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61.
The Significance of the Mesostasis of Basic Layered Igneous Rocks   总被引:4,自引:1,他引:3  
HENDERSON  P. 《Journal of Petrology》1970,11(3):463-473
Many layered igneous rocks consist of two main parts: the cumulus(plus adcumulus and heteradcumulus) material and the pore material,or mesostasis, produced by the crystallization of the trappedliquid. Knowledge of the chemistry of the mesostasis will beuseful in deducing magma fractionation trends and in the determinationof solid/liquid trace element partition coefficients, whichin turn will be significant in helping to elucidate the petrogeneticrelationship between certain basalts and layered gabbros. Anew geochemical method for the determination of both the compositionand amount of mesostasis in layered rocks is proposed. Thismethod uses elements of contrasting behaviour and is best appliedto rhythmically layered rocks rich in mafic or felsic minerals.Data on strontium, cobalt, and uranium are used to apply themethod to two rocks from the Skaergaard intrusion. The resultsobtained are in agreement with published data.  相似文献   
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Abstract— We report the results of a study of TS2, an unusual compact Type A inclusion from Allende. A distinctive, major feature of this inclusion is that many of its melilite crystals have no dominant core-rim zoning but instead consist of 50–200 μm patches of Mg-rich melilite (Åk32–62, median Åk51) set in or partially enclosed by, and optically continuous with, relatively Al-rich melilite (Åk25–53, median Åk38). The Al-rich regions have jagged, dendritic shapes but occur within crystals having straight grain boundaries. Another unusual feature of this inclusion is the size and spatial distribution of spinel. In many places, especially in the interior of the inclusion, the aluminous melilite encloses numerous, fine (0.5–5 μm) inclusions of spinel and minor perovskite and fassaite. The latter phases also occur as isolated grains throughout the inclusion. Coarse-grained spinel, ~50–150 μm across, occurs in clumps and chains enclosed in relatively Mg-rich melilite, whereas none of the fine spinel grains are clumped together. The sample also contains a spinel-free palisade body, 1.7 × 0.85 mm, that consists almost entirely of Åk-rich (45–65 mol%) melilite. Within the palisade body are two grains of perovskite with extremely Nb-rich (~4–8 wt% Nb2O5) cores and rims of typical composition. All phases in this inclusion have chondrite-normalized REE patterns that are consistent with crystal/melt partitioning superimposed upon a bulk modified Group II pattern. We suggest that TS2 had an anomalous cooling history and favor the following model for the formation of TS2. Precursors having a bulk modified Group II pattern melted. Rapid growth of large, dendritic, nonstoichiometric melilite crystals occurred. The melilite trapped pockets of melt and incorporated excess spinel components and TiO2. Bubbles formed in the residual melt. As crystallization slowed, coarse spinel grew. Some spinel grains collected against bubbles, forming spherical shells, and others formed clumps and chains. Relatively Åk-rich melilite crystallized from the residual melt between dendritic melilite crystals and from melt trapped in pockets and between arms of dendrites, and incorporated the clumps and chains of coarse spinel. Bubbles broke and filled with late-stage melt, their shapes preserved by their spinel shells. Slow cooling, or perhaps an episode of reheating, allowed the early melilite to become stoichiometric by exsolving fine grains of spinel, perovskite and fassaite, and allowed the melilite to form smooth grain boundaries. Dendritic crystals are indicative of rapid growth and the melilite crystals in TS2 appear to be dendritic. Coarse, dendritic melilite crystals have been grown from Type B inclusion melts cooled at ~50–100 °C/h. If those results are applicable to Type A inclusions, we can make the first estimate of the cooling rate of a Type A inclusion, and it is outside the range (2–50 °C/h) generally inferred for Type B inclusions. The rapid cooling inferred here may be part of an anomalous thermal history for TS2, or it may be representative of part of a normal thermal history common to Types A and B that involved rapid cooling early (at high temperatures) as inferred for TS2, and slower cooling later (at lower temperatures), as inferred for Type B inclusions. We prefer the former explanation; otherwise, the unusual features of TS2 that are reported here would be common in Type A inclusions (which they are not).  相似文献   
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ABSTRACT. Tensions and contradictions surround photographic representations of landscape—and the practices that created those representations—during the medium's so-called golden age in the late nineteenth century. These are examined by focusing on the landscape views of H. H. Bennett, a photographer of considerable renown whose stereographs and oversized panoramas of the Wisconsin Dells transformed a working river into a picturesque landscape. Such a construction of genteel tourist space in Victorian America suggests a post-frontier aesthetic in which nature is valued less as an opportunity for progress or an occasion for terror than as pleasing scenery.  相似文献   
68.
