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651.
Re–Os dating of molybdenite from small deposits is used to define crustal domains exhibiting ductile versus brittle behaviour during gravitational collapse of the Sveconorwegian orogen in SW Scandinavia. A 1019 ± 3 Ma planar quartz vein defines a minimum age for brittle behaviour in central Telemark. In Rogaland–Vest Agder, molybdenite associated with deformed quartz and pegmatite veins formed between 982 ± 3 and 947 ± 3 Ma in the amphibolite-facies domain (three deposits) and between 953 ± 3 and 931 ± 3 Ma west of the clinopyroxene-in isograd (two deposits) in the vicinity of the 0.93–0.92 Ga Rogaland anorthosite complex. The data constrain the last increment of ductile deformation to be younger than 0.95 and 0.93 Ga in these two metamorphic zones, respectively. Molybdenite is the product of an equilibrium between biotite, oxide and sulfide minerals and a fluid or hydrated melt phase, after the peak of 1.03–0.97 Ga regional metamorphism. Molybdenite precipitation is locally episodic. A model for gravitational collapse of the Sveconorwegian orogen controlled by lithospheric extension after 0.97 Ga is proposed. In the west of the orogen, the Rogaland–Vest Agder sector is interpreted as a large shallow gneiss dome, formed slowly in two stages in a warm and structurally weak crust. The first stage at 0.96–0.93 Ga was associated with intrusion of the post-collisional hornblende–biotite granite suite. The second stage at 0.93–0.92 Ga, restricted to the southwesternmost area, was associated with intrusion of the anorthosite–mangerite–charnockite suite. Most of the central part of the orogen was already situated in the brittle upper crust well before 0.97 Ga, and did not undergo significant exhumation during collapse. In the east of the orogen, situated against the colder cratonic foreland, exhumation of high-grade rocks of the Eastern Segment occurred between 0.97 and 0.95 Ga, and included preservation of high-pressure rocks but no plutonism.  相似文献   
652.
Germanium isotopic variations in igneous rocks and marine sediments   总被引:1,自引:0,他引:1  
A new technique for the precise and accurate determination of Ge stable isotope compositions has been developed and applied to silicate rocks and biogenic opal. The analyses were performed using a continuous flow hydride generation system coupled to a MC-ICPMS. Samples have been purified through anion- and cation-exchange resins to separate Ge from matrix elements and eliminate potential isobaric interferences. Variations of 74Ge/70Ge ratios are expressed as δ74Ge values relative to our internal standard and the long-term external reproducibility of the data is better than 0.2‰ for sample size as low as 15 ng of Ge. Data are presented for igneous and sedimentary rocks, and the overall variation is 2.4‰ in δ74Ge, representing 12 times the uncertainty of the measurements and demonstrating that the terrestrial isotopic composition of Ge is not unique. Co-variations of 74Ge/70Ge, 73Ge/70Ge and 72Ge/70Ge ratios follow a mass-dependent behaviour and imply natural isotopic fractionation of Ge by physicochemical processes. The range of δ74Ge in igneous rocks is only 0.25‰ without systematic differences among continental crust, oceanic crust or mantle material. On this basis, a Bulk Silicate Earth reservoir with a δ74Ge of 1.3 ± 0.2‰ can be defined. In contrast, modern biogenic opal such as marine sponges and authigenic glauconite displayed higher δ74Ge values between 2.0‰ and 3.0‰. This suggests that biogenic opal may be significantly enriched in light isotopes with respect to seawater and places a lower bound on the δ74Ge of the seawater to +3.0‰.This suggests that seawater is isotopically heavy relative to Bulk Silicate Earth and that biogenic opal may be significantly fractionated with respect to seawater. Deep-sea sediments are within the range of the Bulk Silicate Earth while Mesozoic deep-sea cherts (opal and quartz) have δ74Ge values ranging from 0.7‰ to 2.0‰. The variable values of the cherts cannot be explained by binary mixing between a biogenic component and a detrital component and are suggestive of enrichment in the light isotope of diagenetic quartz. Further work is now required to determine Ge isotope fractionation by siliceous organisms and to investigate the effect of diagenetic processes during chert lithification.  相似文献   
653.
