Geoid anomalies over two South Atlantic fracture zones     

Adam P. Freedman  Barry Parsons 《Earth and Planetary Science Letters》1990,100(1-3)

Seasat altimetry profiles across the Falkland-Agulhas fracture zone (FZ) and the Ascension FZ in the South Atlantic were examined for evidence of step-like geoid offsets predicted from thermal modeling of the lithosphere. The geoid profiles exhibit much short-wavelength power and the step-like offsets are often small, making reliable estimation of the heights of the observed geoid offsets difficult. The offsets were estimated by the least-squares fitting of quadratic curves incorporating a step function to the altimetry profiles. A preferred offset value was determined for each profile by taking the average of step heights computed with various distances around the fracture zone excluded from the fit. The age of the crust surrounding the fracture zones, necessary for computing a theoretical geoid offset, was determined from surface ship magnetic anomaly data and from existing ocean floor age maps.Observed variations in geoid step height with age of the lithosphere are not consistent with those predicted from standard thermal plate models. For ages less than 30 Ma, the step offsets across both fracture zones decrease in a manner appropriate for an unusually thin plate with a thickness of 50–75 km. At greater ages, the offsets show complex behavior that may be due to bathymetric features adjacent to the fracture zones. Similar geoid patterns on opposite branches of the Falkland-Agulhas FZ are indicative of processes that act symmetrically on both sides of the Mid-Atlantic Ridge. This behavior of the geoid is consistent both with small-scale convection occurring beneath the lithosphere and with bathymetric features originally produced along the ridge crest and now located symmetrically on opposite sides of the ridge. The west flank of the Ascension FZ displays a regrowth in step height at about 40 Ma consistent with small-scale convection and in agreement with other studies of Pacific and South Atlantic fracture zones.  相似文献   

Residence of trace elements in metasomatized spinel lherzolite xenoliths: a proton-microprobe study   总被引：19，自引：0，他引：19  

Suzanne Y. O'Reilly  W. L. Griffin  C. G. Ryan 《Contributions to Mineralogy and Petrology》1991,109(1):98-113

Minerals occurring in dry and modally metasomatized spinel lherzolites from western Victoria have been analysed by proton microprobe for Ni, Cu, Zn, Ga, Rb, Sr, Y, Zr, Nb, Ba, Pb, Br, rare-earth elements (REE), Th and U. Mass-balance calculations demonstrate that these trace elements are contained in specific acceptor minerals and do not occur in significant concentrations at clean grain boundaries. The level of particular trace elements in the rock depends on the presence of specific phases: for example high levels of REE, Sr (and U, Th, Br) require apatite, while Ba, Nb and Ta are strongly concentrated in amphibole±mica. Mantle metasomatism in these spinel lherzolites is inferred to result from an open-system process involving infiltration of fluids released by crystallizing silicate melts. This process produces metasomatic zones with different modal mineralogy and hence greatly different trace-element signatures. The data demonstrate that large-ion-lithophile (LIL) and high-field strength (HFS) elements in metasomatized spinel lherzolites are strongly concentrated in non-refractory phases, which will break down easily in heated volumes such as the walls of magma conduits. The heterogeneity observed in trace-element patterns of intraplate alkali basaltic rocks may not reflect source heterogeneity, but may result largely from contamination by metasomatized mantle wall rock. The K_Ds for most trace elements show little temperature dependence except for K_DSr between orthopyroxene and clinopyroxene where K_D decreases with increasing temperature. The generally uniform K_Ds can be used to test for disequilibrium in such assemblages.  相似文献   

The structure of the stably stratified internal boundary layer in offshore flow over the sea     

