Evidence for Enhanced Mineral Dissolution in Organic Acid-Rich Shallow Ground Water   总被引：3，自引：0，他引：3  

Peter B. McMahon  Don A. Vroblesky  Paul M. Bradley  Francis H. Chapelle  Cheryl D. Gullett 《Ground water》1995,33(2):207-216

Total concentrations of formate, acetate, and isobutyrate varied from less than 5 to greater than 9,000 μmol/l over distances of < 3 m in ground water from a shallow hydrocarbon contaminated aquifer. Laboratory incubations of aquifer material indicate that organic acid concentrations were dependent on the amount of hydrocarbon loading in the sediment and the relative rates of microbial organic acid production and consumption. In heavily contaminated sediments, production greatly exceeded consumption and organic acid concentrations increased. In lightly contaminated sediments rates were essentially equal and organic acid concentrations remained low. Concentrations of dissolved calcium, magnesium, and iron generally were one to two orders of magnitude higher in organic acid-rich ground water than in ground water having low organic acid concentrations. Carbonate and Fe(III)-oxyhydroxide minerals were the likely sources of these elements. Similarly, concentrations of dissolved silica, derived from quartz and k-feldspar, were higher in organic acid-rich ground water than in other waters. The positive relation (r = 0.60, p < .05, n = 16) between concentrations of silica and organic acids suggests that the microbially mediated buildup of organic acids in ground water enhanced quartz/k-feldspar dissolution in the aquifer, although it was not the only factor influencing their dissolution. A model that included organic acid microequivalents normalized by cation microequivalents significantly strengthened the correlation (r = 0.79, p < .001, n = 16) between dissolved silica and organic acid concentrations, indicating that competition between silica and cations for complexation sites on organic acids also influenced quartz/k-feldspar dissolution. Physical evidence for enhanced mineral dissolution in organic acid-rich waters included scanning electron microscopy images of highly corroded quartz and k-feldspar grains from portions of the aquifer containing organic acid-rich ground water. Microporosity generated in hydrocarbon contaminated sediments may adversely affect remediation efforts that depend on the efficient injection of electron acceptors into an aquifer or on the recovery of solutes from an aquifer.  相似文献   

USGS Reference Samples Attapulgite ATT-1 and Bentonite CSB-1     

John W. Hosterman  Francis J. Flanagan 《Geostandards and Geoanalytical Research》1987,11(1):1-9

The U.S. Geological Survey has prepared an attapulgite and a bentonite as reference samples because of their economic importance. The attapulgite (ATT-1) is from the Meigs-Attapulgite-Quincy fuller's earth district of Georgia and Florida, and the bentonite (CSB-1) is from the Northern Black Hills bentonite district of Wyoming, Montana, and South Dakota. The chemical and mineralogical properties of these two samples are quite different. Provisional values calculated from the few analytical data and the X-ray diffraction mineralogy are presented for those who wish to use the clays as reference samples.  相似文献   

A porous flow model for the geometrical form of volcanoes—critical comments     

G. Wadge  P. Francis 《Earth and Planetary Science Letters》1982,57(2):453-455

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Mössbauer studies of synthetic and natural micas on the polylithionite-siderophyllite join: reply     

Christian Levillain  Pierre Maurel  Francis Menil 《Physics and Chemistry of Minerals》1982,8(2):99-100

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Cultures monoalgales: courte description et discussion d'une méthode permettant une observation à fort grossissement des cellules avant leur isolement à l'aide d'un emporte-pièce     

Dr Par Olivier L. Reymond 《Aquatic Sciences - Research Across Boundaries》1983,45(2):405-408

A method allowing isolation of phytoplancton algae for unialgal cultures is briefly described. Advantages and limits of the method are discussed.  相似文献   

Comments on a method allowing permanent preparations of phytoplankton for light microscopy and the accurate selection and positioning of its cells for transmission electron microscopy     

Dr. Olivier L. Reymond 《Aquatic Sciences - Research Across Boundaries》1983,45(2):409-410

A new flat embedding method is commented. This method allows embedding of the same phytoplankton sample for light and transmission electron microscopy. Rare or interesting field specimens can then be easily selected and sectioned without the need of cultures. A great range of biological material can be handled with this method.  相似文献   

Estimation of uranium endowment by subjective geological analysis—a comparison of methods and estimates for the San Juan Basin,New Mexico     

DeVerle P. Harris  Francis J. Carrigan 《Mathematical Geosciences》1983,15(1):227-227

