Characterizing heterogeneous permeable media with spatial statistics and tracer data using sequential simulated annealing     

Akhil Datta-Gupta  Larry W. Lake  Gary A. Pope 《Mathematical Geology》1995,27(6):763-787

Characterizing heterogeneous permeable media using flow and transport data typically requires solution of an inverse problem. Such inverse problems are intensive computationally and may involve iterative procedures requiring many forward simulations of the flow and transport problem. Previous attempts have been limited mostly to flow data such as pressure transient (interference) tests using multiple observation wells. This paper discusses an approach to generating stochastic permeability fields conditioned to geologic data in the form of a vertical variogram derived from cores and logs as well as fluid flow and transport data, such as tracer concentration history, by sequential application of simulated annealing (SA). Thus, the method incorporates elements of geostatistics within the framework of inverse modeling. For tracer-transport calculations, we have used a semianalytic transit-time algorithm which is fast, accurate, and free of numerical dispersion. For steady velocity fields, we introduce a transit-time function which demonstrates the relative importance of data from different sources. The approach is illustrated by application to a set of spatial permeability measurements and tracer data from an experiment in the Antolini Sandstone, an eolian outcrop from northern Arizona. The results clearly reveal the importance of tracer data in reproducing the correlated features (channels) of the permeability field and the scale effects of heterogeneity.  相似文献   

Crystallization processes in an artificial magma: variations in crystal shape,growth rate and composition with melt cooling history     

Nelia W. Dunbar  Gary K. Jacobs  Michael T. Naney 《Contributions to Mineralogy and Petrology》1995,120(3-4):412-425

A large (4.8 m³, 1.3x10⁷ g) artificial mafic melt with a bulk composition similar to that of a basalt (but with a high CaO content of 17 wt%) was generated during a demonstration of in situ vitrification and was allowed to cool naturally. During the melting process, convection was vigorous, resulting in a chemically and thermally homogeneous melt body. Once heating was complete, the cooling rate was rapid with the temperature dropping from 1500°C to 500°C in 6 days within the interior of the 3 m diameter, 1.5 m thick body. A 20 h period of constant temperature (1140°C) observed during colling was the result of latent heat released by widespread crystallization. The final crystalline assemblage consists of diopsidic to hedenbergitic pyroxene and anorthitic feldspar, with a subordinate amount of potassic feldspar, plus a small amount of evolved glass. The compositions and proportions of phases agree well with those predicted by the MELTS thermodynamic model. Thermal and textural evidence suggest that convection within the melt ceased coincident with formation of the first crystals. Textural investigation of core samples reveals large (up to 1 cm in length) acicular diopsidic pyroxenes in a matrix of smaller feldspar and zoned pyroxene crystals (500 m in length). Crystal shape and pyroxene composition vary as a function of position within the solidified body, as a function of cooling rate. Both crystal size and degree of crystallinity are highest in the central, most slowly-cooled parts of the rock. Crystal shape is characterized by tabular, equilibrium-growth forms in the slowly-cooled areas, grading to highly skeletal, dendritic forms at the rapidly-cooled edges of the body. The pyroxene crystals are dominantly homogeneous diopside, but crystals are characterized by thin Fe-rich hedenbergitic rims. These rims were deposited when Mg in the melt was depleted by diopside growth, and melt temperature had cooled sufficiently to allow Fe-rich pyroxene growth. Crystal growth rates can be calculated based on thermal behavior of the melt, reinforced by thermodynamic modelling, and are determined to be between 10^-7 and 10^-8 cm/s in the central part of the melt. These estimates agree well with growth rates in natural systems with similar cooling rates. Pyroxene crystals that formed at a higher cooling rates are characterized by higher Al and lower Mg contents relative to tabular equilibrium crystalline forms, presumably as a result of disequilibrium melt compositions at the crystal-melt interface.New Mexico Bureau of Mines and Mineral Resources, New Mexico Institute of Mining and Technology, Socorro, NM 87801, USA  相似文献   

Geochemical Evidence for Subduction Fluxes, Mantle Melting and Fractional Crystallization Beneath the South Sandwich Island Arc   总被引：31，自引：11，他引：20  