Dissolved major and trace element concentrations were determined from November 2000 to December 2003 in the lower Rhône River (France). Subsurface water samples were collected about twice a month and more regularly during flood events. An unusual trend was observed for As, Sb, Ni and Ba concentrations which increased with river discharge at the beginning of the floods, in contrast with other elements. Variations of Sb/Na and As/Na molar ratios show that it is related to higher contributions of waters from western tributaries of the Rhône River enriched in As, Sb, Ni and Ba due to ancient mining activities. These unusual variations of dissolved element concentrations are thus interpreted as mark of a water mass origin within the watershed.  相似文献   
654.
The origin of chloride-rich karstic spring waters representative of the Languedoc-Roussillon region has been investigated with a hydrochemical approach. To this end, the major and trace elements most often used in the study of saline environments have been considered (Cl, SO4, Br, B, Li). This study allowed distinguishing the different end-members of the various chloride-rich karstic spring waters (evaporitic, marine, geothermal). Associated with the Cl, Br and B contents, the Li/SO4 ratio appeared as a relevant tracer for the determination of the origin of lithium and by extension of the considered waters. To cite this article: O. Hébrard et al., C. R. Geoscience 338 (2006).  相似文献   
655.
The instrumental drift of the superconducting gravimeter in Membach, Belgium, is estimated using 9 years of co-located and episodic absolute gravity measurements. We show that the best model of the long-term drift of the SG-C021 is an exponential. The thermal levelers used to compensate tilts are unlikely to induce the observed drift. Rather, the capacitance bridge, magnetic variations, gas adsorption on the levitating sphere, or helium gas pressure variations around it are most likely the possible combined causes of the observed instrumental drift. In practice, either linear or exponential drift models are equivalent as long as the record duration does not exceed 10 years. For longer records, this study demonstrates that an exponential models the drift better than a simple linear trend.  相似文献   
656.
The Francevillian series (Gabon) in which the Earth's oldest large colonial organisms were recently discovered (El Albani et al., 2010) were deposited 2 Gyr ago. These series are usually interpreted as a fining-upward basin-fill sequence composed by five superimposed lithological terms noted FA to FE. New studies initiated by AREVA, allowed new data to be collected on the southwestern edge of the Francevillian basin, particularly on newly excavated outcrops. Facies interpretations show that the Poubara sandstones and associated shales and black shales (upper part of FB,FB2a), correspond to turbidites deposited on an upper slope rather than one a shelf, submitted to tidal currents or storm wave action. These new interpretations based on facies association, sedimentary geometries, and basin evolution show that the depositional environment could be a turbidite lobe set at a palaeobathymetry deeper than 200 m.  相似文献   
657.
Impact melt flows exterior to Copernican-age craters are observed in high spatial resolution (0.5 m/pixel) images acquired by the Lunar Reconnaissance Orbiter Camera (LROC) Narrow Angle Camera (NAC). Impact melt is mapped in detail around 15 craters ranging in diameter from 2.4 to 32.5 km. This survey supports previous observations suggesting melt flows often occur at craters whose shape is influenced by topographic variation at the pre-impact site. Impact melt flows are observed around craters as small as 2.4 km in diameter, and preliminary estimates of melt volume suggest melt production at small craters can significantly exceed model predictions. Digital terrain models produced from targeted NAC stereo images are used to examine the three-dimensional properties of flow features and emplacement setting, enabling physical modeling of flow parameters. Qualitative and quantitative observations are consistent with low-viscosity melts heated above their liquidii (superheated) with limited amounts of entrained solids.  相似文献   
658.
