Heavy metal concentrations during storm events in a rehabilitated industrialized catchment     

W. H. Blake  R. P. D. Walsh  M. J. Barnsley  G. Palmer  P. Dyrynda  J. G. James 《水文研究》2003,17(10):1923-1939

Water quality data collected on a fortnightly or monthly basis are inadequate for assessment and modelling of many water quality problems as storm event samples are underrepresented or missed. This paper examines the stormflow dynamics of heavy metals (Pb, Cu, Cd and Zn) in the Nant‐y‐Fendrod stream, South Wales, which has been affected by 250 years of metal smelting, followed by 35 years of landscape rehabilitation measures. For storm events of contrasting (very dry and very wet) antecedent conditions in May 2000 and February 2001, respectively, temporal changes in streamwater heavy metal concentrations above and below an in‐line flood detention lake are analysed. At the upstream site, peaks in total metal concentration were recorded on the rising limb for Pb (0·150 mg l^?1) and Cu (0·038 mg l^?1) but on the falling limb for Zn (1·660 mg l^?1) and Cd (0·006 mg l^?1) in the summer 2000 storm event, yielding clockwise and anticlockwise hysteretic loops respectively. In contrast, metal concentrations, although high throughout the winter storm event, were diluted somewhat during the storm peak itself. The Pb and Cu appear to be supplied by quickflow processes and transported in close association with fine sediment, whereas Zn and Cd are delivered to the channel and lake by slower subsurface seepage in dissolved form. In the winter 2001 event, antecedent soil moisture and shallow groundwater levels were anomalously high and seepage sources of dissolved metals dominated. Downstream of the lake, Pb and Cu levels and suspended sediment were high in the summer storm, but low in the winter storm, suggesting retention with deposition of fine sediment in the lake during the latter. In the winter storm, Zn and Cd levels were higher downstream than upstream of the lake, perhaps because of additional seepage inputs from the surrounding slopes, which failed to have an impact during summer. An understanding of the complex interplay of antecedent soil moisture and the dynamics of subsurface seepage pathways in relation to the three‐dimensional distribution of sources is important in modelling heavy metal fluxes and levels in contaminated urban catchments. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

The Observation and Characterization of Lunar Meteoroid Impact Phenomena     

Cudnik  Brian M.  Palmer  David W.  Palmer  David M.  Cook  Anthony  Venable  Roger  Gural  Peter S. 《Earth, Moon, and Planets》2003,93(2):97-106

Confirmed observations of meteoroids from the Leonid stream impacting the Moon in 1999 and 2001 have opened up new opportunities in observational and theoretical astronomy. These opportunities could help bridge the gap between the ground-based (atmospheric) sampling of the smallest meteoroids and the larger objects observable with ground-based telescopes. The Moon provides a laboratory for the study of hypervelocity impacts, with collision velocities not yet possible in ground-based laboratories. Development of automatic detection software removes the time-intensive activity of laboriously reviewing data for impact event signatures, freeing the observer to engage in other activities. The dynamics of professional-amateur astronomer collaboration have the promise of advancing the study of lunar meteoritic phenomenon considerably. These three factors will assist greatly in the development of a systematic, comprehensive program for monitoring the Moon for meteoroid impacts and determining the physical nature of these impacts.  相似文献   

An Implementation of the Logarithmic Hamiltonian Method for Artificial Satellite Orbit Determination     

Seppo Mikkola  Phil Palmer  Yoshi Hashida 《Celestial Mechanics and Dynamical Astronomy》2002,82(4):391-411

We discuss the use of a recently discovered exact two-body leapfrog for accurate symplectic integration of perturbed two-body motion and for the computation of the state-transition matrix. We pay special attention to artificial satellite orbit determination and describe in detail the evaluation of the perturbing acceleration. Inclusion of air drag and other non-canonical forces are also discussed. The main advantage of this new formulation is conceptual simplicity, for easy programming and high accuracy for orbits with large eccentricity. The method has been evaluated in real artificial satellite orbit determinations.This revised version was published online in October 2005 with corrections to the Cover Date.  相似文献   

Problems with identifying the ‘8200‐year cold event’ in terrestrial records of the Atlantic seaboard: a case study from Dooagh,Achill Island,Ireland     

Katie Head  Chris S. M. Turney  Jon R. Pilcher  J. G. Palmer  M. G. L. Baillie 《第四纪科学杂志》2007,22(1):65-75

