Amino acids derived from Titan tholins     

Khare BN  Sagan C  Ogino H  Nagy B  Er C  Schram KH  Arakawa ET 《Icarus》1986,68(1):176-184

An organic heteropolymer (Titan tholin) was produced by continuous dc discharge through a 0.9 N2/0.1 CH4 gas mixture at 0.2 mbar pressure, roughly simulating the cloudtop atmosphere of Titan. Treatment of this tholin with 6N HCl yielded 16 amino acids by gas chromatography after derivatization of N-trifluroacetyl isopropyl esters on two different capillary columns. Identifications were confirmed by GC/MS. Glycine, aspartic acid, and alpha- and beta-alanine were produced in greatest abundance; the total yield of amino acids was approximately 10(-2), approximately equal to the yield of urea. The presence of "nonbiological" amino acids, the absence of serine, and the fact that the amino acids are racemic within experimental error together indicate that these molecules are not due to microbial or other contamination, but are derived from the tholin. In addition to the HCN, HC2CN, and (CN)2 found by Voyager, nitriles and aminonitriles should be sought in the Titanian atmosphere and, eventually, amino acids on the surface. These results suggest that episodes of liquid water in the past or future of Titan might lead to major further steps in prebiological organic chemistry on that body.  相似文献   

Volume transport of the western boundary current penetrating into a marginal sea   总被引：2，自引：0，他引：2  

Shinya Minato  Ryuji Kimura 《Journal of Oceanography》1980,36(4):185-195

The amount of penetration of a western boundary current into a marginal sea which is connected to an open ocean by two narrow straits is estimated from a linear, steady and barotropic theoretical model. In this model the western boundary current in the open ocean is driven by a wind stress imposed at the sea surface. The inflow of the water of the open ocean into the marginal sea is caused by the pressure difference between two straits produced by the wind-driven circulation in the open ocean.Main external parameters are combined into two non-dimensional parameters; and (the ratio of the depth of the marginal sea to that of the open ocean), whereb is the distance between north and south boundaries of the ocean,D ₀ is the depth of the open ocean, is the latitudinal variation of the Coriolis parameter andR is the coefficient of friction. The friction is assumed to be proportional to the flow velocity.In the limit of infinite the volume transport into the marginal sea is not affected by the width of two straits and . It is mainly controlled by the wind stress and the positions of two straits. For finite values of , however, the volume transport depends considerably on and the width of the straits.Guided by both this model and physical considerations, we obtained a relation between the volume transport into the marginal sea and the external parameters. This relation predicts that about 2 % of the volume transport of the Kuroshio penetrates into the Japan Sea.  相似文献   

Properties of sea ice and overlying snow in the Southern Sea of Okhotsk     

Takenobu Toyota  Shinya Takatsuji  Kazutaka Tateyama  Kazuhiro Naoki  Kay I. Ohshima 《Journal of Oceanography》2007,63(3):393-411

The general properties of sea ice and overlying snow in the southern Sea of Okhotsk were examined during early February of 2003 to 2005 with the P/V “Soya”. Thin section analysis of crystal structure revealed that frazil ice (48% of total core length) was more prevalent than columnar ice (39%) and that stratigraphic layering was prominent with a mean layer thickness of 12 cm, indicating that dynamic processes are essential to ice growth. The mean thickness of ice blocks and visual observations suggest that ridging dominates the deformation process above thicknesses of 30 to 40 cm. As for snow, it was found that faceted crystals and depth hoar are dominant (78%), as which is also common in the Antarctic sea ice, and is indicative of the strong vertical temperature gradients within the snow. Stable isotope measurements (δ¹⁸O) indicate that snow ice occupies 9% of total core length and that the mass fraction of meteoric ice accounts for 1 to 2% of total ice volume, which is lower than the Antarctic sea ice. Associated with this, the effective fractionation coefficient during the freezing of seawater was also derived. Snow ice was characterized by lower density, higher salinity, and nearly twice the gas content of ice of seawater origin. In addition, it is shown that the surface brine volume fraction and freeboard are well correlated with ice thickness, indicating some promise for remote sensing approaches to the estimation of ice thickness.  相似文献   

Absolute pollen productivity and pollen–vegetation relationships in northern Finland     

