Are C1 chondrites chemically fractionated? a trace element study     

Mitsuru Ebihara  Rainer Wolf  Edward Anders 《Geochimica et cosmochimica acta》1982,46(10):1849-1861

Six C1 chondrite samples and a C2 xenolith from the Plainview H5 chondrite were analyzed by radiochemical neutron activation for the elements Ag, Au, Bi, Br, Cd, Ce, Cs, Eu, Ge, In, Ir, Lu, Nd, Ni, Os, Pd, Pt, Rb, Re, Sb, Se, Sn, Tb, Te, Tl, Yb, and Zn. The data were combined with 9 earlier analyses from this laboratory and examined for evidence of chemical fractionation in C1 chondrites.A number of elements (Br, Rb, Cs, Au, Re, Os, Ni, Pd, Sb, Bi, In, Te) show small but correlated variations. Those of the first 8 probably reflect hydrothermal alteration in the meteorite parent body, whereas those of Sb, Bi, In, and Te may at least in part involve nebular processes. Br and Au show systematic abundance differences from meteorite to meteorite, which suggests hydrothermal transport on a kilometer scale. The remaining elements vary from sample to sample, suggesting transport on a centimeter scale.There is no conclusive evidence for nebular fractionation affecting C1 's. Though C1 chondrites have lower $\text{Zr}\text{Hf}$ and $\text{Ir}\text{Re}$ ratios than do other chondrite classes, these ratios vary in other classes, suggesting that those classes rather than C1's are fractionated. Three fractionation-prone REE—Ce, Eu, and Yb have essentially the same relative abundances in C1's and all other chondrite classes, and hence apparently are not fractionated in C1's. We did not confirm the large Tb and Yb variations in C1's reported by other workers.We present revised mean C1 abundances for 35 elements, based on the new data and a critical selection of literature data. Changes are generally less than 10%, except for Br, Rb, Ag, Sb, Te, Au, and the REE.The Plainview C2 xenolith has normal trace element abundances, except for 3 elements falling appreciably above the C2 range: Rb, Cs, and Bi. Hydrothermal alteration may be the reason for all 3, though nebular fractionation remains a possibility for Bi.  相似文献   

Crustal transit time monitoring using PKP     

Max Wyss  R. Kind 《Pure and Applied Geophysics》1983,121(2):269-285

The arrival time difference for the AB branch of PKP from deep Tonga earthquakes is constant over years with a standard deviation of ±0.05 seconds at seismographs located 10 to 50 km from each other. If published travel time curves are used to calculate the relative residuals of PKP the standard deviation from the constant mean is improved by approximately 0.01 seconds for AB branch data. For the BC branch, standard deviations of relative travel times of ±0.06 seconds are reduced to less than ±0.05 seconds by calculating relative residuals. We conclude that changes of crustal transit time forP-waves could be resolved, based on careful PKP arrival time measurement at two or more neighboring stations if the changes exceed 0.05 sec and last for more than one year. The conditions for achieving this result are that PKP from Tonga earthquakes is clearly recorded, and that time-keeping is accurate. The data on which these conclusions are based were obtained from the Graefenberg seismograph array, which is located in West Gemany and consists of 13 stations separated by distances of 10 km to 100 km. We propose that relative arrival times of PKP from Tonga could be used in the Mediterranean - Middle East area to search for precursory travel time changes before large earthquakes.  相似文献   

On the existence of a relation between the Kolmogoroff and von Kármán constants     

Rainer Roth 《Boundary-Layer Meteorology》1970,1(2):131-136

A model is described, in which the mean vertical wind profile and turbulence spectra at different heights are calculated for a turbulent boundary layer without thermal stratification. The model makes use of Heisenberg's formula for the transfer of turbulent energy and is based on the assumption of a constant shearing stress in that boundary layer. As a result, a logarithmic wind profile follows with 0.39 as the value of von Kármán's constant, which is — in this model — strongly related to the inertial subrange of the turbulent energy spectra and therefore to the Kolmogoroff constant.This paper is based on studies done by the author during a one-year visit to CSIRO Division of Meteorological Physics, Aspendale, Australia, and was presented at the AGARD Specialists Meeting on The Aerodynamics of Atmospheric Shear Flows sponsored by the Fluid Dynamics Panel at Munich, Germany, during 15–17 Sept. 1969.  相似文献   

Thermal modeling of Carboniferous to Triassic sediments of the Karawanken Range (Southern Alps) as a tool for paleogeographic reconstructions in the Alpine–Dinaridic–Pannonian realm     

Gerd?RantitschEmail author  Thomas?Rainer 《International Journal of Earth Sciences》2003,92(2):195-209

