Convergent lines of molecular, carbon-isotopic, and phylogenetic evidence have previously indicated (Hinrichs, K.-U., Hayes, J.M., Sylva, S.P., Brewer, P.G., DeLong, E.F., 1999. Methane-consuming archaebacteria in marine sediments. Nature 398, 802–805.) that archaea are involved in the anaerobic oxidation of methane in sediments from the Eel River Basin, offshore northern California. Now, further studies of those same sediments and of sediments from a methane seep in the Santa Barbara Basin have confirmed and extended those results. Mass spectrometric and chromatographic analyses of an authentic standard of sn-2-hydroxyarchaeol (hydroxylated at C-3 in the sn-2 phytanyl moiety) have confirmed our previous, tentative identification of this compound but shown that the previously examined product was the mono-TMS, rather than di-TMS, derivative. Further analyses of 13C-depleted lipids, appreciably more abundant in samples from the Santa Barbara Basin, have shown that the archaeal lipids are accompanied by two sets of products that are only slightly less depleted in 13C. These are additional glycerol ethers and fatty acids. The alkyl substituents in the ethers (mostly monoethers, with some diethers) are non-isoprenoidal. The carbon-number distributions and isotopic compositions of the alkyl substituents and of the fatty acids are similar, suggesting strongly that they are produced by the same organisms. Their structures, n-alkyl and methyl-branched n-alkyl, require a bacterial rather than archaeal source. The non-isoprenoidal glycerol ethers are novel constituents in marine sediments but have been previously reported in thermophilic, sulfate- and nitrate-reducing organisms which lie near the base of the rRNA-based phylogenetic tree. Based on previous observations that the anaerobic oxidation of methane involves a net transfer of electrons from methane to sulfate, it appears likely that the non-archaeal, 13C-depleted lipids are products of one or more previously unknown sulfate-reducing bacteria which grow syntrophically with the methane-utilizing archaea. Their products account for 50% of the fatty acids in the sample from the Santa Barbara Basin. At all methane-seep sites examined, the preservation of aquatic products is apparently enhanced because the methane-oxidizing consortium utilizes much of the sulfate that would otherwise be available for remineralization of materials from the water column. 相似文献
The lithium abundances of planet-harbouring stars have been compared with the lithium abundances of open clusters and field stars. Young (chromospherically active) and subgiant stars have been eliminated from the comparison because they are at different stages of evolution and Li processing than the planet-harbouring stars, and hence have systematically higher Li abundances. The analysis showed that the Li abundances of the planet-harbouring stars are indistinguishable from those of non-planet-harbouring stars of the same age, temperature and composition. This conclusion is opposite to that arrived at by Gonzalez & Laws; it is believed that the field-star sample used by them contained too wide a range of ages, evolutionary types and temperatures to be accommodated by the model that they adopted to describe the dependence of Li on the parameters. The Li abundance does not appear set to provide key insights into the formation and evolution of planetary systems. 相似文献
We have used echelle spectra of resolving power 35 000 to derive chemical abundances and the 12C/13C ratio in the 1.9-d carbon Cepheid RT TrA and the Cepheid U TrA, employed as a comparison star. We confirm that RT TrA is very metal-rich with [Fe/H]=+0.4. In addition, C and N are substantially in excess, and a small deficiency in O is present. We interpret these anomalies as resulting from the appearance on the stellar surface of material enriched in 12C by the 3- α process, followed by CNO cycling to convert 12C to 13C and 14N. In addition, some 16O has been processed to 14N. The partial processing of 16O to 14N indicates that substantial 17O may be present. Proton capture seems to have enhanced 23Na from the Ne isotopes. 相似文献
When the National Weather Service (NWS) issues a tornado warning, the alert is rapidly and widely disseminated to individuals in the general area of the warning. Historically, the assumption has been that a false-negative warning perception (i.e., when someone located within a warning polygon does not believe they have received a tornado warning) carries a higher cost than a false-positive warning perception (i.e., when someone located outside the warning area believes they have received a warning). While many studies investigate tornado warning false alarms (i.e., when the NWS issues a tornado warning, but a tornado does not actually occur), less work focuses on studying individuals outside of the warning polygon bounds who believe they received a warning (i.e., false-positive perceptions). This work attempts to quantify the occurrence of false-positive perceptions and possible factors associated with the rate of occurrence. Following two separate storm events, Oklahomans were asked whether they perceived a tornado warning. Their geolocated responses were then compared to issued warning polygons. Individuals closer to tornado warnings or within a different type of warning (e.g., a severe thunderstorm warning) are more likely to report a false-positive perception than those farther away or outside of other hazard warnings. Further work is needed to understand the rate of false-positive perceptions across different hazards and how this may influence warning response and trust in the National Weather Service.
Regional development has evolved in response to shifting local and global priorities. These shifts have transformed both the way we think about regions, their role and how that shapes the outcomes and benefits that might occur from engaging in regional development. Key debates centre around the ability (or desirability) of regional development interventions to unsettle path dependence and “lock‐in” created by past approaches and to create opportunities for alternative development futures and to provide choices between sectoral‐based investments to support economic activity in contrast to a more place‐based approach to regional development. This paper overviews the dynamic nature of regional development to offer reasons for its recent resurgence by highlighting the key debates about the purpose and function of regions and what regional development can or should do. We then discuss the New Zealand context specifically and use the first year of Provincial Growth Fund investments to reflect on how the processes, objectives and goals reflect particular interpretations of the meaning and purpose of regional development. We conclude that a strong adherence to a growth imperative has the potential to reinforce path dependencies at the expense of alternative development pathways. 相似文献
A significant percentage of the smaller urban centres around the world are losing people which raises questions regarding the appropriate responses to this challenge. Responses from the state have generally been muted, and as a result, concepts of new localism and new regionalism are useful for understanding the role played by place‐based leadership and partnerships between local businesses, community groups and individuals. Key within this space is the role of endogenous responses anchored on local social capital and resilience. This paper overviews key themes in the literature before examining statistical evidence of small town growth, stabilisation or decline in New Zealand. This leads into an examination of how three small towns in the country are responding to demographic and economic change. The cases illustrate the importance of local‐led responses to the debilitating effects of change and the degree to which place based development can be critical in the context of coping with change in small towns. The paper further argues that “right‐sizing” to a new economic and demographic reality may be the appropriate focus of local attention. 相似文献