Empirical determination of diffusion coefficients and geospeedometry     

Olivier Jaoul  Frédéric Béjina 《Geochimica et cosmochimica acta》2005,69(4):1027-1040

Geospeedometry allows to estimate the cooling rate (s_init) of metamorphic rocks at the beginning of the cooling history using diffusion data. But the choice of a diffusion activation energy (E) and a preexponential factor (D₀) from experimental results can be difficult. We propose a method to obtain E directly from the rock itself by studying the variation of the average concentration of elements or isotopes (〈C〉) as a function of mineral grain size (d). An appropriate value of D₀ can then be estimated using an existing compensation rule, a linear relationship between log D₀ and E. Consequently, uncertainties on s_init are markedly reduced. All parameters of this analytical model and their sensitivity on s_init can be estimated from 〈C〉 of the mineral grains under study. As a test we apply our model to a study by Edwards and Valley (1998)**** on ¹⁸O/¹⁶O fractionation between diopside and calcite in Adirondacks marbles, and find a cooling rate in agreement with previous works, without choosing experimental values for E and D₀.  相似文献   

High-resolution historical records from Pettaquamscutt River basin sediments: 2. Pb isotopes reveal a potential new stratigraphic marker   总被引：2，自引：0，他引：2  

Ana Lúcia Lima  Bridget A. Bergquist  Matthew K. Reuer  Francis O. Dudas  Timothy I. Eglinton 《Geochimica et cosmochimica acta》2005,69(7):1813-1824

A high-resolution record of Pb deposition in Rhode Island over the past 250 yr was constructed using a sediment core from the anoxic Pettaquamscutt River basin. The sedimentary Pb concentration record shows the well-described maximum associated with leaded gasoline usage in the United States. Diminished Pb variability during recorded periods of local industrial activity (1735 to 1847) supports the greater importance of regional atmospheric lead transport vs. local inputs. The Pb isotopic composition at this site shows a clear maximum in anthropogenic ²⁰⁶Pb/²⁰⁷Pb in the mid-1800s. Similar peaks have also been observed in sediments from Chesapeake Bay and the Great Lakes, suggesting a common source. Possible causes for this event include mining and smelting of Pb ores in the Upper Mississippi Valley district, which accounted for almost all Pb production in the United States in that period. The timing of this event can provide an important stratigraphic marker for sediments deposited in the past 200 yr in the Northeastern United States. The downcore profile of anthropogenic ²⁰⁶Pb/²⁰⁷Pb provides a classic example of how changes in the mixture of ores for production of tetraethyl lead caused a regional-scale shift in the sedimentary record, and suggests that coal could have played a secondary role in Pb emissions after 1920.  相似文献   

Adsorption of REE(III)-humate complexes onto MnO₂: Experimental evidence for cerium anomaly and lanthanide tetrad effect suppression     

Mélanie Davranche  Olivier Pourret  Gérard Gruau  Aline Dia  Martine Le Coz-Bouhnik 《Geochimica et cosmochimica acta》2005,69(20):4825-4835

Experiments were conducted to evaluate the impact of organic complexation on the development of Ce anomalies and the lanthanide tetrad effect during the adsorption of rare-earth elements (REE) onto MnO₂. Two types of aqueous solutions—NaCl and NaNO₃—were tested at pH 5 and 7.5. Time-series experiments indicate that a steady-state is reached within less than 10 h when REE occur as free inorganic species, whereas steady state is not reached before 10 d when REE occur as REE-humate complexes. The distribution coefficients (K_d^REE) between suspended MnO₂ and solution show no or only very weak positive Ce anomaly or lanthanide tetrad effect when REE occur as humate complexes, unlike the results obtained in experiments with REE occurring as free inorganic species. Monitoring of dissolved organic carbon (DOC) concentrations show that log K_d^REE_organic/K_d^DOC ratios are close to 1.0, implying that the REE and humate remain bound to each other upon adsorption. Most likely, the Ce anomaly reduction/suppression in the organic experiments arises from a combination of two processes: (i) inability of MnO₂ to oxidize Ce(III) because of shielding of MnO₂ surfaces by humate molecules and (ii) Ce(IV) cannot be preferentially removed from solution due to quantitative complexation of the REE by organic matter. We suggest that the lack of lanthanide tetrad effect arises because the adsorption of REE-humate complexes onto MnO₂ occurs dominantly via the humate side of the complexes (anionic adsorption), thereby preventing expression of the differences in Racah parameters for 4f electron repulsion between REE and the oxide surface. The results presented here explain why, despite the development of strongly oxidizing conditions and the presence of MnO₂ in the aquifer, no (or insignificant) negative Ce anomalies are observed in organic-rich waters. The present study demonstrates experimentally that the Ce anomaly cannot be used as a reliable proxy of redox conditions in organic-rich waters or in precipitates formed at equilibrium with organic-rich waters.  相似文献   

Glacial flood pulse effects on benthic fauna in equatorial high‐Andean streams          下载免费PDF全文