Vitrinite reflectance was measured in Late Carboniferous to Triassic shales, siltstones and marls of the Karawanken Range. Thermal models of the central South-Karawanken Range were calibrated on the basis of these data. They suggest an eroded overburden of more than 3,200 m of Jurassic to Cretaceous sediments and a heat flow in the range of 42 to 60 mW m^?2 during the time of maximum subsidence. Because the reconstructed thermal history of the South-Karawanken Range is very similar to the thermal history of the Generoso basin (western Southern Alps), these data provide strong evidence for a deep basinal position of the Southern Karawanken Range during Jurassic to Cretaceous times. A vitrinite reflectance anomaly at the northern margin of the South-Karawanken Range is explained by advective heat transport during the Oligocene. The heat source for the anomalies at the western margin of the Seeberg Rise and in the area between the Periadriatic Lineament and the Donat Fault Zone is unknown. Vitrinite reflectance in Late Triassic sediments indicates the South-Karawanken Range and the South-Zala Unit of the Pannonian basement as exotic blocks in the Sava Composite Unit. This is explained by Miocene displacement of structural units, which were derived from different paleogeographical segments of the Permo-Mesozoic western Tethyan margin.  相似文献   

Long-Term Evolution of Objects in the Kuiper Belt Zone—Effects of Insolation and Radiogenic Heating     

Young-Jun ChoiMerav Cohen  Rainer MerkDina Prialnik 《Icarus》2002,160(2):300-312

The Kuiper Belt zone is unique insofar as the major heat sources of objects a few tens of kilometers in size—solar radiation on the one hand and radioactive decay on the other—have comparable power. This leads to unique evolutionary patterns, with heat waves propagating inward from the irradiated surface and outward from the radioactively heated interior. A major radioactive source that is considered in this study is ²⁶Al. The long-term evolution of several models with characteristics typical of Kuiper Belt objects is followed by means of a 1-D numerical code that solves the heat and mass balance equations on a spherically symmetric grid. The free parameters considered are radius (10-500 km), heliocentric distance (30-120 AU), and initial ²⁶Al content (0-5×10⁻⁸ by mass). The initial composition assumed is a porous mixture of ices (H₂O, CO, and CO₂) and dust. Gases released in the interior are allowed to escape to the surface. It is shown that, depending on parameters, the interior may reach quite high temperatures (up to 180 K). The models suggest that Kuiper Belt objects are likely to lose the ices of very volatile species during early evolution; ices of less volatile species are retained in a surface layer, about 1 km thick. The models indicate that the amorphous ice crystallizes in the interior, and hence some objects may also lose part of the volatiles trapped in amorphous ice. Generally, the outer layers are far less affected than the inner part, resulting in a stratified composition and altered porosity distribution. These changes in structure and composition should have significant consequences for the short-period comets, which are believed to be descendants of Kuiper Belt objects.  相似文献   

Sublimation pressure and sublimation enthalpy of H₂O ice Ih between 0 and 273.16 K     

Rainer Feistel  Wolfgang Wagner 《Geochimica et cosmochimica acta》2007,71(1):36-45

The sublimation of water in the region of extremely low pressures and temperatures meets increasing interest for the exploration of icy cosmic bodies. At temperatures below 130 K, the shape of the sublimation curve of H₂O is not known; neither experimental data nor theoretical treatments exist for this region. Based upon theoretical upper and lower bounds for the heat capacity of water vapor in this range, a narrow region in the pressure-temperature diagram is identified which must necessarily enclose the sublimation curve down to virtually any lower pressures and temperatures. Within this region, an approximate sublimation curve is computed from the 2006 Gibbs potential of ice Ih, using available heat capacity data points of water vapor between 10 and 130 K. The theoretical zero-point limiting law of the sublimation pressure is derived. Valid between 20 and 273.16 K, correlation equations for the sublimation enthalpy and the sublimation pressure are fitted to the computed data. All quantities are expressed in the 1990 temperature scale ITS-90. Under cosmic conditions, our results suggest that the sublimation of ice is unlikely below 50 K and impossible below 23 K.  相似文献   

Comparison of Galerkin-type discretization techniques for two-phase flow in heterogeneous porous media   总被引：1，自引：0，他引：1  

Rainer Helmig  Ralf Huber 《Advances in water resources》1998,21(8):545

A comparison of Standard Galerkin, Petrov-Galerkin, and Fully-Upwind Galerkin methods for the simulation of two-phase flow in heterogeneous porous media is presented. On the basis of the coupled pressure-saturation equations, a generalized formulation for all three finite element methods is derived and analysed. For flow in homogeneous media, the Petrov-Galerkin method gives excellent results. But this method fails miserably for problems with heterogeneous media. This is because it is not able to capture correctly processes that take place at interfaces when, for instance, the capillary pressure-saturation relationship after Brooks and Corey is assumed. The Fully-Upwind Galerkin method is superior to the Petrov-Galerkin approach because it is able to give correct results for flow in homogeneous and heterogeneous media for the two models of van Genuchten and Brooks-Corey. The widely used formulation which is correct for the homogeneous case cannot be used for heterogeneous media. Instead the straightforward approach of gradp_c in combination with a chord-slope technique must be utilized.  相似文献   

Geochronology of high-pressure rocks on Sifnos (Cyclades,Greece)     

Rainer Altherr  Manfred Schliestedt  Martin Okrusch  Eberhard Seidel  Hans Kreuzer  Wilhelm Harre  Heinz Lenz  Immo Wendt  Günther A. Wagner 《Contributions to Mineralogy and Petrology》1979,70(3):245-255