J. R. Garratt  B. F. Ryan 《Boundary-Layer Meteorology》1989,47(1-4):17-40

Observations obtained mainly from a research aircraft are presented of the mean and turbulent structure of the stably stratified internal boundary layer (IBL) over the sea formed by warm air advection from land to sea. The potential temperature and humidity fields reveal the vertical extent of the IBL, for fetches out to several hundred of kilometres, geostrophic winds of 20–25 m s^–1, and potential temperature differences between undisturbed continental air and the sea surface of 7 to 17 K. The dependence of IBL depth on these external parameters is discussed in the context of the numerical results of Garratt (1987), and some discrepancies are noted.Wind observations show the development of a low-level wind maximum (wind component normal to the coast) and rotation of the wind to smaller cross-isobar flow angles. Potential temperature () profiles within the IBL reveal quite a different structure to that found in the nocturnal boundary layer (NBL) over land. Over the sea, profiles have large positive curvature with vertical gradients increasing monotonically with height; this reflects the dominance of turbulent cooling within the layer. The behaviour is consistent with known behaviour in the NBL over land where curvature becomes negative (vertical gradients of decreasing with height) as radiative cooling becomes dominant.Turbulent properties are discussed in terms of non-dimensional quantities, normalised by the surface friction velocity, as functions of normalised height using the IBL depth. Vertical profiles of these and the normalised wavelength of the spectral maximum agree well with known results for the stable boundary layer over land (Caughey et al., 1979).  相似文献   

Biogeochemical prospecting for uranium in Nova Scotia     

R.R. Brooks  J. Holzbecher  D.J. Robertson  D.E. Ryan 《Journal of Geochemical Exploration》1982,16(3):189-195

Ashed twigs of Picea rubens (red spruce) collected over an area of uranium mineralization in central Nova Scotia were analyzed for uranium in the course of biogeochemical prospecting for this element. Uranium levels in background samples were significantly lower than in those collected from areas with mineralization either at depth or on the surface. Scintillometric data were useful only to differentiate background and surface mineralization. Uranium levels in soils showed no correlation whatsoever with mineralization or with radiometry. There was a very high degree of correlation between the scintillometric data and uranium concentrations in ashed twigs and it is considered that twigs of Picea rubens might be successfully used for biogeochemical prospecting for uranium in this area.  相似文献   

'Driving people crazy': A geography of boy racers in Christchurch, New Zealand     

Ryan Falconer  Simon Kingham 《New Zealand geographer》2007,63(3):181-191

Abstract:   So-called 'boy racers' form a subculture, which is subject to ongoing public scrutiny and media attention, usually negative. This study aimed to deconstruct the term 'boy racer' and to explore the subculture in detail, within the context of Christchurch, New Zealand, using a phenomenological ethnographic approach. This included conducting semistructured interviews and observing the activities of participants. Results show the subculture has a relatively diverse membership and a range of associated behaviours, activities and attitudes. Moreover, performances within the subculture are linked to place, and are seen by other members of the community as threats to normative boundaries.  相似文献   

Gravity anomalies and crustal shortening in the eastern Mediterranean   总被引：1，自引：0，他引：1  

Philip D. Rabinowitz  William B. F. Ryan 《Tectonophysics》1970,10(5-6):585-608

Crustal shortening of the ocean floor in the eastern Mediterranean is recognized by a marked thickening of the sedimentary layer seaward of the Hellenic and Calabrian island arcs. Steep gradients and large negative free-air anomalies in the gravity field along with a highly uniform, low regional heat flow are manifestations of the thickened crust. Bodies of recently deformed sediment in and seaward of the Hellenic Trough reveal the style, polarity, and dynamics of the thickening mechanism.

A linear buried anticlinal structure, inferred from analysis of surface ship gravity profiles, may mark the site of contemporary intrabasinal underthrusting. The distribution of earthquakes beneath the Mediterranean Ridge supports the interpretation that the Anaximander, Ptolomy, and Strabo Mountains are features comparable to large basement nappes. Cyprus is one such structure, offset to the south, where the oceanic crust and part of the upper mantle have been involved in the décollement.  相似文献   

Comments on “The crustal structure of the Balearic Sea” — in light of deep-sea drilling in the Mediterranean     

K.J. Hsü  W.B.F. Ryan   《Tectonophysics》1973,20(1-4):303-306

Supplementary to the paper by K. Hinz on The crustal structure of the Balearic Sea, some results are reported from the deep-sea drilling cruise of the “Glomar Challenger”.  相似文献   

Modification Of The Standard ∈-Equation For The Stable Abl Through Enforced Consistency With Monin–Obukhov Similarity Theory     

Frank R. Freedman  Mark Z. Jacobson 《Boundary-Layer Meteorology》2003,106(3):383-410

