The tropospheric distribution of formaldehyde during TROPOZ II     

D. W. Arlander  D. Brüning  U. Schmidt  D. H. Ehhalt 《Journal of Atmospheric Chemistry》1995,22(3):251-269

A series of 149 measurements of the HCHO mixing ratio were made between 0 and 10 km altitude and 70° N to 60° S latitude during TROPOZ II. The data show a vertical decrease of the HCHO mixing ratio with altitude at all latitudes and a broad latitudinal maximum in the HCHO mixing ratio between 30° N and 30° S at all altitudes. The measured mixing ratios of HCHO are considerably higher than those expected from CH₄ oxidation alone, but agree broadly with the average latitude by altitude distribution of HCHO derived by a 2D model including emissions of C₁–C₇ hydrocarbons. A number of the regional scale deviations of the measured HCHO distribution from the average modelled one can be explained in terms of the local wind field.  相似文献   

Vertical column abundances of HCN deduced from ground-based infrared solar spectra: Long-term trend and variability     

E. Mahieu  C. P. Rinsland  R. Zander  P. Demoulin  L. Delbouille  G. Roland 《Journal of Atmospheric Chemistry》1995,20(3):299-310

A set of high-resolution IR solar spectra recorded at the International Scientific Station of the Jungfraujoch, Switzerland, from 84/06 to 93/06, and at the National Solar Observatory McMath-Pierce solar telescope facility on Kitt Peak, Arizona, U.S.A. from 78/05 to 92/07 have been analyzed to determine the vertical column abundances of hydrogen cyanide, HCN, above the two stations. The analysis was based on least-squares curve fitting of calculated spectra to the observations encompassing the P4 and the P8 lines of HCN respectively located at 3299.5273 and 3287.2483 cm^–1. The results obtained for the two stations indicate that no significant long-term trend affects either of the two databases; however, this analysis reveals variable increases during springtime of up to a factor of 2 in the HCN total column above the Jungfraujoch and even up to 3 above Kitt Peak. The calculated mean vertical column abundances, excluding the spring observations, are equal to (2.55±0.30)×10¹⁵ molec./cm² (S.D.) and (2.75±0.30)×10¹⁵ molec./cm² respectively above the Jungfraujoch and the Kitt Peak observatories. Based on a realistic volume mixing ratio profile, these columns translate into mean volume mixing ratios equal to 190×10^–12 ppv at the respective altitudes of the stations.  相似文献   

Cyclotella-taxa (Bacillariophyceae) in lakes of the Alpine region and their relationship to environmental variables     

Sybille Wunsam  Roland Schmidt  Rolf Klee 《Aquatic Sciences - Research Across Boundaries》1995,57(4):360-386

Surface sediment diatom assemblages for 86 Alpine lakes were analysed focusing on the dominant genusCyclotella and corresponding environmental data. The range of morphological variability of theCyclotella bodanica/radiosa, C. distinguenda, C. ocellata, C. comensis andC. stelligera complexes was documented. Significance tests included in the canonical correspondence analysis (CCA) indicated that total phosphorus, conductivity and surface water temperature were significantly correlated withCyclotella taxa assemblage distribution. Numerical species optima and tolerances were calculated in respect to these significant variables using weighted averaging (WA) regression and calibration. CCA and WA were able to provide information about the environmental preferences of the various morphotypes observed.  相似文献   

Vertical profiles of wind speed,snow concentration,and humidity in blowing snow   总被引：1，自引：1，他引：1  

R. A. Schmidt 《Boundary-Layer Meteorology》1982,23(2):223-246

To estimate the sublimation rate of snow during relocation by wind, sizes and concentration of ice crystal fragments were measured at 6 levels in the lowest 1 m, during ten 10-min runs, in a nocturnal blizzard. Power-law functions of height described the decrease in mean particle diameter and concentration. The vertical gradient of water vapor, measured with a thermocouple psychrometer, was approximately linear from 0.2 to 1.0m above the surface. Evaporation of blowing snow over 3 km of transport distance was estimated to be 39% of transport rate, under conditions of the experiment.  相似文献   

ΣDDT and PCBs in equatorial Atlantic organisms     

Rolf Roland Weber 《Marine pollution bulletin》1983,14(7):274-275

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A comparison between the fabric camera and texture goniometer methods of fabric analysis by X-ray diffraction     

Professor John Starkey  Stefan Schmidt 《International Journal of Earth Sciences》1983,72(2):529-539

The effects of grain size on the analysis of fabrics by X-ray diffraction using both the fabric camera and the texture goniometer are discussed. Simple calculations show the interdependance between the mean grain diameter and the number of crystals which are measured by each instrument. The effects of both grain size and modal composition of the specimen are illustrated by comparative analyses. Both the fabric camera and texture goniometer are well suited to the analysis of specimens in which the mean grain diameter is between approximately 10 and 100 microns. The texture goniometer is more suitable when the grain size is less than this, while the fabric camera is better suited when the grain size is coarser, especially when the specimen is not monomineralic.  相似文献   

Supporting large-scale hydrogeological monitoring and modelling by time-variable gravity data   总被引：1，自引：0，他引：1  