Sophie Cauvy‐Fraunié  Patricio Andino  Rodrigo Espinosa  Roger Calvez  Fabien Anthelme  Dean Jacobsen  Olivier Dangles 《水文研究》2014,28(6):3008-3017

Equatorial glacier‐fed streams present unique hydraulic patterns when compared to glacier‐fed observed in temperate regions as the main variability in discharge occurs on a daily basis. To assess how benthic fauna respond to these specific hydraulic conditions, we investigated the relationships between flow regime, hydraulic conditions (boundary Reynolds number, Re*), and macroinvertebrate communities (taxon richness and abundance) in a tropical glacier‐fed stream located in the high Ecuadorian Andes (> 4000 m). Both physical and biotic variables were measured under four discharge conditions (base‐flow and glacial flood pulses of various intensities), at 30 random points, in two sites whose hydraulic conditions were representative to those found in other streams of the study catchment. While daily glacial flood pulses significantly increased hydraulic stress in the benthic habitats (appearance of Re* > 2000), low stress areas still persisted even during extreme flood events (Re* < 500). In contrast to previous research in temperate glacier‐fed streams, taxon richness and abundance were not significantly affected by changes in hydraulic conditions induced by daily glacial flood pulses. However, we found that a few rare taxa, in particular rare ones, preferentially occurred in highly stressed hydraulic habitats. Monte‐Carlo simulations of benthic communities under glacial flood reduction scenarios predicted that taxon richness would be significantly reduced by the loss of high hydraulic stress habitats following glacier shrinking. This pioneer study on the relationship between hydraulic conditions and benthic diversity in an equatorial glacial stream evidenced unknown effects of climate change on singular yet endangered aquatic systems. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Does stress transmission in forelands depend on structural style? Distinctive stress magnitudes during Sevier thin‐skinned and Laramide thick‐skinned layer‐parallel shortening in the Bighorn Basin (USA) revealed by stylolite and calcite twinning paleopiezometry     

Nicolas Beaudoin  Olivier Lacombe  Marie‐Elonore David  Daniel Koehn 《地学学报》2020,32(3):225-233

The Sheep Mountain‐Little Sheep Mountain Anticlines, Bighorn Basin (USA) formed as basement‐cored Laramide structures in the formerly undeformed foreland of the thin‐skinned Sevier orogen. We take advantage of the well‐constrained microstructural network there to reconstruct differential stress magnitudes that prevailed during both Sevier and Laramide layer‐parallel shortening (LPS), before the onset of large‐scale folding. Differential stress magnitudes determined from tectonic stylolites are compared and combined to previous stress estimates from calcite twinning paleopiezometry in the same formations. During stress loading related to LPS, differential stress magnitudes transmitted from the distant Sevier thin‐skinned orogen into the sedimentary cover of the Bighorn basin (11–43 MPa) are higher than the differential stress magnitudes accompanying the early stage of LPS related to the thick‐skinned Laramide deformation (2–19 MPa). This study illustrates that the tectonic style of an orogen affects the transmission of early orogenic stress into the stable continental interior.  相似文献   

Segmentation and kinematics of the North America‐Caribbean plate boundary offshore Hispaniola          下载免费PDF全文

Sylvie Leroy  Nadine Ellouz‐Zimmermann  Jordane Corbeau  Frédérique Rolandone  Bernard Mercier de Lépinay  Bertrand Meyer  Roberte Momplaisir  José‐Luis Granja Bruña  Anne Battani  Céline Baurion  Evgueni Burov  Valérie Clouard  Rémy Deschamps  Christian Gorini  Youri Hamon  Manfred Lafosse  Jottin Leonel  Laetitia Le Pourhiet  Pilar Llanes Estrada  Nicolas Loget  Francis Lucazeau  Daniel Pillot  Jeffrey Poort  Kevin R. Tankoo  José‐Luis Cuevas  José‐Fernando Alcaide  Claude Jean Poix  Alfonso Muñoz‐Martin  Serge Mitton  Yamil Rodriguez  Julien Schmitz  Leonardo Seeber  Andres Carbo‐Gorosabel  Santiago Muñoz 《地学学报》2015,27(6):467-478

We explored the submarine portions of the Enriquillo–Plantain Garden Fault zone (EPGFZ) and the Septentrional–Oriente Fault zone (SOFZ) along the Northern Caribbean plate boundary using high‐resolution multibeam echo‐sounding and shallow seismic reflection. The bathymetric data shed light on poorly documented or previously unknown submarine fault zones running over 200 km between Haiti and Jamaica (EPGFZ) and 300 km between the Dominican Republic and Cuba (SOFZ). The primary plate‐boundary structures are a series of strike‐slip fault segments associated with pressure ridges, restraining bends, step overs and dogleg offsets indicating very active tectonics. Several distinct segments 50–100 km long cut across pre‐existing structures inherited from former tectonic regimes or bypass recent morphologies formed under the current strike‐slip regime. Along the most recent trace of the SOFZ, we measured a strike‐slip offset of 16.5 km, which indicates steady activity for the past ~1.8 Ma if its current GPS‐derived motion of 9.8 ± 2 mm a^?1 has remained stable during the entire Quaternary.  相似文献   

