Petroleum Hydrocarbon Bioventing Kinetics Determined in Soil Core, Microcosm, and Tubing Cluster Studies   总被引：2，自引：0，他引：2  

Ellen E. Moyer  David W. Ostendorf  Robin J. Richards  Steve Goodwin 《Ground Water Monitoring & Remediation》1996,16(1):141-153

Aerobic biodegradation of vapor-phase petroleum hydrocarbons was evaluated in an intact soil core from the site of an aviation gasoline release. An unsaturated zone soil core was subjected to a flow of nitrogen gas, oxygen, water vapor, and vapor-phase hydrocarbons in a configuration analogous to a biofilter or an in situ bioventing or sparging situation. The vertical profiles of vapor-phase hydrocarbon concentration in the soil core were determined by gas chromatography of vapor samples. Biodegradation reduced low influent hydrocarbon concentrations by 45 to 92 percent over a 0.6-m interval of an intact soil core. The estimated total hydrocarbon concentration was reduced by 75 percent from 26 to 7 parts per million. Steady-state concentrations were input to a simple analytical model balancing advection and first-order biodegradation of hydrocarbons. First-order rate constants for the major hydrocarbon compounds were used to calibrate the model to the concentration profiles. Rate constants for the seven individual hydrocarbon compounds varied by a factor of 4. Compounds with lower molecular weights, fewer methyl groups, and no quaternary carbons tended to have higher rate constants. The first-order rate constants were consistent with kinetic parameters determined from both microcosm and tubing cluster studies at the field site.  相似文献   

Reducing global warming — The role of rice     

Heinz-Ulrich Neue  Lewis H. Ziska  Robin B. Matthews  Qiujie Dai 《GeoJournal》1995,35(3):351-362

Activities to provide energy for an expanding population are increasingly disrupting and changing the concentration of atmospheric gases that increase global temperature. Increased CO₂ and temperature have a clear effect on growth and production of rice as they are key factors in photosynthesis. Rice yields could be increased with increased levels of CO₂, however, the rise of CO₂ may be accompanied by an increase in global temperature. The effect of doubling CO₂ levels on rice production was predicted using rice crop models. They showed different effects of climate change in different countries. A simulation of the Southeast Asian region indicated that a doubling of CO₂ increases yield, whereas an increase in temperature decreases yield.Enhanced UV-B radiation resulting for stratographic ozone depletion has been demonstrated to significantly reduce plant height, leaf area and dry weight of two rice cultivars under glasshouse conditions. Data are still insufficient, however, for conclusive results on the effect of UV-B radiation on rice growth under field conditions.Rice production itself has a significant effect on global warming and atmospheric chemistry through methane emission from flooded ricefields. Water regime, soil properties and the rice plant are major factors controlling the flux of methane in ricefields. Global and regional estimates of methane emission rates are still highly uncertain and tentative. Integration of mechanistic modeling of methane fluxes with geographic information systems of factors controlling these processes are required to improve estimates and predictions.  相似文献   

LNAPL Retention in Sandy Soil     

David W. Ostendorf  Robin J. Richards  Frank P. Beck 《Ground water》1993,31(2):285-292

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Analysing Pumping Tests by Resistance Network Analogue     

Robin Herbert 《Ground water》1968,6(2):12-18

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Oxide minerals in lithic fragments from Luna 20 fines     

Robin Brett  R.C Gooley  Eric Dowty  Martin Prinz  Klaus Keil 《Geochimica et cosmochimica acta》1973,37(4):761-773

One hundred and seventy-six oxide mineral grains in the Luna 20 samples were analyzed by electron microprobe. Spinel is the most abundant oxide, occurring in troctolite fragments. Next most abundant is ilmenite, which occurs in all rock types except those containing spinel. Chromite also occurs in all rock types except those containing spinel. Minor amounts of ulvöspinel, armalcolite, zirkelite, baddeleyite and an unidentified TiO₂-rich phase were also found.Spinel grains are predominantly spinel-hercynite solid solutions, commonly with very minor chromite. The $\text{Fe}\text{(Fe + Mg)}$ ratio is generally lower than in spinel from Apollo 14 rocks. Chromites in non-mare rocks are similar to those from mare rocks. Ilmenite of mare origin is Mg-poor and Zr-rich compared to non-mare ilmenite; these elements may therefore be useful in determining the origin of ilmenite grains.Phase equilibria considerations suggest that spinel troctolite crystallized from a melt high in alumina; a likely candidate is the high-alumina basalt of Prinzet al. (1973a).Sub-micron wide rods of metallic Fe occur in plagioclase grains and may have formed by sub-solidus reduction processes.  相似文献   

A lunar core of Fe-Ni-S     

Robin Brett 《Geochimica et cosmochimica acta》1973,37(1):165-170

Several workers have proposed that lunar samples were magnetized by a field created by a lunar core of molten Fe. Low abundances of siderophile elements in lunar rocks are compatible with formation of a metallic lunar core. A molten Fe core requires that the bulk of the Moon was above, or close to, the melting point, a requirement which disagrees with most models of the lunar thermal regime.A core (or perhaps a layer or pockets) of molten Fe-Ni-S, at or close to the eutectic composition would act as a lunar dynamo, and be at a temperature (approx. 1000°C) consistent with some reasonable models of lunar thermal history. The existence of a Fe-Ni-S core would also partly explain the depletion in volatile elements in lunar basalts. Such a core, occupying up to 20 per cent of the Moon's radius requires a bulk S content for the moon of only 0.3 wt per cent.  相似文献   

The lunar crust: a product of heterogeneous accretion or differentiation of a homogeneous Moon?     

