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11.
Fisheries in boreal ecosystems 总被引:2,自引:1,他引:2
12.
13.
Many classes of environmental contaminants affect the reproductive function of animals through interactions with the endocrine system. The primary components affected by endocrine active compounds (EACs) are the steroid receptors and the enzymes responsible for steroidogenesis. This study sought to develop an in vitro model for assessing EAC effects in sea turtles by examining their ability to alter cytochrome P450 aromatase (CYP19) activity. Aromatase is the enzyme responsible for the conversion of testosterone to estradiol. This enzyme is critical in the sexual differentiation of reptiles which demonstrate temperature-dependent sex determination. An immortal testis cell line GST-TS from a green sea turtle was grown in culture at 30 degrees C in RPMI 1640 media. The cells were exposed to three known aromatase inducers; dexamethasone (Dex), 8Br-cyclic AMP, or human chronic gonadotropin (HCG) and one aromatase inhibitor 4-androstenol-dione (4-OHA). In addition, the GST-TS cells were exposed to 0.1-30 microM atrazine and 3-100 microM 4,4'-DDE. The inducing compounds that have been shown to increase aromatase activity in other systems failed to induce aromatase activity in the GST-TS cells, yet exposure to the inhibiting compound, 4-OHA, did result in a significant reduction. Atrazine (0.1, 1.0 and 10 microM) significantly induced aromatase activity following a 24 h exposure, and 4,4'-DDE inhibited the activity but only at cytotoxic concentrations (100 microM). Based on these results, this in vitro model can be useful in examining the endocrine effects of EACs in sea turtles. 相似文献
14.
An analysis of the rotation of coronal holes (CHs) spanning 18 years was done based on data from theCatalogue of Coronal Holes (Sanchez-Ibarra and Barraza-Paredes, 1992). A differential rotation of CHs is confirmed for the totality of CHs, but a different behavior was found when those were separated as equatorial or isolated, and polar hole extensions, such as in theCatalogue. Isolated CHs show a typical differential rotation, but polar hole extensions display two different types of behavior: a rotation rate below 40° ± 5° of heliographic latitude, increasing to the equator, and a rotation rate above the same heliographic latitude but increasing to the poles. Also discussed here is how this last result agrees with other studies that indicate the mostly rigid rotation of the corona at higher latitudes. 相似文献
15.
The behavior of trace elements during schwertmannite precipitation and subsequent transformation into goethite and jarosite 总被引:5,自引:0,他引:5
Patricia Acero Carlos Ayora José-Miguel Nieto 《Geochimica et cosmochimica acta》2006,70(16):4130-4139
Schwertmannite is a ubiquitous mineral formed from acid rock drainage (ARD), and plays a major role in controlling the water chemistry of many acid streams. The formation of schwertmannite was investigated in the acid discharge of the Monte Romero abandoned mine (Iberian Pyrite Belt, SW, Spain). Schwertmannite precipitated from supersaturated solutions mainly owing to the oxidation of Fe(II) to Fe(III) and transformed with time into goethite and jarosite. In a few hours, schwertmannite precipitation removed more than half of the arsenic load from solution, whereas the concentration of divalent trace metals (Zn, Cu, Pb, Cd, Ni, and Co) remained almost unchanged. In the laboratory, natural schwertmannite was kept in contact with its coexisting acid water in a flask with a solid-liquid mass ratio of 1:5 for 353 days. During this time, the pH of the solution dropped from 3.07 to 1.74 and the concentrations of sulfate and Fe increased. During the first 164 days, schwertmannite transformed into goethite plus H3O-jarosite but, subsequently, goethite was the only mineral to form. Some of the trace elements, such as Al, Cu, Pb, and As were depleted in solution during the first stage as schwertmannite transformed into goethite plus H3O-jarosite. On the contrary, the transformation of schwertmannite to goethite (with no jarosite) during the second stage released Al, Cu, and As to the solution. Despite the variation in their concentrations in solution, approximately 80% of the total Al and Cu inventories and more than 99% As and Pb remained in the solid phase throughout the entire aging process. 相似文献
16.