Polymetamorphic rocks of Sifnos (Greece) have been investigated by Rb-Sr, K-Ar, and fission track methods. Critical mineral assemblages from the northern and southernmost parts of Sifnos include jadeite+quartz+3T phengite, and omphacite+garnet +3T phengite, whereas the central part is characterized by the assemblage albite+chlorite+epidote+2M ₁ phengite.K-Ar and Rb-Sr dates on phengites (predominantly 3T) of the best preserved high P/itTmetamorphic rocks from northern Sifnos gave concordant ages around 42 m.y., indicating a Late Lutetian age for the high P/T metamorphism. Phengites (2M ₁+3T) of less preserved high P/T assemblages yielded K-Ar dates between 48 and 41 m.y. but generally lower Rb-Sr dates. The higher K-Ar dates are interpreted as being elevated by excess argon.K-Ar and Rb-Sr ages on 2M ₁ phengites from central Sifnos vary between 24 and 21 m.y. These ages date a second, greenschist-facies metamorphism which overprinted the earlier high-pressure metamorphic rocks.  相似文献   

Meteoritic material at four Canadian impact craters     

Rainer Wolf  Alicia B. Woodrow  Richard A.F. Grieve 《Geochimica et cosmochimica acta》1980,44(7):1015-1022

Eleven impact melt and 6 basement rock samples from 4 craters were analyzed by neutron activation for Au, Co, Cr, Fe, Ge, Ir, Ni, Os, Pd, Re and Se. Wanapitei Lake, Ontario: the impact melts show uniform enrichments corresponding to 1–2% C1-chondrite material. Interelement ratios ($\text{Co}\text{Cr}$, $\text{Ni}\text{Cr}$, $\text{Ni}\text{Ir}$) suggest that the impacting body was a Cl-, C2-, or LL-chondrite. Nicholson Lake, North West Territory: Ni, Cr and Co are distinctly more enriched than Ir and Au which tentatively suggests an olivine-rich achondrite (nakhlite or ureilite). Gow Lake, Saskatchewan and Mistastin, Labrador: small enrichments in Ir and Ni; both the low $\text{Ir}\text{Ni}$ ratios and low Cr content suggest iron meteorites, but the signals are too weak for conclusive identification.A tentative comparison of meteoritic signatures at 10 large, ≥4km craters and their presumed celestial counterparts (13 Apollo and Amor asteroids) shows more irons and achondrites among known projectile types, and a preponderance of S-type objects, having no known meteoritic equivalent, among asteroids. It is not yet clear that these differences are significant, in view of the tentative nature of the crater identifications (achondrites in particular), and the limited statistics.  相似文献   

Gibt es Zusammenhänge zwischen Erdbeben und Gebirgsschlaghäufungen im Bergbau Bleiberg?     

H. Rainer 《Rock Mechanics and Rock Engineering》1974,6(2):91-100

ZusammenfassungGibt es Zusammenhänge zwischen Erdbeben und Gebirgsschlaghäufungen im Bergbau Bleiberg Langjährige Beobachtungen beim Bergbau Bleiberg lassen den Schluß zu, daß dieselben Spannungen in der Erdkruste, welche Erdbeben auslösen, auch Gebirgsschlaghäufungen hervorrufen. Im besonderen wirkt sich auf Bleiberg offenbar die durch den Mittelmeerraum führende Erdbebenzone aus. Aber auch Unruhen anderer Teile der Erdkruste, so jene des Karibischen Raumes, scheinen Einfluß zu haben. Von Erdbeben der südamerikanischen Pazifikküste konnte nach unseren Aufzeichnungen kein Einfluß abgeleitet werden.

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SummaryAre there Connexions Between Earthquakes and the Frequency of Rock Bursts in the Mine of Bleiberg Observations, that were done in the mine of Bleiberg, allow the conclusion, that the same stresses in the earth's crust, which cause earthquakes cause higher frequencies of rock bursts, to. Specially the area of earthquakes around the Mediterranean has effects on Bleiberg. But also other parts of the earth's crust in particular those of the Caribbean area, seem to have their effects. Effects caused by earthquakes of the South-American Pacific-Coast could not be derived from our records.

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RésuméRelations entre des tremblements de terre et des coups de rupture de roche Des observations faites durant des années dans la mine de Bleiberg on permis de conclure, que les contraintes dans l'écorce terrestre qui provoque des séismes suscitent également une augmentation de la fréquence des coups de rupture de roche. En particulier, Bleiberg est sous l'influence de la zone sismique de la région de la Méditerranée, mais il semble, que d'autres régions de l'écorce terrestre, par exemple celles de la région caraibe, ont une influence sur la région mentionnée. Par contre selon les enregistrements effectués on a pas pu constaté une influence des séismes de la côte sud-américaine du Pacifique sur cette région.

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Vortrag, gehalten während des XXII. Geomechanik-Kolloquiums im Oktober 1973 in Salzburg.

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Mit 7 Abbildungen  相似文献