Chlorite dissolution in the acid ph-range: a combined microscopic and macroscopic approach   总被引：1，自引：0，他引：1  

Felix Brandt  Dirk Bosbach  Thuro Arnold 《Geochimica et cosmochimica acta》2003,67(8):1451-1461

The dissolution of chlorite with intermediate Fe-content was studied macroscopically via mixed flow experiments as well as microscopically via atomic force microscopy (AFM). BET surface area normalized steady state dissolution rates at 25 °C for pH 2 to 5 vary between 10⁻¹² and 10⁻¹³ mol/m^2.s. The order of the dissolution reaction with respect to protons was calculated to be about 0.29. For pH 2 to 4, chlorite was found to dissolve non-stoichiometrically, with a preferred release of the octahedrally coordinated cations. The additional release of octahedrally coordinated cations may be due to the transformation of chlorite to interstratified chlorite/vermiculite from the grain edges inward.In-situ atomic force microscopy performed on the basal surfaces of a chlorite sample, which has been preconditioned at pH 2 for several months, indicated a defect controlled dissolution mechanism. Molecular steps with height differences which correspond to the different subunits of chlorite, e.g. TOT sheet and brucite like layer, originated at surface defects such or compositional inhomogenities or cracks, which may be due to the deformation history of the chlorite sample. In contrast to other sheet silicates, at pH 2 nanoscale etch pits occur on the chlorite basal surfaces within flat terraces terminated by a TOT-sheet as well as within the brucite like layer. The chlorite basal surface dissolves layer by layer, because most of the surface defects are only expressed through single TOT or brucite-like layers. The defect controlled dissolution mechanism favours dissolution of molecular steps on the basal surfaces compared to dissolution of the grain edges. At pH 2 the dissolution of the chlorite basal surface is dominated by the retreat of 14 Å steps, representing one chlorite unit cell.The macroscopic and microscopic chlorite dissolution rates can be linked via the reactive surface area as identified by AFM. The reactive surface area with respect to dissolution consists of only 0.2% of the BET-surface area. A dissolution rate of 2.5 × 10⁻⁹ mol/m²s was calculated from macroscopic and microscopic dissolution experiments at pH 2, when normalized to the reactive surface area.  相似文献   

Geotechnical properties and behaviour of Nigerian tar sand     

S.A. Ola 《Engineering Geology》1991,30(3-4):325-336

A brief review of the geology of the tar sand areas of Nigeria is given. Analysis shows that the tar sand used for the tests consists of a well graded silty sand (cmf) with about 5% clay; and 3–5% bitumen. Results presented show a very high in situ compressive strength of about 450 kN/m², a high ratio of tensile to compressive strength of about 22%, peak shear strength parameters of C_p′=15kN/m²and φ_p′ = 19° and residual parameters of C_r =0, φ_r = 18°. The compacted tar sand behaved like an overconsolidated soil with a preconsolidating pressure, P_c of 140 kN/m2. In general, the results of the in situ strength tests indicate that the Nigerian tar sand behaved as a soft sandstone.  相似文献   

A Multiscale Object-Specific Approach to Digital Change Detection   总被引：1，自引：0，他引：1  

Ola Hall  Geoffrey J. Hay 《International Journal of Applied Earth Observation and Geoinformation》2003,4(4):311-327

Landscape spatial pattern is dependent not only on interacting physiographic and physiological processes, but also on the temporal and spatial scales at which the resulting patterns are assessed. To detect significant spatial changes occurring through space and time three fundamental components are required. First, a multiscale dataset must be generated. Second, a change detection framework must be applied to the multiscale dataset. Third, a procedure must be developed to delineate individual image-objects and identify them as they change through scale. In this paper, we introduce an object-specific multiscale digital change detection approach. This approach incorporates multitemporal SPOT Panchromatic (Pan) data, object-specific analysis (OSA), object-specific up-scaling (OSU), marker-controlled watershed segmentation (MCS) and image differencing change detection. By applying this framework to SPOT Pan data, image-objects that have changed between registration dates can be identified and delineated at their characteristic scale of expression. Results illustrate that this approach has the ability to automatically detect changes at multiple scales as well as suppress sensor related noise. This study was conducted in the forest region of the Örebro Administrative Province, Sweden.  相似文献   

Simulating spatiotemporal variations of atmospheric CO₂ using a nested hemispheric model     