Shinya Sugita  Sheila Hicks  Henna Sormunen 《第四纪科学杂志》2010,25(5):724-736

Pollen productivity is one of the most critical parameters for pollen–vegetation relationships, and thus for vegetation reconstruction, in either pollen percentages or pollen accumulation rates. We obtain absolute pollen productivity of three major tree types in northern Finland: pine (Pinus sylvestris), spruce (Picea abies) and birch (Betula pubescens ssp. pubescens and B. pubescens ssp. czerepanovii treated as one taxon). Long‐term monitoring records of pollen traps from 15 sites (duration: 5–23 years) and tree volume estimates within a 14 km radius of each trap were compared to estimate pollen productivity (grains m^?3 a^?1) of these trees using a regression method. The slope of the linear relationship between pollen loading and distance‐weighted plant abundance represents pollen productivity. Estimated productivities of pollen (×10⁸ grains m^?3 a^?1) for pine, spruce and birch are 128.7 (SE 31.5), 341.9 (SE 81.3) and 411.4 (SE 307.7), respectively. The birch estimate (P > 0.05) is not as good as the others and should be used with caution. Pollen productivities of pine, spruce and birch in northern Finland are, in general, comparable to those of congeneric species in other regions of Europe and Japan. Although the year‐to‐year variations are significant, our volume‐based estimates of pollen productivity for pine and spruce will be essential for quantitative reconstruction of vegetation in the region. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Surface-temperature history during the last 1000 years near Prudhoe Bay, Alaska: applying control theory to the inversion of borehole temperature profiles     

Shinya Kakuta   《Global and Planetary Change》1992,6(2-4)

The temperature-depth profile data by Lachenbruch et al. (1982) in ice-bearing permafrost near Prudhoe Bay, Alaska, are analyzed with control theory to retrodict the last 1000-yr history of the surface temperature. For this purpose, an inversion scheme for a nonlinear problem of heat diffusion in permafrost is developed. The following conclusions are made: (1) During the last 1000 years, the surface temperature near Prudhoe Bay, Alaska, oscillated with amplitude of 3 ± 1°C. (2) There was a minimum of the temperature in 1853 AD between two maxima at 1623 AD and 1937 AD. (3) A net warming by 4°C occurred from 1853 AD to 1973 AD.  相似文献   

Sedimentary Steryl Chlorin Esters (SCEs) and Other Photosynthetic Pigments as Indicators of Paleolimnological Change Over the Last 28,000 Years from the Buguldeika Saddle of Lake Baikal     

Yuko Soma  Yukinori Tani  Mitsuyuki Soma  Hideo Mitake  Ryo Kurihara  Shinya Hashomoto  Takahiro Watanabe  Toshio Nakamura 《Journal of Paleolimnology》2007,37(2):163-175

Detailed depth profiles of photosynthetic pigments in a sediment core (G-12) collected at the BDP93 site, the Buguldeika saddle, of south Lake Baikal, along with depth profiles of total organic carbon (TOC) and biogenic silica, were studied to elucidate the temporal changes of phytoplankton assemblages in the lake during the past 28 kyr. In addition to the quantification of carotenoids by high-performance liquid chromatography with photodiode-array detection (HPLC-PDA), steryl chlorin esters (SCEs) were analyzed by HPLC-PDA, HPLC-mass spectrometry (LC-MS) and sterols in SCEs by gas chromatography–mass spectrometry (GC–MS) to enrich the taxonomical information on the phytoplankton composition. Allochthonous input of organic matter from the Selenga River resulted in the higher TOC contents in core G-12 than in a previously reported core (G-6) collected at another site from the southern basin. The poorer correlation in core G-12 than in G-6 between TOC and chlorophyll-a-originating pigments, which are indicative of autochthonous production, also indicated a significant allochthonous input at the site. The abundance of lutein among the carotenoids detected, and the good correlation of total chlorophyll a and b shows that green algae represented a significant portion of the phytoplankton, accompanying the diatoms at the G-12 site, after the last glacial period. The presence of cryptomonads and cyanobacteria were confirmed from marker carotenoids in the sediment core. GC–MS analysis of sterols in SCEs detected marker sterols of diatoms, green algae, chrysophytes and dinoflagellates. The depth profiles of the measured indicators gave consistent features for temporal changes in phytoplankton assemblage at the G-12 site of Lake Baikal after the last glacial maximum. Notably, the profile of a chrysophyte-specific sterol in SCEs was consistent with the reported distribution of chrysophyte cysts during the Holocene. The presence of phytoplankton, such as green algae, diatoms and chrysophytes, in Lake Baikal during the late last glacial period was indicated by the analysis of sterols in SCEs. Sedimentary carotenoids and sterols in SCEs were found to give complementary information about phytoplankton composition. These molecular indicators allow us to reconstruct past lake phytoplankton assemblages responding to environmental changes with a time resolution as high as age–depth relationship in sediments attainable at present.  相似文献   

Climato-hydrological environment inferred from Lake Baikal sediments based on an automatic orbitally tuned age model     

Shinya?OchiaiEmail author  Kenji?Kashiwaya 《Journal of Paleolimnology》2005,33(3):303-311