This study investigates how estimates of uranium endowment made by a geologist using an appraisal system that is based upon a formalization of geoscience and decision rules compare with estimates made by informal and unconstrained intuitive processes. The motivation for this study derives from the premise that formalization of decisions would mitigate the heuristic biases and hedging that may result from the use of unconstrained intuitive processes. Estimates of the uranium endowment of the San Juan Basin of New Mexico by four methodologies are compared in this study. These methods, ranked from top to bottom by degree of decomposition (mitigating of heuristic bias)and control on hedging, are as follows Implicit 2 1.5 × 10⁶ s.t. of U₃O₈ Implicit 1 1.6 × 10⁶ s.t. of U₃O₈ NURE (1980) 2.4 × 10⁶ s.t. of U₃O₈ Appraisal system 3.9 × 10⁶ s.t. of U₃O₈ The magnitude of expected uranium endowment estimated by these methods, ranked from smallest to largest, is in this same order. With the exception of the NURE estimates, the magnitude of the variance (uncertainty)of uranium endowment, ranked from smallest to largest, also is in this same order. These results prompt the suggestion that the more decomposed and formalized the estimation procedure, the greater the expected value and the variance of uranium endowment. Equivalently, predicating U ₃ O ₈ endowment estimation strictly upon that part of the geologist's geoscience that is useful in making U ₃ O ₈ endowment estimates and upon his understanding of the region's history produced larger estimates than have previously been reported. However, this method of estimation also shows that uncertainty about the actual state of U ₃ O ₈ endowment is much greater than previously described.  相似文献   

Coseismic and post-seismic signatures of the Sumatra 2004 December and 2005 March earthquakes in GRACE satellite gravity   总被引：2，自引：0，他引：2  

Isabelle Panet  Valentin Mikhailov  Michel Diament  Fred Pollitz  Geoffrey King  Olivier de Viron  Matthias Holschneider  Richard Biancale  Jean-Michel Lemoine 《Geophysical Journal International》2007,171(1):177-190

The GRACE satellite mission has been measuring the Earth's gravity field and its temporal variations since 2002 April. Although these variations are mainly due to mass transfer within the geofluid envelops, they also result from mass displacements associated with phenomena including glacial isostatic adjustment and earthquakes. However, these last contributions are difficult to isolate because of the presence of noise and of geofluid signals, and because of GRACE's coarse spatial resolution (>400 km half-wavelength). In this paper, we show that a wavelet analysis on the sphere helps to retrieve earthquake signatures from GRACE geoid products. Using a wavelet analysis of GRACE geoids products, we show that the geoid variations caused by the 2004 December ( M _w= 9.2) and 2005 March ( M _w= 8.7) Sumatra earthquakes can be detected. At GRACE resolution, the 2004 December earthquake produced a strong coseismic decrease of the gravity field in the Andaman Sea, followed by relaxation in the area affected by both the Andaman 2004 and the Nias 2005 earthquakes. We find two characteristic timescales for the relaxation, with a fast variation occurring in the vicinity of the Central Andaman ridge. We discuss our coseismic observations in terms of density changes of crustal and upper-mantle rocks, and of the vertical displacements in the Andaman Sea. We interpret the post-seismic signal in terms of the viscoelastic response of the Earth's mantle. The transient component of the relaxation may indicate the presence of hot, viscous material beneath the active Central Andaman Basin.  相似文献   

Cumulating processes at the crust-mantle transition zone inferred from Permian mafic-ultramafic xenoliths (Puy Beaunit,France)     

Julien Berger  Olivier Féménias  Nicolas Coussaert  Jean-Claude C. Mercier  Daniel Demaiffe 《Contributions to Mineralogy and Petrology》2007,153(5):557-575

Ultramafic and mafic xenoliths of magmatic origin, sampled in the Beaunit vent (northern French Massif Central), derive from the Permian (257 Ma) Beaunit layered complex (BLC) that was emplaced at the crust-mantle transition zone (∼1 GPa). These plutonic xenoliths are linked to a single fractional crystallisation process in four steps: peridotitic cumulates; websteritic cumulates; Al-rich mafic cumulates (plagioclase, pyroxenes, garnet, amphibole and spinel) and finally low-Al mafic cumulates. This sequence of cumulates can be related to the compositional evolution of hydrous Mg basaltic magma that evolved to high-Al basalt and finally to andesitic basalt. Sr and Nd isotopic compositions confirm the co-genetic character of the various magmatic xenoliths and argue for an enriched upper mantle source comparable to present mantle wedges above subduction zones. LILE, LREE and Pb enrichment are a common feature of all xenoliths and argue for an enriched sub-alkaline transitional parental magma. The existence of a Permian magma chamber at 30 km depth suggests that the low-velocity zone observed locally beneath the Moho probably does not represent an anomalous mantle but rather a sequence of mafic/ultramafic cumulates with densities close to those of mantle rocks.  相似文献   

Investigation of Reductive Dechlorination Supported by Natural Organic Carbon   总被引：1，自引：0，他引：1  

Heather V. Rectanus  Mark A. Widdowson  Francis H. Chapelle  Catherine A. Kelly  John T. Novak 《Ground Water Monitoring & Remediation》2007,27(4):53-62

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