C Geels  J.H Christensen  L.M Frohn  J Brandt 《Physics and Chemistry of the Earth》2002,27(35):1495-1505

A three-dimensional Eulerian nested model for transport, diffusion, and surface fluxes of CO₂ has been developed. The model is used to study the spatial and temporal variations of atmospheric CO₂ concentrations as a step towards a better understanding of the regional source pattern over Europe. The influence from the national surface characteristics, as e.g. fossil CO₂ emissions or ecosystem fluxes, can be treated on a continental or national level in the model. In the future the model can be used as a mean to corroborate national and EU-wide controls or reductions of carbon emissions. One of the major questions in the estimation of e.g. national CO₂ budgets is the quantification of surface ecosystem fluxes. In order to test the sensitivity of atmospheric CO₂ concentrations to ecosystem fluxes, two different parameterizations [J. Geophys. Res. 92 (1987) 2999] and [Global Biogeochem. Cycles 10 (1996) 269] have been implemented in the model. The model both with and without nest is validated by comparison with measurements and the different model results will be discussed. The results show that including a nested domain with higher spatial resolution significantly improves the model performance in some areas. In spite of regional deviations in the two sets of ecosystems fluxes no major differences are seen over Europe as a whole when either of the two parameterizations are included in the model and the results compared.  相似文献   

A Parameterized Representation of Uncertain Conceptual Spaces   总被引：3，自引：0，他引：3  

Ola Ahlqvist 《Transactions in GIS》2004,8(4):493-514

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The effect of thermal fronts on fish growth: A bioenergetics evaluation of food and temperature     

Stephen B. Brandt 《Estuaries and Coasts》1993,16(1):142-159

Fish aggregations at fronts may be caused by either increased food availability or better thermal conditions at the front, but a quantitative evaluation of the effects of fronts on fish has yet to be done. Bioenergetics models were used to evaluate the growth rate potential of a cool-water fish, the chinook salmon (Oncorhynchus tshawytscha), and a warm-water fish, the striped bass (Morone saxatilis), across thermal fronts of different temperatures and prey concentrations. The distributions of growth rate potentials across these fronts depended on fish physiology, the temperatures encompassed by the front, and prey distributions across the front. When food was distributed uniformly across the front, the growth rates of both species were highest at their optimal temperatures, if sufficient prey was available. Lower temperatures were better for growth if prey availability was low. Increased food availability at the front enhanced fish growth rate potential at the front. Actual growth rates depended on whether the fish behaviorally selected habitats by temperature, food, or growth rate potential. Results illustrate that prey patchiness and the nonlinearities inherent in the relationsip of fish growth to temperature and prey availability must be considered in order to evaluate how a population of fish might respond to a front and how the front might affect fish growth and production.  相似文献   

The reference spectral noise ratio method to evaluate the seismic response of a site   总被引：2，自引：0，他引：2  

L. M. Fernandez  M. B. C. Brandt 《Soil Dynamics and Earthquake Engineering》2000,20(5-8):381-388

The seismic response of several sites in the Durban area of South Africa has been investigated using a refined version of the spectral ratio (H/V) generated by cultural seismic noise. Two samples of noise separated by an interval of several minutes for the vertical and the two orthogonal horizontal components were taken at each site. Though the two samples differed noticeably in the time as well as in the frequency domain, when the components are considered separately, the ratios of the horizontal to the vertical spectra were very similar for most of the pairs. This similitude was obvious not only in the frequencies of the peaks, but also in the range of amplifications involved. These observations have been used to introduce a refinement to the Nakamura Method. This refinement consists in using as a reference the H/V spectral ratio of a well-known, hard rock site. All the other soft sites of interest are then compared with this standard reference site. This comparison provides valuable information on the frequencies and amplification factors introduced by the critical soft sediments. This refined method will be referred here as the ‘Reference spectral noise ratio’.This method, is compared to a similar one devised to investigate the response of horizontal layers to longitudinal seismic waves, using the ratio of the spectra generated by long- period waves.  相似文献   

ROSAT PSPC detection of soft X-ray absorption in GB 1428+4217: the most distant matter yet probed with X-ray spectroscopy     

TH. Boller  A. C. Fabian  W. N. Brandt  M. J. Freyberg 《Monthly notices of the Royal Astronomical Society》2000,315(2):L23-L28