PEARCE  JULIAN A.; BAKER  PETER E.; HARVEY  PETER K.; LUFF  IAN W. 《Journal of Petrology》1995,36(4):1073-1109

The volcanoes of the South Sandwich island arc follow threedistinct series: low-K tholeiitic (followed by Zavodovski, Candlemas,Vindication, Montagu and Bristol), tholeiitic (followed by Visokoi,Saunders and Bellinghausen) and calcalkaline (followed by Leskov,Freehand and part of Cook and Thule). Flux calculations indicatethat the percentage contribution of the subduction componentto the mantle source of all three series varies from undetectable(e.g. Zr) through small (e.g. Nd=20%) and moderate (e.g. La,Ce, Sr=50–80%) to dominant (e.g. Pb, K, Ba, Rb, Cs >90%)with little change along the arc. Isotope systematics (Pb, Nd,Sr) show that this subduction component obtains a greater contributionfrom altered oceanic crust than from pelagic sediment. Elementsfor which the subduction contribution is small show that themantle is already depleted relative to N-MORB mantle (equivalentto loss of an 2•5% melt fraction) before melting beneaththe arc. After addition of the subduction component, dynamicmelting of this depleted mantle then causes the variations inK that distinguish the three series. The estimated degree ofpartial melting (20%) is slightly greater than that beneathocean ridges, though geothermometry suggests that the primarymagma temperature (1225C) is similar to that of primary MORB.About half of the melting may be attributed to volatile addition,and half to decompression. Dynamic melting involving three-dimensional,two-phase flow may be needed to explain fully the inter-islandvariations. KEY WORDS: geochemistry; petrology; fluxes; melting; subduction ^*Corresponding author  相似文献   

Melt Extraction during Formation of K-Feldspar + Sillimanite Migmatites, West of Revelstoke, British Columbia   总被引：1，自引：1，他引：0  

NYMAN  MATTHEW W.; PATTISON  DAVID R. M.; GHENT  EDWARD D. 《Journal of Petrology》1995,36(2):351-372

An exposure of sillimanite-rich, strongly deformed, stromatic,K-feldspar-bearing migmatites in the Monashee Terrane west ofRevelstoke, British Columbia, has been examined to determinethe process of migmatization and to evaluate whether the systemwas open or closed during leucosome formation. An anatecticorigin for the migmatites is supported by: (1) the minimum meltcomposition of the leucosomes; (2) textures suggesting a fluidbehavior of the leucosomes and local pegmatitic textures; and(3) P–T estimates (720–820C; 75–9 kbar)above vaporabsent melting conditions of muscovitt + quartz. To establish whether melt was extracted or added during migmatization,measured volume percents of leucosome were compared with estimatesof melt production modeled by muscovite + quartz dehydrationmelting. Quantitative estimates of volume percent of leucosomeat present in the outcrop are between 20 and 30%. The amountof melt produced from the model muscovite dehydration meltingreaction is constrained by measured modal percent of sillimanite(15–25%) in the outcrop and is dependent on modal proportionof muscovite in the unmelted protolith and the melt water contentUsing a muscovite-rich protolith and a melt water content of4 wt%, complete dehydration melting of muscovite results ina production of 54 vol % melt and 25 vol % sillmanite, indicatinga melt loss of 29 vol %. A melt water content of 6 wt% resultsin production of 41 vol % melt and 23 vol % sillimanite, indicatinga melt loss of 16 vol %. Melt loss may have occurred by meltmovement along foliation planes during flattening, during formationof shear bands or locally along subvertical fractures. Spatialproximity of the outcrop to the Monashee dcollement suggeststhat thrusting was localized to zones of high melt production,which in turn facilitated melt migration. KEY WORDS: migmatites; British Columbia; Monashee Tarrane; anatexis; melt extraction ^*Corresponding author. Present address: Department of Earth and Planetary Sciences, The Univenity of New Mexico, Albuquerque, NM 817131, USA  相似文献   

Molecular indicators for palaeoenvironmental change in a Messinian evaporitic sequence (Vena del Gesso, Italy). II: High-resolution variations in abundances and 13C contents of free and sulphur-bound carbon skeletons in a single marl bed     

Kenig F  Damsté JS  Frewin NL  Hayes JM  De Leeuw JW 《Organic Geochemistry》1995,23(6):485-526