Metamorphism in the Adirondacks: II. The Role of Fluids   总被引:6,自引:2,他引:4  
Quantitative estimates of metamorphic fluid speciation, stableisotopic analyses, and studies of fluid inclusions all documentthe local complexity of fluids in the deep crustal rocks exposedin the Adirondack Mountains, NY. Estimates of the activity ofH2O in the granulite facies are substantially lower than inthe amphibolite facies gneisses. The onset of low water activitiesin semi-pelitic gneisses generally correlates with migmatitictextures in the uppermost amphibolite facies, suggesting thatpartial melts absorbed H2O at the peak of metamorphism. In granulitefacies marbles and calc-silicates, conditions varied from extremelyundersaturated in H2O-CO2 fluid to fluid saturated, and H2Oand CO2 show sharp gradients within single outcrops. Low valuesof fO2 and fH2O, or of fCO2, and fH2O indicate fluid-absentconditions for some orthogneisses and marbles, which are inferredto have been ‘dry’ rocks before and during granulitefacies recrystallization. Wollastonite is preserved from earlycontact metamorphism and serves as an index mineral for fluid-absentconditions in granulites where H2O is low. Values offO2 rangefrom near the hematite + magnetite buffer in metamorphosed ironformation to substantially below the quartz + magnetite + fayalitebuffer in some orthogneisses. The anorthosite suite is moreoxidized than some associated granitic gneisses. Halogens (Fand Cl) substitute extensively for OH in micas and amphiboles,extending their stability, although F2, Cl2, HCl, and HF areminor components in any fluid. Oxybiotite-type exchanges involvingO for OH are also important, extending the stability of biotite.Stable isotopic ratios of O and C demonstrate that premetamorphicwhole-rock compositions are commonly preserved whereas mineralcompositions generally reflect equilibration at the peak ofmetamorphism. The Marcy Anorthosite Massif was intruded as ahigh 18O magma. The combination of mineral equilibria, stable isotope data,and fluid inclusions is used to identify and to distinguishamong pre-orogenic contact metamorphic/hydrothermal events,peak metamorphic events, and retrograde/postmetamorphic events.Polymetamorphism is documented at skarn zones adjacent to anorthosite,where large volumes of hydrothermal fluid were channeled duringearly, shallow contact metamorphism and where conditions werefluid poor during subsequent regional metamorphism. Peak metamorphicevents are inferred to have been caused primarily by magmaticprocesses of intrusion and anatexis. Partial melting has causedlow values of H2O in many rocks, but in other cases low valuesof H2O are recorded in orthogneisses derived from H2O-poor magmas.Isotopic studies show that maximum fluid/rock ratios were <0?land possibly 0?0 for infiltrating fluids at the peak of metamorphismin many localities. No evidence of pervasive, regional infiltrationby a fluid at the peak of metamorphism has been substantiatedin the Adirondacks. Fluid inclusions containing high-densityCO2 or CO2 + H2O represent conditions from after the peak ofmetamorphism and document isobaric cooling, in agreement withestimates from garnet zoning. Fine-scale retrograde veins arecommon and are associated with high-density CO2-rich fluid inclusions.  相似文献   
69.
