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31.
Nano‐alumina modified by 9‐aminoacridine was used as a sorbent for separation and determination of dichromate ions from water. Statistical method, based on surface response design, has been used for the optimization of dichromate ions elution from 9‐aminoacridine nano‐alumina. The adsorbed dichromate ions were found to be eluted quantitatively with 0.8 mol L?1 KCl in 1.6 mol L?1 NaOH which optimized by response surface design. Under optimum conditions, the accuracy, precision (relative standard deviation, RSD%) and R‐square of the method were calculated as >98, <3, and >94%, respectively. Remarkable agreement between experimental and theoretical data was confirmed the predicted assumption. The method was applied to the simultaneous determination of dichromate in natural and industrial water samples. We also examined the retention of dichromate anions in the presence of Cl?, , and anions at pH 3.  相似文献   
32.
Regularization methods are used to recover a unique and stable solution in ill-posed geophysical inverse problems. Due to the connection of homogeneous operators that arise in many geophysical inverse problems to the Fourier basis, for these operators classical regularization methods possess some limitations that one may try to circumvent by wavelet techniques.
In this paper, we introduce a two-step wavelet-based regularization method that combines classical regularization methods with wavelet transform to solve ill-posed linear inverse problems in geophysics. The power of the two-step wavelet-based regularization for linear inversion is twofold. First, regularization parameter choice is straightforward; it is obtained from a priori estimate of data variance. Second, in two-step wavelet-based regularization the basis can simultaneously diagonalize both the operator and the prior information about the model to be recovered. The latter is performed by wavelet-vaguelette decomposition using orthogonal symmetric fractional B-spline wavelets.
In the two-step wavelet-based regularization method, at the first step where fully classical tools are used, data is inverted for the Moore-Penrose solution of the problem, which is subsequently used as a preliminary input model for the second step. Also in this step, a model-independent estimate of data variance is made using nonparametric estimation and L-curve analysis. At the second step, wavelet-based regularization is used to partially recover the smoothness properties of the exact model from the oscillatory preliminary model.
We illustrated the efficiency of the method by applying on a synthetic vertical seismic profiling data. The results indicate that a simple non-linear operation of weighting and thresholding of wavelet coefficients can consistently outperform classical linear inverse methods.  相似文献   
33.
At the end of the western part of Bagharan Kuh Mountain in the northeast of Iran, mountain growth has been stopped toward the west because of the stress having been consumed by the thrusting movements and region rising instead of shear movement. Chahkand fault zone is situated at the western part of this mountain; this fault zone includes several thrust sheets that caused upper cretaceous ophiolite rocks up to younger units, peridotite exposure and fault related fold developing in the surface. In transverse perpendicular to the mountain toward the north, reduction in the parameters like faults dip, amount of deformation, peridotite outcrops show faults growth sequence and thrust sheets growth from mountain to plain, thus structural vergence is toward the northeast in this fault zone. Deformation in the east part of the region caused fault propagation fold with axial trend of WNW-ESE that is compatible with trending of fault plane. In the middle part, two types of folds is observed; in the first type, folding occurred before faulting and folds was cut by back thrust activity; in the second type, faults activity caused fault related folds with N60-90W axial trend. In order to hanging wall strain balance, back thrusts have been developed in the middle and western part which caused popup and fault bend folds with N20-70E trend. Back thrusts activity formed footwall synclines, micro folds, foliations, and uplift in this part of the region. Kinematic analysis of faults show stress axis σ1 = N201.6, 7, σ2 = N292.6, 7.1, σ3 = N64.8, 79.5; stress axis obtained by fold analysis confirm that minimum stress (σ3) is close to vertical so it is compatible with fault analysis. Based on the results, deformation in this region is controlled by compressional stress regime. This stress state is consistent with the direction of convergence between the Arabian and Eurasian plates. Also study of transposition, folded veins, different movements on the fault planes and back thrusts confirm the progressive deformation is dominant in this region that it increases from the east to the west.  相似文献   
34.
Ring footings can be more effective and economical than circular footings. In spite of similarities between circular and ring footings, their behaviors are different in some respects such as bearing pressure distribution under the footing and settlement. But no exclusive theoretical prediction of ultimate bearing capacity has been reported for ring footings. In the present study, stress characteristics method is employed for coding the bearing capacity of ring footing with horizontal ground surface. In the calculations, friction at the contact between the soil and foundation is considered. In this research, the soil obeys the Mohr–Coulomb yield criterion and that is cohesive–frictional-weighted with applied surcharge pressure. The bearing capacity factors Nγ, Nq and Nc for ring footings were calculated by a written code based on the method of characteristics. Bearing capacity was determined for different conditions of soil and different ratio of radii in comparison with the principle of superposition results. The findings show that the principle of superposition is effective for determining the bearing capacity of a ring footing.  相似文献   
35.
36.