The Northern Hemisphere cooling event 8200 years ago is believed to represent the last known major freshwater pulse into the North Atlantic as a result of the final collapse of the North American Laurentide ice sheet. This pulse of water is generally believed to have occurred independently of orbital variations and provides an analogue for predicted increases in high‐latitude precipitation and ice melt as a result of anthropogenically driven future climate change. The precise timing, duration and magnitude of this event, however, are uncertain, with suggestions that the 100‐yr meltwater cooling formed part of a longer‐term cold period in the early Holocene. Here we undertook a multiproxy, high‐resolution investigation of a peat sequence at Dooagh, Achill Island, on the west coast of Ireland, to determine whether the 8200‐year cold event impacted upon the terrestrial vegetation immediately ‘downwind’ of the proposed changes in the North Atlantic. We find clear evidence for an oscillation in the early Holocene using various measures of pollen, indicating a disruption in the vegetation leading to a grassland‐dominated landscape, most probably driven by changes in precipitation rather than temperature. Radiocarbon dating was extremely problematic, however, with bulk peat samples systematically too young for the North Atlantic event, suggesting significant contamination from downward root penetration. The sustained disruption to vegetation over hundreds of years at Dooagh indicates the landscape was impacted by a long‐term cooling event in the early Holocene, and not the single century length 8200‐year meltwater event proposed in many other records in the North Atlantic region. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

The δ18O stratigraphy of the Hoxnian lacustrine sequence at Marks Tey,Essex, UK: implications for the climatic structure of MIS 11 in Britain          下载免费PDF全文

G. J. Tye  J. Sherriff  I. Candy  P. Coxon  A. Palmer  E. L. McClymont  D. C. Schreve 《第四纪科学杂志》2016,31(2):75-92

Marine Isotope Stage 11 (MIS 11) is considered one of the best analogues for the Holocene. In the UK the long lacustrine sequence at Marks Tey, Essex, spans the entirety of the Hoxnian interglacial, the British correlative of MIS 11c. We present multiproxy evidence from a new 18.5‐m core from this sequence. Lithostratigraphy, pollen stratigraphy and biomarker evidence indicate that these sediments span the pre‐, early and late temperate intervals of this interglacial as well as cold climate sediments that post‐date the Hoxnian. The δ¹⁸O signal of endogenic carbonate from this sequence produces several clear patterns that are interpreted as reflecting the climatic structure of the interglacial. As well as providing evidence for long‐term climate stability during the interglacial and a major post‐Hoxnian stadial/interstadial oscillation the δ¹⁸O signal provides strong evidence for abrupt cooling events during the interglacial itself. One of these isotopic events occurs in association with a short‐lived increase in non‐arboreal pollen (the NAP phase). The results presented here are discussed in the context of other MIS 11 records from Europe and the North Atlantic, particularly with respect to our understanding of the occurrence of abrupt climatic events in pre‐Holocene interglacials. Copyright © 2016 The Authors. Journal of Quaternary Science Published by John Wiley & Sons Ltd.  相似文献   

A Radial Injection Tracer Experiment in a Confined Aquifer, Scarborough, Ontario, Canada     

Carl D. Palmer  Robert L. Nadon 《Ground water》1986,24(3):322-331

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A new direction for shallow refraction seismology: integrating amplitudes and traveltimes with the refraction convolution section   总被引：1，自引：0，他引：1  

Derecke Palmer 《Geophysical Prospecting》2001,49(6):657-673

The refraction convolution section (RCS) is a new method for imaging shallow seismic refraction data. It is a simple and efficient approach to full‐trace processing which generates a time cross‐section similar to the familiar reflection cross‐section. The RCS advances the interpretation of shallow seismic refraction data through the inclusion of time structure and amplitudes within a single presentation. The RCS is generated by the convolution of forward and reverse shot records. The convolution operation effectively adds the first‐arrival traveltimes of each pair of forward and reverse traces and produces a measure of the depth to the refracting interface in units of time which is equivalent to the time‐depth function of the generalized reciprocal method (GRM). Convolution also multiplies the amplitudes of first‐arrival signals. To a good approximation, this operation compensates for the large effects of geometrical spreading, with the result that the convolved amplitude is essentially proportional to the square of the head coefficient. The signal‐to‐noise (S/N) ratios of the RCS show much less variation than those on the original shot records. The head coefficient is approximately proportional to the ratio of the specific acoustic impedances in the upper layer and in the refractor. The convolved amplitudes or the equivalent shot amplitude products can be useful in resolving ambiguities in the determination of wave speeds. The RCS can also include a separation between each pair of forward and reverse traces in order to accommodate the offset distance in a manner similar to the XY spacing of the GRM. The use of finite XY values improves the resolution of lateral variations in both amplitudes and time‐depths. The use of amplitudes with 3D data effectively improves the spatial resolution of wave speeds by almost an order of magnitude. Amplitudes provide a measure of refractor wave speeds at each detector, whereas the analysis of traveltimes provides a measure over several detectors, commonly a minimum of six. The ratio of amplitudes obtained with different shot azimuths provides a detailed qualitative measure of azimuthal anisotropy and, in turn, of rock fabric. The RCS facilitates the stacking of refraction data in a manner similar to the common‐midpoint methods of reflection seismology. It can significantly improve S/N ratios.Most of the data processing with the RCS, as with the GRM, is carried out in the time domain, rather than in the depth domain. This is a significant advantage because the realities of undetected layers, incomplete sampling of the detected layers and inappropriate sampling in the horizontal rather than the vertical direction result in traveltime data that are neither a complete, an accurate nor a representative portrayal of the wave‐speed stratification. The RCS facilitates the advancement of shallow refraction seismology through the application of current seismic reflection acquisition, processing and interpretation technology.  相似文献   