Metamorphism in the Adirondacks. I. Petrology, Pressure and Temperature   总被引:3,自引:2,他引:3  
Grenville Supergroup sediments and suites of pre- and syn-tectonicigneous rocks have been metamorphosed to the upper amphiboliteand granulite facies in the Adirondacks of northern New Yorkduring the Grenville orogeny about one billion years ago. Magnetite-ilmenite, alkali feldspar-plagioclase, calcite-dolomiteand garnet-clinopyroxene thermometry indicate that metamorphictemperatures (T) increase from about 650 ?C in the area westand northwest of Gouverneur to 700–750 ?C near Coltonand along the Lowlands-Highlands boundary to 750–800 ?Cin areas within and around the Marcy anorthosite massif. Thepresence of grossular-rich garnet + quartz without wollastonite+ plagioclase in calc-silicate rocks and the apparent absenceof metamorphic ferropigeonite in charnockites restrict maximummetamorphic T to less than 800–850 ?C. Metamorphic pressures (P), determined from coexisting pyrite-pyrrhotite-sphalerite,garnet-rutile-sillimanite-ilmenite-quartz, fayalite-quartz-ferrosilite,fayalite-anorthite-garnet, ferrosilite-anorthite-garnet-quartz,kyanite-sillimanite, anorthite-garnet-sillimanite-quartz andthe stability of akermanite, are 6?5–7?0 kb near Gouverneurand increase to 7?5–8?0 kb in the central Adirondack Highlands. The above P-T data deduced from diverse mineralogical/chemicalsystems are interpreted as peak or near-peak conditions forAdirondack metamorphism. The compositions of thin retrograderims on garnets indicate a post-peak-metamorphic P-T path forthe Adirondacks with appreciable cooling (200–300?) beforedecompression. Peak and retrograde P-T conditions inferred forthe Adirondacks are similar to numerous other granulite terranessuggesting that similar tectonothermal events are necessaryfor the formation of many granulite belts.  相似文献   
70.
A 45 km long barrier island exists west of the town of Guerrero Negro, Mexico, along the western coast of the Baja California peninsula, about 720 km south of San Diego, California. This barrier has developed in a mesotidal, arid-climate regime characterized by steady, strong, onshore winds from the NW. The barrier island W of Guerrero Negro has prograded seaward about 1·6 km in the last 1800 years while an aeolian dunefield fed by sand blown from beaches has advanced inland up to 13 km. Landward progradation of the dune system from the barrier has occurred during relative rise in sea-level; thus, aeolian sediments exist at or below the water table over a wide area. The progradation of dunes across marshes, tidal flats, and tidal channels, as well as the repeated submergence of interdune areas by tidal waters, has created a complex suite of mixed aeolian and subaqueous sediments in the back barrier. The complexity of the suites of aeolian sedimentary structures, together with the inclusion of subaqueously formed structures such as current and oscillation ripples, would make recognition of the aeolian origin of much of the sediments difficult in ancient rocks. In addition to the scientific importance of recognizing the aeolian deposits, the sedimentation model represented by the Guerrero Negro barrier has applications in petroleum exploration and development. Currently, most preservational models for barrier islands attach little volumetric importance to aeolian deposits. This modern example suggests that volumetrically significant aeolian deposits can be preserved behind a barrier, particularly in an arid-climate regime. If preserved and charged with oil, the resulting productive sandstone could have an extremely irregular landward edge comprised in part of onshore-prograded aeolian dune sandstone with excellent reservoir characteristics. As with current barrier models, the reservoir would be sealed landward and above by lagoonal mudstone and silt, evaporites, or evaporitic, sandy sabkha deposits. High organic productivity occurs in lagoons immediately adjacent to the dunefields of Guerrero Negro, suggesting that organic-rich source rock may exist near aeolian sandstone in ancient settings similar to Guerrero Negro.  相似文献   
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