Mechanical and Elastic Properties of Transversely Isotropic Slate   总被引:3,自引:1,他引:2  
Planes of weakness like schistosity and foliation affect the strength and deformational behaviors of rocks. In this paper, an attempt has been made to study the elastic and strength behavior of slate rocks obtained from foundation of Sardasht dam site in Iran. Wet and dry specimens with different orientation of foliation were evaluated under uniaxial, triaxial, and Brazilian tests. According to the results obtained, slate mechanically pronounced U-shaped anisotropy in uniaxial and triaxial compression tests. In addition, the degree of anisotropy for the slates tested in current study was relatively high, showing the effect of foliation plane on strength and elastic parameters. It was concluded that stiffness of the samples decrease as the angle of anisotropy reaches 30–40°. This change was more pronounced for wet comparing to dry samples. However, the tensile strength obtained during Brazilian tests indicated that there is no apparent relationship between angle of anisotropy and tensile strength. However, increasing the water saturation decreased the tensile strength of the samples. The calculated elastic moduli referring to different anisotropy angles could be valuable for the design of various engineering structures in planar textured rock masses.  相似文献   
37.
One large group of persistent and toxic contaminants is the hydrophobic organic contaminants. Among them, perchloroethylene (PCE) has been recognized as a representative group of these pollutants with low solubility. This study reports on the effects of electrokinetic remediation with non-ionic surfactant on PCE-contaminated soil. The performance of electrokinetic process was investigated in the treatment of clay soil that artificially contaminated with two levels: 10,000 and 30,000 mg/kg PCE and 0.33 g/kg Triton X-100. A DC power supply with electric voltage (1 V/cm) was used for 8–16 days. A negatively charged soil surface resulted in a more negative zeta potential and greater electroosmotic flow toward the cathode. The PCE was measured after extraction using n-hexane and analyzed by Fourier transform infrared spectroscopy instrument. The water content of soil was kept 25 % (w/w). Results were shown that PCE removal efficiency achieved was 74 and 89 % for 10,000 and 30,000 mg/kg PCE, respectively, for 16 days. Therefore, in this study, the integration of electrokinetic with non-ionic surfactant as a hybrid method was most effective for the remediation of PCE-contaminated soils.  相似文献   
38.
A modified failure criterion is proposed to determine the strength of transversely isotropic rocks. Me-chanical properties of some metamorphic and sedimentary rocks including gneiss, slate, marble, schist, shale, sandstone and limestone, which show transversely isotropic behavior, were taken into consider-ation. Afterward, introduced triaxial rock strength criterion was modified for transversely isotropic rocks. Through modification process an index was obtained that can be considered as a strength reduction parameter due to rock strength anisotropy. Comparison of the parameter with previous anisotropy in-dexes in literature showed reasonable results for the studied rock samples. The modified criterion was compared to modified Hoek-Brown and Ramamurthy criteria for different transversely isotropic rocks. It can be concluded that the modified failure criterion proposed in this study can be used for predicting the strength of transversely isotropic rocks.  相似文献   
39.
Marine sediments typically exhibit steep porosity gradients in their uppermost centimeters. Although the decrease in porosity with depth below the sediment-water interface is primarily due to compression arising from the accumulation of overlying sediment, early diagenetic mineral dissolution and precipitation reactions may potentially also affect the porosity gradient. Here, we present a steady state compaction model, based on the mass and momentum conservation of total fluid and solid phases, in order to quantify the relative contributions of mineral reactions and physical compaction on porosity changes. The compaction model is applied to estimate hydraulic conductivity and compressive response coefficients of deep-sea sediments from measured porosity depth profiles. The results suggest an inverse relation between the compressive response coefficient and the lithogenic content of marine sediments. For deep-sea sediments exhibiting high rates of dissolution of siliceous shell fragments, the compaction model ignoring mineral reactions overestimates the hydraulic conductivity and compressive response coefficients. In contrast to non-compacting porous media, mineral dissolution in surficial sediments can lead to lower porosity. However, as illustrated for a deep-sea sediment in the equatorial Atlantic characterized by extensive dissolution of calcareous shell fragments, the effect of mineral dissolution and precipitation reactions on porosity gradients is, in most cases, negligible.  相似文献   
40.
In this study, the trends of the annual, seasonal and monthly maximum (T max) and minimum (T min) air temperatures time series were investigated for 20 stations in the western half of Iran during 1966?C2005. Three statistical tests including Mann?CKendall, Sen??s slope estimator and linear regression were used for the analysis. The annual T max and T min series showed a positive trend in 85% of the stations and a negative trend in 15% of the stations in the study region. The highest increase of T max and T min values were obtained over Kermanshah and Ahwaz at the rates of (+)0.597°C/decade and (+)0.911°C/decade, respectively. On the seasonal scale, the strongest increasing trends were identified in T max and T min data in summer. The highest numbers of stations with positive significant trends occurred in the monthly T max and T min series in August. In contrast, the lowest numbers of stations with significant positive trends were observed between November and March. Overall, the results showed similar increasing trends for the study variables, although T min generally increased at a higher rate than T max in the study period.  相似文献   
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