In our present understanding of the Solar System, small bodies (asteroids, Jupiter Trojans, comets and TNOs) are the most direct remnants of the original building blocks that formed the planets. Jupiter Trojan and Hilda asteroids are small primitive bodies located beyond the ‘snow line’, around respectively the L4 and L5 Lagrange points of Jupiter at ~5.2?AU (Trojans) and in the 2:3 mean-motion resonance with Jupiter near 3.9?AU (Hildas). They are at the crux of several outstanding and still conflicting issues regarding the formation and evolution of the Solar System. They hold the potential to unlock the answers to fundamental questions about planetary migration, the late heavy bombardment, the formation of the Jovian system, the origin and evolution of trans-neptunian objects, and the delivery of water and organics to the inner planets. The proposed Trojans’ Odyssey mission is envisioned as a reconnaissance, multiple flyby mission aimed at visiting several objects, typically five Trojans and one Hilda. It will attempt exploring both large and small objects and sampling those with any known differences in photometric properties. The orbital strategy consists in a direct trajectory to one of the Trojan swarms. By carefully choosing the aphelion of the orbit (typically 5.3?AU), the trajectory will offer a long arc in the swarm thus maximizing the number of flybys. Initial gravity assists from Venus and Earth will help reducing the cruise time as well as the ΔV needed for injection thus offering enough capacity to navigate among Trojans. This solution further opens the unique possibility to flyby a Hilda asteroid when leaving the Trojan swarm. During the cruise phase, a Main Belt Asteroid could be targeted if requiring a modest ΔV. The specific science objectives of the mission will be best achieved with a payload that will perform high-resolution panchromatic and multispectral imaging, thermal-infrared imaging/ radiometry, near- and mid-infrared spectroscopy, and radio science/mass determination. The total mass of the payload amounts to 50?kg (including margins). The spacecraft is in the class of Mars-Express or a down-scaled version of Jupiter Ganymede Orbiter. It will have a dry mass of 1200?kg, a total mass at launch of 3070?kg and a ΔV capability of 700?m/s (after having reached the first Trojan) and can be launched by a Soyuz rocket. The mission operations concept (ground segment) and science operations are typical of a planetary mission as successfully implemented by ESA during, for instance, the recent flybys of Main Belt asteroids Steins and Lutetia.  相似文献   
659.
Abstract– The insoluble organic matter (IOM) of an unequilibrated enstatite chondrite Sahara (SAH) 97096 has been investigated using a battery of analytical techniques. As the enstatite chondrites are thought to have formed in a reduced environment at higher temperatures than carbonaceous chondrites, they constitute an interesting comparative material to test the heterogeneities of the IOM in the solar system and to constrain the processes that could affect IOM during solar system evolution. The SAH 97096 IOM is found in situ: as submicrometer grains in the network of fine‐grained matrix occurring mostly around chondrules and as inclusions in metallic nodules, where the carbonaceous matter appears to be more graphitized. IOM in these two settings has very similar δ15N and δ13C; this supports the idea that graphitized inclusions in metal could be formed by metal catalytic graphitization of matrix IOM. A detailed comparison between the IOM extracted from a fresh part and a terrestrially weathered part of SAH 97096 shows the similarity between both IOM samples in spite of the high degree of mineral alteration in the latter. The isolated IOM exhibits a heterogeneous polyaromatic macromolecular structure, sometimes highly graphitized, without any detectable free radicals and deuterium‐heterogeneity and having mean H‐ and N‐isotopic compositions in the range of values observed for carbonaceous chondrites. It contains some submicrometer‐sized areas highly enriched in 15N (δ15N up to 1600‰). These observations reinforce the idea that the IOM found in carbonaceous chondrites is a common component widespread in the solar system. Most of the features of SAH 97096 IOM could be explained by the thermal modification of this main component.  相似文献   
660.
The end of the Triassic and the Early Jurassic are intervals characterised by profound biotic and environmental changes, accompanied by dramatic decreases in marine fauna diversity. Corals were strongly affected and assemblages underwent a severe reduction; compared with those of the Upper Triassic, the Early Jurassic is traditionally defined as holding a “reef gap”. A Sinemurian coral-microbialites patch reef, located in southern France in the Hérault department (Le Perthus locality), is here described. This bioconstruction developed in a shallow mixed siliciclastic-carbonate inner ramp setting. The reef volume is composed of up to 70% of an intercoral facies mostly microbialites, with subordinated sediments (approximately 20–30% of the intercoral facies). Therefore, the patch reef can be defined as a coral-microbialite bioconstruction, in which microbialites were the main framebuilders. The coral assemblage has low diversity and is dominated by massive to branching colonies of Chondrocoenia clavellata. This highlights the reef diversity after the T/J boundary crisis. The Le Perthus patch reef could have acted as an edge for the dominant currents and probably induced reductions in hydrodynamic energy and sedimentation on one of its sides. Consequently, it could have triggered the growth of small lateral bioconstructions, composed of oysters and microbialites, uniquely on one of its sides. The evolution of the facies shows that the Le Perthus patch reef grew in a shallowing-upward setting accompanied by an increase in siliciclastic inputs. The rate of bioerosion and the faunal assemblage suggest that the bioconstructions could have been developed in a mesotrophic environment.  相似文献   
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