A condition is derived for consistency of the standard-equation with Monin–Obukhov (MO) similarity theory of thestably-stratified surface layer. The condition is derivedby extending the procedure used to derive the analogous condition forneutral theory to stable stratification. It is shown that consistencywith MO theory requires a function of flux Richardson number, Ri_f, to be absorbed into either of two closure parameters, c ₁ or c ₂.Inconsistency, on the other hand, results if constant values of these are maintained for all Ri_f, as is done in standardapplication of the equation, and the large overpredictions ofturbulence found in such application to the one-dimensionalstable atmospheric boundary layer (1D-SBL) are traced to thisinconsistency. Guided by this, we formulate a MO-consistent-equation by absorbing the aforementioned function intoc ₁, and combine this with a Level-2.5 second-orderclosure model for vertical eddy viscosity and diffusivities.Numerical predictions of the 1D-SBL by the modified model converge to a quasi-steady state, rectifying the predictive failure of the standard -equation for the case.Quasi-steady predictions of non-dimensional variables agree stronglywith Nieuwstadt's theory. Qualitative accuracy of predictionsis inferred from comparisons to field data, large-eddy simulationresults and Rossby-number similarity relationships.  相似文献   

Single-Column Model Intercomparison for a Stably Stratified Atmospheric Boundary Layer   总被引：2，自引：15，他引：2  

J. Cuxart  A. A. M. Holtslag  R. J. Beare  E. Bazile  A. Beljaars  A. Cheng  L. Conangla  M. Ek  F. Freedman  R. Hamdi  A. Kerstein  H. Kitagawa  G. Lenderink  D. Lewellen  J. Mailhot  T. Mauritsen  V. Perov  G. Schayes  G-J. Steeneveld  G. Svensson  P. Taylor  W. Weng  S. Wunsch  K-M. Xu 《Boundary-Layer Meteorology》2006,118(2):273-303

The parameterization of the stably stratified atmospheric boundary layer is a difficult issue, having a significant impact on medium-range weather forecasts and climate integrations. To pursue this further, a moderately stratified Arctic case is simulated by nineteen single-column turbulence schemes. Statistics from a large-eddy simulation intercomparison made for the same case by eleven different models are used as a guiding reference. The single-column parameterizations include research and operational schemes from major forecast and climate research centres. Results from first-order schemes, a large number of turbulence kinetic energy closures, and other models were used. There is a large spread in the results; in general, the operational schemes mix over a deeper layer than the research schemes, and the turbulence kinetic energy and other higher-order closures give results closer to the statistics obtained from the large-eddy simulations. The sensitivities of the schemes to the parameters of their turbulence closures are partially explored.  相似文献   

Probing the oxidation-reduction properties of terrestrially and microbially derived dissolved organic matter   总被引：5，自引：0，他引：5  

Ryan L. Fimmen  Rose M. Cory  Tamara D. Trouts 《Geochimica et cosmochimica acta》2007,71(12):3003-3015

Dissolved organic matter (DOM) has been shown to be an integral component in biogeochemical electron transfer reactions due to its demonstrated ability to facilitate redox reactions. While the role of DOM as a facilitator of electron transfer processes has been demonstrated, greater knowledge would lead to better understanding of the structural components responsible for redox behavior, such as quinones and nitrogen and sulfur (N/S) functional groups. This investigation uses direct scan voltammetry (DSV) coupled with fluorescence and NMR spectroscopy as well as thermochemolysis gas chromatography mass spectrometry (GC-MS) and X-ray photoelectron spectroscopy (XPS) to elucidate the organic moieties responsible for facilitating electron transfer reactions. We contrast electrochemical properties and structural details of three organic matter isolates from diverse sources; Great Dismal Swamp DOM (terrestrially derived, highly aromatic), Pony Lake DOM (microbially derived, highly aliphatic) and Toolik Lake (terrestrially derived, photochemically and microbially altered) with juglone (a redox-active model quinone). Aromatic and phenolic constituents were detected (by ¹³C NMR) and recovered (by thermochemolysis GC-MS) from all three fulvic acid samples, highlighting the ubiquity of these compounds and suggesting that the quinone-phenol redox couple is not limited to DOM derived from lignin precursors. The range of hydroxy-benzene and benzoic acid derivatives may explain the lack of a single pair of well-defined oxidation and reduction peaks in the DSV scans. The presence of a wide-range of hydroxylated benzoic acid isomers and other redox-active aromatic residues implies that native DOM possesses overlapping redox potentials analogous to their characteristic range of pK_a values.  相似文献