Several types of anhydrite-bearing rocks have been found in the amphibolite-facies metamorphosed rocks at the north-eastern margin of the Moldanubian Zone. Anhydrite either forms monomineralic bands up to 40 cm thick, or occurs in the form of disseminated grains in surrounding calc-silicate gneiss together with feldspar, scapolite, amphibole, pyroxene, epidote and pyrite. The isotopic composition of sulphur ('34S=30.6 to 32.3) and strontium (87Sr/86Sr=0.70797 to 0.70781) in anhydrite may indicate a marine source of sulphate. The isotopic ratio of strontium is in the same range as that of metamorphosed strata-bound barite-sulphide ores, which have been previously described in the same area. The '34S values of coexisting pyrite range from 21.4 to 22.5, the (34Sanhydrite-pyrite corresponding to the metamorphic temperature of 600 to 660 °C. In contrast to many submarine-exhalative deposits, the oxygen isotopic compositions of anhydrite ('18O=9.3 to 10.2) are lighter than that of barite ('18O=10.4 to 13.8). This indicates that the both minerals are not in isotopic equilibrium. Therefore, it is probable that anhydrite and barite from the Roná district were deposited from fluids that contained different proportions of seawater and hydrothermal fluids or from hydrothermal fluids that underwent variable extent of oxygen isotope exchange with seafloor rocks. The '13C values in calcite ('13C=-17.2 to -18.7) from anhydrite-bearing rock are lower than those in distant marbles. As graphite is absent in anhydrite- and calcite-bearing rocks, impoverishment in the 13C isotope cannot be attributed to the graphite-carbonate isotopic exchange during metamorphism. It is proposed that low '13C values in carbonates are caused by pre-metamorphic oxidation of organic matter in course of hydrothermal processes. Anhydrite and anhydrite-bearing calc-silicate gneiss from the north-eastern part of the Moldanubian Zone are interpreted to be the high-grade metamorphosed analogue of anhydrite-rich exhalites commonly found in submarine-exhalative hydrothermal deposits. 相似文献
17.
Direct observations of aluminosilicate weathering in the hyporheic zone of an Antarctic Dry Valley stream 总被引:1,自引:0,他引:1
Patricia A. Maurice Diane M. McKnightLaura Leff Julia E. FulghumMichael Gooseff 《Geochimica et cosmochimica acta》2002,66(8):1335-1347
This study focused on chemical weathering and bacterial ecology in the hyporheic zone of Green Creek, a McMurdo Dry Valley (Antarctica) stream. An in situ microcosm approach was used to observe dissolution features on the basal-plane surface of muscovite mica. Four mica chips were buried in December 1999 and dug up 39 d later. Atomic force microscopy (AFM) of the basal-plane surfaces revealed small, anhedral ∼10-Å-deep etch pits covering ∼4% of the surfaces, from which an approximate basal-plane dissolution rate of 8.3 × 10−18 mol muscovite cm−2 s−1 was calculated (on the basis of the geometric surface area) for the study period. This is an integrated initial dissolution rate on a fresh surface exposed for a relatively brief period over the austral summer and should not be compared directly to other long-term field rates. The observation of weathering features on mica agrees with previous stream- and watershed-scale studies in the Dry Valleys, which have demonstrated that weathering occurs where liquid water is present, despite the cold temperatures.AFM imaging of mica surfaces revealed biofilms including numerous small (<1 μm long), rounded, oblong bacteria. The AFM observations agreed well with X-ray photoelectron microscopy results showing increased organic C and N. Bacteriologic analysis of the hyporheic zone sediments also revealed <1-μm-long bacteria. α-Proteobacteria were observed, consistent with the oligotrophic conditions of the hyporheic zone. Nitrate-reducing bacteria were found, in agreement with a previous tracer test at Green Creek that suggested nitrate reduction occurs in the hyporheic zone. The results of this study thus provide direct evidence of dynamic geochemical and microbial processes in the hyporheic zone of a Dry Valley stream despite the extreme conditions; such processes were inferred previously from stream-scale hydrogeochemical studies. 相似文献
18.