Robin Brett 《Geochimica et cosmochimica acta》1973,37(12):2697-2703

The outer portion of the Moon including the Al-rich crust and the source regions of mare basalts was either accreted heterogeneously or was the product of widespread differentiation of an originally homogeneous source. A number of constraints make the heterogeneous accretion model unlikely; the differentiation model appears more plausible.If the differentiation model is correct, a series of cumulate rocks complimentary to the Al-rich crustal rocks must exist. The mare basalts may have been derived from such a complimentary cumulate for several reasons. For example, Philpottset al. (1973) on the basis of REE studies, suggest that Apollo 11 and 17 mare basalts were formed by partial melting of a cumulate rich in a phase(s) containing high Ti and heavy REE. The high Ti of Apollo 11 and 17 basalts is not readily explained in terms of partial melting of an undifferentiated mantle, but is consistent with partial melting of a pyroxene cumulate enriched in Fe, Ti oxides. The characteristic Fe-rich nature of mare basalts would be partly a consequence of melting of oxide cumulate minerals. It is postulated that the plagioclase-poor source region of mare basalts was enriched in an intercumulus residual liquid. During the partial melting that produced mare basalts, this material was largely incorporated into the melt, thus explaining the ancient model ages observed in most mare basalts. If the cumulate model is correct, then samples derived from the true (undifferentiated) lunar mantle have not been identified.  相似文献   

Application of multiple sublethal stress indicators to assess the health of fish in Pamlico Sound following extensive flooding   总被引：1，自引：0，他引：1  

S.?Marshall?AdamsEmail author  Mark?S.?Greeley  J.?McHugh?Law  Edward?J.?Noga  Judith?T.?Zelikoff 《Estuaries and Coasts》2003,26(5):1365-1382

Multiple indicators of sublethal stress (bioindicators) were used to assess the health and condition of two important estuarine fish species in the Pamlico Sound estuary following extensive flooding from three sequential hurricanes that occurred during early fall 1999. Bioindicators ranging from the biochemical to the reproductive and organism-level were used to assess the health of southern flounder and spot in Pamlico Sound compared to the health of these same species sampled from a relatively unaffected references site in lower Core Sound. Many of the physiological, reproductive, immunological, histopathological, and general condition indices suggested that both species, and particularly spot, in Pamlico Sound were sublethally stressed and in poorer condition than fish sampled from Core Sound. The major environmental stressors causing these sublethal stress responses in Pamlico Sound fish appears to be those related to episodic hypoxic exposure or a combination of effects associated with hypoxic conditions such as alterations in preferred habitat and food availability. Although fish populations in Pamlico Sound do not appear to be severely damaged or impaired at this time, organisms that are sublethally stressed can incur increased vulnerability to additional or future stressors such as modified physicochemical regimes, changes in food and habitat availability, and increases in infectious pathogens. Because of the low flushing rate (～1 yr) of Pamlico Sound, recovery rate may be exceptionally slow, prolonging any adverse effects of altered nutrient regimes (such as hypoxia) on the health and fitness of resident fish populations. Flooding from the 1999 hurricanes may have contributed to the short-term health and condition of finfish species in Pamlico Sound and also influenced longer-term recovery and ecological status of this system. Longer-term manifestation of effects from flooding may be of particular concern as the frequency of hurricanes is expected to increase over the next few years and the accelerated uses of the coastal zone places further stress on estuarine resources.  相似文献   

Institutional Adaptation of Water Resource Infrastructures to Climate Change in Eastern Ontario   总被引：1，自引：1，他引：1  

P. Crabbé  M. Robin 《Climatic change》2006,78(1):103-133

Institutional barriers and bridges to local climate change impacts adaptation affecting small rural municipalities and Conservation Authorities (CAs are watershed agencies) in Eastern Ontario (Canada) are examined, and elements of a community-based adaptation strategy related to water infrastructures are proposed as a case-study in community adaptation to climate change. No general water scarcity is expected for the region even under unusually dry weather scenarios. Localized quantity and quality problems are likely to occur especially in groundwater recharge areas. Some existing institutions can be relied on by municipalities to build an effective adaptation strategy based on a watershed/region perspective, on their credibility, and on their expertise. Windows of opportunity or framing issues are offered at the provincial level, the most relevant one in a federal state, by municipal emergency plan requirements and pending watershed source water protection legislation. Voluntary and soon to be mandated climate change mitigation programs at the federal level are other ones.  相似文献   

Two-dimensional maps in multi-dimensional worlds: A case of community-based mapping in Northern Thailand     

Robin Roth 《Geoforum》2007,38(1):49-59

Community-based mapping has become a necessary tool for development work worldwide - its adoption is near hegemonic. Mapping community land, however, can have unforeseen consequences in part due to its tendency to render what are complex configurations of social-ecological relationships into two-dimensional form. I argue that one of the key limitations to commonly practiced community-based mapping is the assumption that the spatial organization of resource use and management is an abstract entity that can be mapped independent of the social relations that produce it. This paper uses a case study from Northern Thailand to show how mapping techniques that fix and simplify fluid and complex associations can inadvertently prescribe changes to how residents manage their land, effectively becoming not only a tool for securing land tenure but also a tool for the spatial re-organization of land-use and management.  相似文献