Andreas Güntner  Roland Schmidt  Petra Döll 《Hydrogeology Journal》2007,15(1):167-170

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Upper-mantle structure of the Baltic Shield below the Swedish National Seismological Network (SNSN) resolved by teleseismic tomography     

Tuna Eken  Z. Hossein Shomali  Roland Roberts  Reynir Bödvarsson 《Geophysical Journal International》2007,169(2):617-630

Upper-mantle structure under the Baltic Shield is studied using non-linear high resolution teleseismic P -phase tomography. Observed relative arrival-time residuals from 52 teleseismic earthquakes recorded by the Swedish National Seismological Network (SNSN) are inverted to delineate the structure of the upper mantle. The network consists of 47 (currently working) three-component broad-band stations located in an area about 450 km wide and 1450 km long. In order to reduce complications due to possible significant three-dimensionality of Earth structure, events chosen for this study lay close to in-line with the long-axis of the array  (±30°)  . Results indicate P -wave velocity perturbations of ±3 per cent down to at least 470 km below the network. The size of the array allows inversion for structures even at greater depths, and lateral variations of velocity at depths of up to 680 km appear to be resolved. Below the central part of the array (60°–64° N), where ray coverage is best, the data reveals a large region of relatively low velocity at depths of over about 300 km. At depths less than about 250–300 km, the models include a number of features, including an apparent slab-like structure dipping gently towards the north.  相似文献   

Dual models of pore spaces     

Roland Glantz  Markus Hilpert 《Advances in water resources》2007

We present a model for pore spaces that consists of two parts related by duality: (1) a decomposition of an open polyhedral pore space into open contractible pore bodies separated by relatively open interfaces and (2) a pore network that is homotopy equivalent to the pore space. The dual model is unique and free of parameters, but it relies on regularity conditions for the pore space. We show how to approximate any pore space by the interior of a polyhedral complex such that the regularity conditions are fulfilled. Thus, we are able to calculate the dual model from synthetic porous media and images of real porous media. The pore bodies are unions of relatively open Delaunay cells with respect to the corners of the pore boundary, and the pore network consists of certain at most two-dimensional (2D) Voronoi cells with respect to the corners of the pore boundary. The pore network describes the neighborhood relations between the pore bodies. In particular, any relatively open 2D Delaunay face f separating two pore bodies has a unique (relatively open) dual network edge. In our model, f is a pore throat only if it is hit by its dual network edge. Thus, as opposed to widespread intuition, any pore throat is convex, and adjacent pore bodies are not necessarily separated by pore throats. Due to the duality between the pore network and the decomposition of the pore space into pore bodies it is straightforward to store the geometrical properties of the pore bodies [pore throats] as attributes of the dual network vertices [edges]. Such an attributed network is used to perform 2D drainage simulations. The results agree very well with those from a pore-morphology based modeling approach performed directly on the digital image of a porous medium. Contractibility of the pore bodies and homotopy equivalence of the pore space and the pore network is proven using discrete Morse theory and the nerve theorem from combinatorial topology.  相似文献   

Equilibrium and disequilibrium degassing of a phonolitic melt (Vesuvius AD 79 “white pumice”) simulated by decompression experiments     

Giada Iacono Marziano  Burkhard C. Schmidt  Daniela Dolfi 《Journal of Volcanology and Geothermal Research》2007

Equilibrium and disequilibrium degassing of a volatile phase from a magma of K-phonolitic composition was investigated to assess its behavior upon ascent. Decompression experiments were conducted in Ar-pressurized externally heated pressure vessels at superliquidus temperature (1050 °C), in the pressure range 10–200 MPa using pure water as fluid phase. All experiments were equilibrated at 200 MPa and then decompressed to lower pressures with rates varying from 0.0028 to 4.8 MPa/s. Isobaric saturation experiments were performed at the same temperature and at 900–950 °C to determine the equilibrium water solubility in the pressure range 30–250 MPa. The glasses obtained from decompression experiments were analyzed for their dissolved water content, vesicularity and bubble size distribution. All decompressed samples presented a first event of bubble nucleation at the capsule–melt interface. Homogeneous bubble nucleation in the melt only occurred in fast-decompressed experiments (4.8 and 1.7 MPa/s), for ΔP ≅ 100 MPa. For these decompression rates high water over-saturations were maintained until a rapid exsolution was triggered at ΔP > 150 MPa. For slower rates (0.0028, 0.024, 0.17 MPa/s) the degassing of the melt took place by diffusive growth of the bubbles nucleating at the capsule–melt interface. This process sensibly reduced water over-saturation in the melt, preventing homogeneous nucleation to occur. For decompression rates of 0.024 and 0.17 MPa/s low water over-saturations were attained in the melt, gradually declining toward equilibrium concentrations at low pressures. A near-equilibrium degassing path was observed for a decompression rate of 0.0028 MPa/s. Experimental data combined with natural pumice textures suggest that both homogeneous and heterogeneous bubble nucleations occurred in the phonolitic magma during the AD 79 Vesuvius plinian event. Homogeneous bubble nucleation probably occurred at a depth of ∼ 3 km, in response to a fast decompression of the magma during the ascent.  相似文献