Intra-interstadial environmental changes in Last Glacial loess revealed by molluscan assemblages from the Upper Palaeolithic site of Amiens-Renancourt 1 (Somme,France)     

Olivier Moine  Pierre Antoine  Sylvie Coutard  Gilles Guérin  Christine Hatté  Clément Paris  Ségolène Saulnier-Copard 《第四纪科学杂志》2021,36(8):1322-1340

The Amiens-Renancourt 1 site recently yielded one of the most important Upper Palaeolithic human occupations of northern France by the number of flint artefacts and especially by the presence of Venus figurines. All the material comes from a single archaeological layer located in a tundra gley bracketed by loess units. A multi-proxy study combining a detailed stratigraphy, luminescence and radiocarbon datings and high-resolution (5 cm per sample) grain size and molluscan analyses was therefore carried out to reconstruct and date the associated environmental changes and to determine the exact context of the human occupation. The chronological frame thus established supports the correlations of the archaeology-bearing tundra gley and of an underlying arctic brown soil with Greenland interstadials GI-4 and GI-3. Composition changes in the molluscan population enabled the identification of transitional and optimum phases and sub-phases within these two pedogenetic horizons. A conceptual correlation model linking molluscan phases with millennial-scale variations of Greenland ice-core and Sieben Hengste speleothem climate records is proposed. The Human occupation appears contemporaneous to the end of the stadial–interstadial transition of GI-3. Synchronous in Amiens-Renancourt 1 and Nussloch, subsequent micro-gleys may also result from a regional/global forcing. Such a level of detail is unprecedented in a loess sequence.  相似文献   

Floods and livelihoods: The impact of changing water resources on wetland agro-ecological production systems in the Tana River Delta,Kenya     

Crystele Leauthaud  Stéphanie Duvail  Olivier Hamerlynck  Jean-Luc Paul  Hubert Cochet  Judith Nyunja  Jean Albergel  Olivier Grünberger 《Global Environmental Change》2013,23(1):252-263

Wetlands are highly dynamic and productive systems that have been under increased pressure from changes in land use and water management strategies. In Eastern Africa, wetlands provide resources at multiple spatial and temporal levels through farming, fishing, livestock ownership and a host of other ecosystem services that sustain the local economy and individual livelihoods. As part of a broader effort to describe future development scenarios for East African coastal wetlands, this qualitative study focuses on understanding the processes by which river water depletion has affected local food production systems in Kenya's Tana River Delta over the past 50 years, and how this situation has impacted residents’ livelihoods and well-being. Interviews performed in six villages among various ethnic groups, geographical locations and resource profiles indicated that the agro-ecological production systems formerly in place were adapted to the river's dynamic flooding patterns. As these flooding patterns changed, the local population diversified and abandoned or adopted various farming, fishing and livestock-rearing techniques. Despite these efforts, the decrease in water availability affected each subcomponent of the production systems under study, which led to their collapse in the 1990s. Water depletion negatively impacted local human well-being through the loss of food security. The current study provides a detailed account of the dynamics of agro-ecological production systems facing the effects of river water depletion in a wetland-associated environment in Sub-Saharan Africa.  相似文献   

Moving from rhetoric into action: effectiveness of state–civil society synergy for healthcare delivery in rural Ghana     

Francis Jagri  Thomas Yeboah 《GeoJournal》2016,81(3):411-425

The issue of extending healthcare to marginalized underserved rural population remains a cardinal rhetoric policy of the Ghana Government. Meanwhile we note a growing inequity in terms of access and utilization of quality and affordable healthcare between urban and rural areas of the country. The Government of Ghana through its various policy initiatives in 2002 collaborated with civil societies with the aim of bringing healthcare to the doorsteps of rural folks in the country. Using a mixed method approach through a semi structured interviews and questionnaire administration, and focusing on the Community-based Health Planning and Services (CHPS) programme in Nsanfo community in the Mfanstiman municipal area, this study assesses the effectiveness and challenges confronting state–civil society partnership in co-producing a public good (healthcare). We found that synergy between the state (Mfanstiman Municipal Health Directorate) and the civil society (community health volunteers) has yielded positive results in bringing healthcare to the door steps as well as improving the health conditions of the local people in the study area. Nonetheless, certain challenges such as lack of volunteer motivation, deplorable state of the CHPS compound and logistics threaten the very existence of this collaboration. Our study has far reaching implications for healthcare planning in Ghana.  相似文献   

Effect of High Temperature on Mineralogy,Microstructure, Shear Stiffness and Tensile Strength of Two Australian Mudstones     

Xianfeng Liu  Chonglei Zhang  Shengyang Yuan  Stephen Fityus  Scott William Sloan  Olivier Buzzi 《Rock Mechanics and Rock Engineering》2016,49(9):3513-3524

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