M M Jana 《Journal of the Indian Society of Remote Sensing》1997,25(2):105-111
River basin management and development are most important for utilising and conserving the water resources in any region where the average annual rainfall is highly fluctuating, the North Bengal is one of such region. Though there are a large number of rivers having a large catchment area in the hills and carry a huge amount of water during rainy season but they are completely dry in winter and summer. The upper part of majority of river basins arc highly sensitive to water erosion and land slides due to deforestation, intensive cultivation, increased settlements in sloping and erosion prone areas. So, floods in the rainy season and droughts in summer months are frequent features in North Bengal. In view of this proper management and effective conservation of land and water resources is necessary to develop the region. An integrated river basin management consisting soil conservation, afforestation, flood control, and adoption of suitable cropping pattern is essential for economic development of North Bengal. 相似文献
19.
Calculating the two-dimensional magnetotelluric Jacobian in finite elements using reciprocity 总被引:6,自引:0,他引:6
Patricia Pastana de Lugão Philip E. Wannamaker 《Geophysical Journal International》1996,127(3):806-810
To speed up the calculation of the field Jacobian for 2-D magnetoteliuric inversion using finite elements, the principle of electromagnetic reciprocity is applied. The governing relationship for the Jacobian of the field along strike is obtained by differentiating the Helmholtz equation with respect to the resistivity of each region in the finite-element mesh. The result is a similar Helmholtz equation for the Jacobian, with new sources distributed over all nodes within the parameter medium. However, according to the principle of electromagnetic reciprocity, the roles of sources and receivers are interchangeable. Utilizing reciprocity, the field values obtained from the original forward problem and for new unit sources imposed at the receivers are then utilized in the calculation of the Jacobian by simple multiplication and summation with finite-element terms at each rectangle in the mesh. For the auxiliary (across-strike) fields, the Jacobian terms are obtained by solving source vectors loaded with parabola coefficients used in the approximation to Maxwell's equations. Jacobian terms for the apparent resistivity ( p a ), the impedance phase (φ) and the vertical magnetic field ( K zy ) are then calculated utilizing the parallel- and auxiliary-field Jacobians. Comparison of Jacobian values obtained from reciprocity calculations and by differencing two forward solutions show that the reciprocity method is accurate and can be used to decrease the number of calculations required to obtain sensitivities by one to two orders of magnitude. 相似文献
20.
Liquid metal-liquid silicate partitioning of Fe, Ni, Co, P, Ge, W and Mo among a carbon-saturated metal and a variety of silicate melts (magnesian-tholeiitic-siliceous-aluminous-aluminosiliceous basalts) depends modestly to strongly upon silicate melt structure and composition. Low valency siderophile elements, Fe, Ni and Co, show a modest influence of silicate melt composition on partitioning. Germanium shows a moderate but consistent preference for the depolymerized magnesian melt. High valency siderophile elements, P, Mo, and W, show more than an order of magnitude decrease in metal-silicate partition coefficients as the silicate melt becomes more depolymerized. Detailed inspection of our and other published W data shows that polymerization state, temperature and pressure are more important controls on W partitioning than oxidation state. For this to be true for a high and variable valence element implies a secondary role in general for oxidation state, even though some role must be present. Equilibrium core segregation through a magma ocean of ‘ultrabasic’ composition can provide a resolution to the ‘excess’ abundances of Ge, P, W and Mo in the mantle, but the mantle composition alone cannot explain the excess abundances of nickel and cobalt in chondritic proportions. 相似文献