A multiple-parameter approach to andesitic tephra correlation, Ruapehu volcano, New Zealand     

Shane J. Cronin  Vincent E. Neall  Robert B. Stewart  Alan S. Palmer 《Journal of Volcanology and Geothermal Research》1996,72(3-4)

A multi-parameter approach was used to correlate andesitic tephras in a complex tephra sequence ranging in age from ca. 23 to ca. 75 ka on the eastern ring plain of Ruapehu volcano, North Island. Field properties, combined with ferromagnesian mineral assemblages and mineral compositions, were required to map and correlate this sequence. Three tephra units could be identified based on their unique physical appearance, but other tephras could not be correlated on this basis alone. Hornblende and olivine proved to be valuable marker minerals enabling further distinction of two of the marker units recognised by field properties, as well as defining two further marker tephras. Unweathered titanomagnetite crystals, present in all of the tephras, were subjected to major-element analysis by electron microprobe. Canonical discriminant function analysis (DFA) of these analyses enabled the grouping and discrimination of tephra units, further aiding the identification of defined marker units, as well as defining new marker units. The titanomagnetite chemistry showed a strong relationship to the ferromagnesian mineralogy, showing that the ferromagnesian phenocrysts formed from the same melt or under the same melt conditions prior to eruption of each tephra. Canonical DFA was also applied to hornblende and olivine mineral analyses to identify further marker beds and to confirm identifications of previously defined units. This statistical analysis was found to be invaluable in reducing the large amount of compositional data from this study into a useable form for andesitic tephra correlation and mapping.  相似文献   

Selected elements in major minerals from bituminous coal as determined by INAA: implications for removing environmentally sensitive elements from coal     

C. A. Palmer  P. C. Lyons 《International Journal of Coal Geology》1996,32(1-4)

The four most abundant minerals generally found in Euramerican bituminous coals are quartz, kaolinite, illite and pyrite. These four minerals were isolated by density separation and handpicking from bituminous coal samples collected in the Ruhr Basin, Germany and the Appalachian basin, U.S.A. Trace-element concentrations of relatively pure ( 99⁺%) separates of major minerals from these coals were determined directly by using instrumental neutron activation analysis (INAA). As expected, quartz contributes little to the trace-element mass balance. Illite generally has higher trace-element concentrations than kaolinite, but, for the concentrates analyzed in this study, Hf, Ta, W, Th and U are in lower concentrations in illite than in kaolinite. Pyrite has higher concentrations of chalcophile elements (e.g., As and Se) and is considerably lower in lithophile elements as compared to kaolinite and illite. Our study provides a direct and sensitive method of determining trace-element relationships with minerals in coal.Mass-balance calculations suggest that the trace-element content of coal can be explained mainly by three major minerals: pyrite, kaolinite and illite. This conclusion indicates that the size and textural relationships of these major coal minerals may be a more important consideration as to whether coal cleaning can effectively remove the most environmentally sensitive trace elements in coal than what trace minerals are present.  相似文献   

Status of the Transient Gamma-Ray Spectrometer     

H. Seifert  B. J. Teegarden  D. Palmer  N. Gehrels  T. L. Cline  R. Ramaty  A. Owens  K. Hurley  R. Pehl  N. Madden 《Astrophysics and Space Science》1995,231(1-2):475-478

The Transient Gamma-Ray Spectrometer (TGRS) was launched aboard the GGS/WIND spacecraft on November 1, 1994. After several deep space orbits (2 yrs) WIND will eventually be injected into a halo orbit around the Sun-EarthL ₁ point. TGRS consists of a 215 cm³ high purityn-type Ge crystal which is kept at cryogenic temperatures by a passive radiative cooler. The energy range covered by the instrument is 25–8000 keV with an energy resolution of 2–3 keV. The primary task of TGRS is to perform high resolution spectroscopy of gamma-ray bursts and solar flares. Additional objectives are the study of transient x-ray pulsars and, using an on-board passive occulter, the long-term monitoring of sources such as the Crab and the Galactic Center. Since launch, TGRS has been performing exceedingly well, and all the important experiment parameters such as background levels, gain, and resolution have proven to be very stable. To date, TGRS has detected 27 GRBs and three solar flares. Preliminary analysis of our data also indicates that TGRS is indeed sensitive to sources such as the Crab and the Galactic Center.  相似文献