We propose a new automatic orbital tuning algorithm to adjust climatic signals to insolation. This can tune two signals with periodicity only without shape similarity. A Genetic Algorithm (GA) is used as an optimizing method. The new age model for the Brunhes epoch in Lake Baikal core BDP98 defined climatic shifts at about 250 kyr B.P., 350 kyr B.P. and 700 kyr B.P. The sedimentation rate for the interval from 350 kyr B.P. to 700 kyr B.P. was comparatively low and stable. This new model also indicates that there was a stadial during the super interglacial period (MIS 11), and that the terrestrial response to climate change was complex in this period.  相似文献   

POM and Two-Way Nesting POM Study of Kuroshio Damping Phenomenon Caused by a Strong Wind     

Yasumasa Miyazawa  Shinya Minato 《Journal of Oceanography》2000,56(3):275-294

A Kuroshio damping phenomenon of a few days scale caused by a strong wind was studied using the Princeton Ocean Model (POM) and a two-way nesting model for the POM. We simulated an idealized eastward Kuroshio in a zonal channel in terms of the inflow/outflow condition at the western/eastern boundaries and examined responses of the idealized Kuroshio to a strong easterly wind. This study was motivated by observations of JMA research vessel Shumpu Maru which reported deformation of isopycnals and damping of the Kuroshio before and after the attack of Typhoon 6804. Deformation of isopycnals and damping of the Kuroshio are found to depend on magnitude of wind stress, intensity of stratification, distance of the Kuroshio from coast, and grid resolution. The deformation of isopycnals is related to the vertical circulation pattern caused by the divergence/convergence of the onshore Ekman transport. A simple stratification model composed of Niiler (1969)'s modification of the Ekman transport and the coastal boundary is proposed to explain the damping phenomenon. An idealized cape was added in other experiments in order to study whether the Kuroshio damping mechanism discussed here works in three dimensions. The newly developed two-way nesting model for the POM was applied for this experiment and made it possible to clarify more detailed features of response in the nested area than did the coarse grid model.  相似文献   

Different characteristics of the structure of atmospheric boundary layer between dry and rainy periods over the northern Tibetan Plateau     

MaoShan Li  YaoMing M  WeiQiang M  Ishikawa Hirohiko  FangLin Sun  Shinya Ogino 《寒旱区科学》2011,3(6):0509-0516

In this paper, based on in-situ observational data of the Coordinated Enhanced Observing Period (CEOP) Asia-Australia Monsoon Project (CAMP) on the Tibetan Plateau (CAMP-Tibet), structure of the Atmospheric Boundary Layer (ABL) was preliminarily studied during the dry and rainy seasons. The main results show: (a) Diurnal variation of the ABL is obvious over the northern Tibetan Plateau area. The height of the ABL is different with the season change, which ranges from 2,211 m to 4,430 m during the pre-monsoon season and from 1,006 m to 2,212 m during the monsoon season. The ABL height is higher during the dry period than during the rainy period. (b) The humidity is lower during the dry period than during the rainy period, and there are reverse humidity during both periods. (c) Horizontal wind direction is mostly west during the dry period, east under the height of 2,500 m and west above the height of 2,500 m during the rainy period. The wind speed is low during both the rainy and dry periods in the lower ABL layer. The wind speed is stronger within the upper ABL during the dry period than during the rainy period.  相似文献   

Long-term riverbed response of lower Tedori River,Japan, to sediment extraction and dam construction     

Minh Hai Dang  Shinya Umeda  Masatoshi Yuhi 《Environmental Earth Sciences》2014,72(8):2971-2983

Effects of sediment extraction and dam construction on changes of riverbed characteristics over yearly to decadal scales in the lower Tedori River of Japan are clarified. Over 1950–1991, the riverbed degraded in excess of 0.5–3.5 m. Concurrently, riverbed sediment volume of the 0–16 km reach decreased by 12.7 × 10⁶ m³. Intensive sediment extraction was the dominant cause of riverbed degradation during the period. During 1991–2007, an increase in riverbed sediment volume of 0.6 × 10⁶ m³ resulted in accretion of the riverbed by average depth 0.04 m. The cessation of sand and gravel mining (SGM), coupled with Tedorigawa Dam operation since 1980, was responsible for that accretion. Temporal change in riverbed elevation during 1950–2007 indicates that there were five phases of vertical adjustment. Combination of nonlinear regression models described four of these phases well. During 1950–1979, the first four modes of empirical orthogonal function analysis successfully captured temporal and spatial responses of the riverbed to natural and anthropogenic impacts. That is, the first mode explained the mean riverbed profile and temporal variation in riverbed sediment volume. The second through fourth spatial eigenfunctions reflected spatial variation in vertical adjustment rate for phases II, III and I, respectively. The corresponding temporal eigenfunctions explained the respective effects on the riverbed of SGM, of imbalance between sediment transport capacity and sediment supply, and of dredging activity.  相似文献