The extractable organic matter of 10 immature samples from a marl bed of one evaporitic cycle of the Vena del Gesso sediments (Gessoso-solfifera Fm., Messinian, Italy) was analyzed quantitatively for free hydrocarbons and organic sulphur compounds. Nickel boride was used as a desulphurizing agent to recover sulphur-bound lipids from the polar and asphaltene fractions. Carbon isotopic compositions (delta vs PDB) of free hydrocarbons and of S-bound hydrocarbons were also measured. Relationships between these carbon skeletons, precursor biolipids, and the organisms producing them could then be examined. Concentrations of S-bound lipids and free hydrocarbons and their delta values were plotted vs depth in the marl bed and the profiles were interpreted in terms of variations in source organisms, 13 C contents of the carbon source, and environmentally induced changes in isotopic fractionation. The overall range of delta values measured was 24.7%, from -11.6% for a component derived from green sulphur bacteria (Chlorobiaceae) to -36.3% for a lipid derived from purple sulphur bacteria (Chromatiaceae). Deconvolution of mixtures of components deriving from multiple sources (green and purple sulphur bacteria, coccolithophorids, microalgae and higher plants) was sometimes possible because both quantitative and isotopic data were available and because either the free or S-bound pool sometimes appeared to contain material from a single source. Several free n-alkanes and S-bound lipids appeared to be specific products of upper-water-column primary producers (i.e. algae and cyanobacteria). Others derived from anaerobic photoautotrophs and from heterotrophic protozoa (ciliates), which apparently fed partly on Chlorobiaceae. Four groups of n-alkanes produced by algae or cyanobacteria were also recognized based on systematic variations of abundance and isotopic composition with depth. For hydrocarbons probably derived from microalgae, isotopic variations are well correlated with those of total organic carbon. A resistant aliphatic biomacromolecule produced by microalgae is, therefore, probably an important component of the kerogen. These variations reflect changes in the depositional environment and early diagenetic transformations. Changes in the concentrations of S-bound lipids induced by variations in conditions favourable for sulphurization were discriminated from those related to variations in primary producer assemblages. The water column of the lagoonal basin was stratified and photic zone anoxia occurred during the early and middle stages of marl deposition. During the last stage of the marl deposition the stratification collapsed due to a significant shallowing of the water column. Contributions from anaerobic photoautotrophs were apparently associated with variations in depth of the chemocline.  相似文献   

Powder- and single crystal Mössbauer spectroscopy on synthetic fayalite     

W. Lottermoser  K. Forcher  G. Amthauer  H. Fuess 《Physics and Chemistry of Minerals》1995,22(4):259-267

Mössbauer measurements on synthetic iron orthosilicate Fe₂SiO₄ (fayalite) were carried out in the antiferromagnetic spin state below T _N 65 K. The Mössbauer parameters isomer shift , inner magnetic field H(0), angle between H(0) and the z-component of the electric field gradient (efg), quadrupole splitting QS and asymmetry parameter were determined as a function of temperature. These parameters could be attributed to the two crystallographic sites M1 and M2.The smaller isomer shift on M1 with respect to M2 displays the more covalent character of the Fe-O bond on M1, which is supported by previous neutron diffraction experiments. H(0) shows a Brillouin-type behaviour with different fields on the two crystallographic sites (stronger on M1) and a small discontinuity at T = 23 K which corresponds with previous magnetic measurements. The quadrupole splitting is equal on both sites within error bars, in agreement with previous theoretical results and in contradiction to previous Mössbauer refinements published elsewhere.  相似文献   

The Panafrican Stratoid Granites of Madagascar: Alkaline Magmatism in a Post-Collisional Extensional Setting   总被引：6，自引：0，他引：6  

NDLEC  ANNE; STEPHENS  EDRYD W.; FALLICK  ANTHONY E. 《Journal of Petrology》1995,36(5):1367-1391

