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River discharge of Ob and Yenisei to the Kara Sea is highly variable on seasonal and interannual time scales. River water dominates the shallow bottom water near the river mouths, making it warmer and less saline but seasonally and interannually more changeable than bottom water on the deeper shelf. This hydrographic pattern shows up in measurements and modelling, and in stable isotope records (δ18O, δ13C) along the growth axis of bivalve shells and in multiple analyses of single benthic foraminiferal shells. Average isotope ratios increase, but sample-internal variability decreases with water depth and distance from river mouths. However, isotope records of bivalves and foraminifera of a sediment core from a former submarine channel of Yenisei River reveal a different pattern. The retreat of the river mouth from this site due to early Holocene sea level rise led to increasing average isotope values up core, but not to the expected decrease of the in-sample isotope variability. Southward advection of cold saline water along the palaeo-river channel probably obscured the hydrographic variability during the early Holocene. Later, when sediment filled the channel, the hydrographic variability at the core location remained low, because the shallowing proceeded synchronously with the retreat of the river mouth.  相似文献   
74.
A validation protocol for multicomponent spectroscopic assays based on principal componentsregression is described. Factorial design and hypothesis tests are used to establish the linearity andabsence of interaction between components in the regression model. Testing considers multiple responsevariables simultaneously so that correlation between residuals is properly treated. Assay reproducibilityand sensitivity to related substances are evaluated.  相似文献   
75.
One of the major application areas of factor analysis, multivariate calibration and quantitation, is coveredin this review. The algorithms, methodologies and applications covered include principal componentregression, target transformation factor analysis, singular value decomposition and rank annihilationfactor analysis. Many important areas of research having relevance to multivariate calibration andquantitation problems are also covered in this review, including background correction, measurementerror, rank determination, cross-validation, figures of merit, detection of invalid samples, experimentaldesign, sample selection, statistical inference and wavelength selection.  相似文献   
76.
Gould Pond sediments are unusual in North America in that they include a continuous record of change from marine to freshwater conditions during the late-glacial period, with a wide array of micro- and macrofossils deposited during a period of high sedimentation rate. Marine waters, much colder than those in the present Gulf of Maine, covered the site at the time of deglaciation (c. 13,200 BP). Plants characteristic of modem tundra grew on nearby uplands. Marine recession, due to isostatic rebound of the land, occurred from c . 12,800–12,200 BP. The lake water was completely freshened by 12,000 BP. A sparse shrub-herb tundra became established around Gould Pond as marine waters receded. Subsequent to 11,300 BP, sedges and other herbs became more abundant, and willow and Dryas less abundant, signifying increased warmth and decreased frost action. At least six tree species, all now common in the area, arrived around Gould Pond between c . 10,800 and 10,500 BP. This rapid transition was coincident with the most rapid major non-anthropogenic change of vegetation at sites across eastern North America during the postglacial period.  相似文献   
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The teeth, or elements, ofconodonts are among the most important Palaeozoic microfossils. Despite this, the biological relationships of conodonts have long remained enigmatic. Recent evidence of their soft anatomy, and of the ultrastructure of the elements, has finally revealed that they are vertebrates. These discoveries push vertebrate origins firmly back into the Cambrian and add a large cohort of specialists to the ranks of the vertebrate palaeontologists.  相似文献   
79.
Lithologic, petrographic and paleontologic data for the various areas of late Silurian (?) and early Devonian grey-green sandstones (greywackes) in the Liefdefjord area of northern Spitsbergen are evaluated. A number of new localities with fossil fauna have been detected in these sandstones, both to the north and south of Liefdcfjordcn. It is shown that vertebrate and invertebrate fossils occur at lower levels than hitherto believed. Differences in the amounts of plagioclase and potash feldspar in the sandstones north and south of the fjord, as well as the finds of fossils, suggest that the Siktefjellet Sandstone is restricted to the type area north of Liefdefjorden. The grey-green sandstones south of Liefdefjorden are correlated with the Andreebrecn Sandstone Formation of the Red Bay Group.  相似文献   
80.
Principal component analysis is used to examine large multivariate databases.The graphical approachto exploratory data analysis is described and illustrated with a single example of chemical compositiondata obtained on environmental dust particles.While the graphical approach to exploratory data analysishas certain advantages over the numerical procedures,the empirical approach described here should beviewed as complementary to the more robust treatments that statistical methodologies afford.  相似文献   
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