluids are assumed to have derived from meteoric water. A second pulse of electrolyte-rich hydrothermal fluids resulted in quartz overgrowths. Fluid mobilization seems to be linked to the disintegration of Pangaea and to reactivated fault systems extending from the crystalline basement into the intramontane sediments. 相似文献
The study of molecular transformation processes of dissolved organic carbon (DOC) in the environment significantly contributes to a better understanding of the global biogeochemical organic matter cycle. In an oxic karst groundwater system, in which the most powerful abiotic DOC degradative reactions, photodegradation and metal-mediated redox chemistry, are at best marginal contributors, a near complete turnover of fulvic acids (FAs) has been observed within decades (∼60 years). Depletion of oxygen for a very extensive range of aliphatic and aromatic carbon chemical environments has been confirmed as well as the formation of novel classes of compounds, suggesting a major contribution from biotic processes. From these results we infer that FAs must be perceived as a rather active participant in the global carbon cycle. Molecular-level alterations of such magnitude and rapidity on such short-time scales ought to be considered as widespread in the processing of “refractory” DOC in the environment. 相似文献
A series of thermal conductivity measurements for various materials was performed in a large climate chamber. The size of
the chamber allowed the preparation of relatively large samples in a controlled thermal environment. Three types of thermal
sensors were used: (1) two needle probes; (2) a grid of temperature sensors, evenly distributed inside the sample; (3) two
additional thermal probes, which were simplified versions of an instrument originally developed for measuring thermal properties
of the ice/dust mixture expected to exist at the surface of a comet nucleus. They consist of a series of individual temperature
sensors integrated into a glass fibre rod. Each of these sensors can be operated in an active (heated) or passive (only temperature
sensing) mode. The following sample materials were used: fine-grained reddish sand, coarse-grained moist sand, gravels with
various grain size distributions from < 1 cm up to about 6 cm, and for comparison and calibration pure water (with convection
suppressed by adding agar-agar), compact ice, and compact granite. Of particular interest are the measurements with composite
samples, like stones embedded in an agar-agar matrix. We describe the evaluation methods and present the results of the thermal
conductivity measurements. 相似文献