A major alkali province of late Panafrican age occupies centralMadagascar and takes the form of a thick sequence of ‘stratoid’(sheet-like)granites emplaced in a mid-crustal gneissic basement This alkalinemagmatism has been interpreted as a consequence of extensionaltectonics accompanying the collapse of the Mozambique belt.The rocks belong to three petrographic types: subsolvus granites,hypersolvus alkaline granites and syenites. Major and traceelement analyses have typical A-type characteristics. Two distinctmagmatic suites are recognized: a mildly alkaline suite includingall the subsolvus granites and a strongly alkaline suite includingthe hypersolvus alkaline granites and the syenites. We proposethat the mildly alkaline suite was derived from a granodioriticcrustal protolith. Some of the strongly alkaline granites andthe quartz syenites display low ¹⁸O isotopic signatures of around+6.The parental magmas for this suite are most probably of mantlederivation. The more evolved compositions are consistent withcrystal fractionation processes. Contemporaneous alkaline silicicplutonismoccurs in many parts of the Panafrican belt of Eastern Africa;however, sheet-like intrusions have rarely been described. Asa large-scale province, the nearest analogues of the stratoidgranites of Madagascar are the rapakivi granites of earlierProterozoic age in Scandinavia and Greenland. KEY WORDS: alkaline granite; Madagascar; Panafrican; pastcollisional magmatism ^*Corresponding author  相似文献   

Analysis of COMPTEL gamma-ray burst locations and spectra     

R. M. Kippen  J. Ryan  A. Connors  M. McConnell  C. Winkler  L. O. Hanlon  V. Schönfelder  J. Greiner  M. Varendorff  W. Collmar  W. Hermsen  L. Kuiper 《Astrophysics and Space Science》1995,231(1-2):231-234

In its first three years of operation, the COMPTEL instrument on theCompton Gamma-Ray Observatory has measured the locations (mean accuracy 1°) and spectra (0.75-30 MeV) of 18 gamma-ray bursts and continues to observe new events at a rate of 1/month. With good angular resolution and sensitivity at MeV energies, the growing COMPTEL burst catalog is an important new piece of evidence in the on-going GRB mystery. The COMPTEL burst locations are consistent with an isotropic distribution of sources, yet the spatial coincidence of two of the bursts indicates the possibility of repetition. The COMPTEL burst spectra are in most cases consistent with a single power law model with spectral index in the range 2–3. However, two bursts show evidence of a spectral break in the MeV range. Measurement of rapid variability at MeV energies in the stronger bursts provides evidence that either the sources are nearby (within the Galaxy) or the gamma-ray emission is relativistically beamed. We present an overview of analysis results obtained from the COMPTEL burst catalog concentrating on the search for burst repetition and the implications of highly variable MeV emission.  相似文献   

Search for low energyν e,μ,τ andv e,μ,τ in coincidence with BATSE gamma ray bursts     

M. Aglietta  P. Antonioli  G. Badino  G. Bologna  C. Castagnoli  A. Castellina  V. L. Dadykin  W. Fulgione  P. Galeotti  F. F. Khalchukov  E. V. Korolkova  P. V. Kortchaguin  V. B. Kortchaguin  V. A. Kudryavtsev  A. S. Malguin  L. Periale  V. G. Ryassny  O. G. Ryazhskaya  O. Saavedra  G. Trinchero  S. Vernetto  C. Vigorito  V. F. Yakushev  G. T. Zatsepin 《Astrophysics and Space Science》1995,231(1-2):355-358

A search for low energy neutrinos of all flavours in correlation with 553 ray bursts detected by BATSE aboard the Compton Observatory has been performed by the LSD (Liquid Scintillator Detector) neutrino telescope. No excess ofe,, orv _e,, candidate has been detected by LSD during the time interval in which BATSE detected the 90% of the photon flux for any of the GRBs analyzed. Upper limits on the neutrino fluxes are given in the paper.  相似文献   

New kinematic distances of NGC 7009 and BD+30°3639 from UV and radio data     

W. J. Maciel 《Astrophysics and Space Science》1995,229(2):203-213

Measurements of the equivalent width of the interstellar Lyman line from IUE spectra in the direction of the planetary nebulae NGC 7009 and BD+30°3639 are used to infer the H column density in these directions. Hydrogen 21 cm profiles are also used in connection with the ultraviolet data so that the expected rotation velocities and distances can be determined. The results are compared with recently published distances, in an attempt to distinguish between the short and long PN distance scales as applied to these objects.  相似文献