We report on a ROSAT PSPC observation of the highly luminous z =4.72 radio-loud quasar GB 1428+4217 obtained between 1998 December 11 and 17, the final days of the ROSAT satellite. The low-energy sensitivity of the PSPC detector was employed to constrain the intrinsic X-ray absorption of the currently most distant X-ray detected object. Here we present the detection of significant soft X-ray absorption towards GB 1428+4217, making the absorbing material the most distant matter yet probed with X-ray spectroscopy. X-ray variability by 25±8 per cent is detected on a time-scale of 6500 s in the rest frame. The X-ray variation requires an unusually high radiative efficiency of at least 4.2, further supporting the blazar nature of the source.  相似文献   

Changes in timber haul emissions in the context of shifting forest management and infrastructure     

Sean P Healey  Jock A Blackard  Todd A Morgan  Dan Loeffler  Greg Jones  Jon Songster  Jason P Brandt  Gretchen G Moisen  Larry T DeBlander 《Carbon balance and management》2009,4(1):1-11

The issues surrounding 'Reduced Emissions from Deforestation and Forest Degradation' (REDD) have become a major component of continuing negotiations under the United Nations Framework Convention on Climate Change (UNFCCC). This paper aims to address two key requirements of any potential REDD mechanism: first, the generation of measurable, reportable and verifiable (MRV) REDD credits; and secondly, the sustainable and efficient provision of emission reductions under a robust financing regime. To ensure the supply of MRV credits, we advocate the establishment of an 'International Emission Reference Scenario Coordination Centre' (IERSCC). The IERSCC would act as a global clearing house for harmonized data to be used in implementing reference level methodologies. It would be tasked with the collection, reporting and subsequent processing of earth observation, deforestation- and degradation driver information in a globally consistent manner. The IERSCC would also assist, coordinate and supervise the computation of national reference scenarios according to rules negotiated under the UNFCCC. To overcome the threats of "market flooding" on the one hand and insufficient economic incentives for REDD on the other hand, we suggest an 'International Investment Reserve' (IIR) as REDD financing framework. In order to distribute the resources of the IIR we propose adopting an auctioning mechanism. Auctioning not only reveals the true emission reduction costs, but might also allow for incentivizing the protection of biodiversity and socio-economic values. The introduced concepts will be vital to ensure robustness, environmental integrity and economic efficiency of the future REDD mechanism.  相似文献   

Soil temperature and soil moisture dynamics in winter and spring under heavy snowfall conditions in North-Eastern Japan     

Alexander C. Brandt  Qiqin Zhang  Maximo Larry Lopez Caceres  Hideki Murayama 《水文研究》2020,34(15):3235-3251

Warm winters and high precipitation in north-eastern Japan generate snow covers of more than three meters depth and densities of up to 0.55 g cm⁻³. Under these conditions, rain/snow ratio and snowmelt have increased significantly in the last decade under increasing warm winters. This study aims at understanding the effect of rain-on-snow and snowmelt on soil moisture under thick snow covers in mid-winter, taking into account that snowmelt in spring is an important source of water for forests and agriculture. The study combines three components of the Hydrosphere (precipitation, snow cover and soil moisture) in order to trace water mobility in winter, since soil temperatures remained positive in winter at nearly 0.3°C. The results showed that soil moisture increased after snowmelt and especially after rain-on-snow events in mid-winter 2018/2019. Rain-on-snow events were firstly buffered by fresh snow, increasing the snow water equivalent (SWE), followed by water soil infiltration once the water storage capacity of the snowpack was reached. The largest increase of soil moisture was 2.35 vol%. Early snowmelt increased soil moisture with rates between 0.02 and 0.035 vol% hr⁻¹ while, rain-on-snow events infiltrated snow and soil faster than snowmelt and resulted in rates of up to 1.06 vol% hr⁻¹. These results showed the strong connection of rain, snow and soil in winter and introduce possible hydrological scenarios in the forest ecosystems of the heavy snowfall regions of north-eastern Japan. Effects of rain-on-snow events and snowmelt on soil moisture were estimated for the period 2012–2018. Rain/snow ratio showed that only 30% of the total precipitation in the winter season 2011/2012 was rain events while it was 50% for the winter 2018/2019. Increasing climate warming and weakening of the Siberian winter monsoons will probably increase rain/snow ratio and the number of rain-on-snow events in the near future.  相似文献