The varved sediment of Lake Suigetsu (central Japan) provides a valuable opportunity to obtain high‐resolution, multi‐proxy palaeoenvironmental data across the last glacial/interglacial cycle. In order to maximize the potential of this archive, a well‐constrained chronology is required. This paper outlines the multiple geochronological techniques being applied – namely varve counting, radiocarbon dating, tephrochronology (including argon–argon dating) and optically stimulated luminescence (OSL) – and the approaches by which these techniques are being integrated to form a single, coherent, robust chronology. Importantly, we also describe here the linkage of the floating Lake Suigetsu (SG06) varve chronology and the absolute (IntCal09 tree‐ring) time scale, as derived using radiocarbon data from the uppermost (non‐varved) portion of the core. This tie‐point, defined as a distinct (flood) marker horizon in SG06 (event layer B‐07–08 at 1397.4 cm composite depth), is thus derived to be 11 255 to 11 222 IntCal09 cal. years BP (68.2% probability range). 相似文献
Deposition in the New Jersey Pinelands was very acidic (pH=4.17) and contained high levels of SO2−2 based on bulk deposition measurementsfrom July 1984–July 1986. Streamwater over the same interval in undisturbed watersheds
was less acidic (pH =4.52) and had proportionately less SO4−2. A preliminary alkalinity budget for undisturbed watersheds suggested that SO4−2 retention within Pinelands watersheds accounted for a large portion of the total alkalinity generated and thereby lessened
the impact of acidic deposition on surface waters. The only process capable of explaining the retention of SO4−2 was microbial sulfate reduction in the extensive wetlands surrounding Pinelands streams which occurred at high rates. 相似文献
After reaction with a pH < 4, the surface of labradorite is extensively enriched in Si and H, and depleted in Al, Ca and Na relative to an unreacted crystal. However, the amount of hydrogen measured in the reacted surface is less than that predicted on the basis of exchange of hydrogen (or hydronium) ions for cations in the feldspar. By analogy with studies of silicate glass, this low concentration of hydrogen suggests that some silanol groups in the reacted surface repolymerize subsequent to ion-exchange and depolymerization reactions. The net result is a relatively porous, Si-rich leached layer which is amorphous to electron diffraction, and which allows rapid diffusion of unreactive solutes.
Both the surface area of the reacted feldspar and the porosity increase with acid hydrolysis. Modeling of nitrogen sorption onto the surface suggests that the pores have a nominal radius of 20–80 Å or less. This distribution of pore sizes resembles other acid-reacted silicate materials, such as glass, chrysotile and kaolinite. Although the mineral surface clearly becomes more porous during acid hydrolysis, the increase in powder area also does not coincide with an increase in the flux of dissolved Si from the powder. We thus attribute most of this increase in area to spallation of the silica-rich surface from the feldspar upon drying. 相似文献
A diverse volcanic and plutonic rock suite was recovered from the center of the 80 km long ridge segment of the Southwest Indian Ridge (54°S, 7°16 E) between the Islas Orcadas and Shaka Fracture Zones. The cumulus nature of the gabbroic rocks in the suite is indicated by phase, modal and cryptic layering, igneous lamination, and low incompatible element abundances. We present a mass-balance model for calculating the proportions and compositions of cumulus phases and crystallized intercumulus liquid from bulk-rock major element compositions. The model is based on the ability to define a compositional array of basaltic liquids and on the assumption that cumulus minerals are initially in equilibrium with trapped liquid. Calculated proportions of trapped liquid range from 3%–15%; values that are characteristic of adcumulates to mesocumulates. Models of postcumulus crystallization indicate significant enrichments of incompatible elements and buffering of compatible elements in residual trapped liquids, thus explaining the high TiO2 contents observed in magnesian clinopyroxenes. Cumulus phase assemblages and compositions suggest solidification in shallow level magma chambers, but disequilibrium plagioclase compositions suggest some crystallization at greater depth. Furthermore, basalt compositions projected onto the olivine-clinopyroxenequartz pseudoternary suggest magma generation over a range of pressures (from less than 10 to greater than 20 kb) as well as polybaric fractional crystallization. We suggest that the Southwest Indian Ridge is characterized by low magma supply with small batches of melt that either ascend directly to the surface having undergone limited polybaric crystallization or are trapped in shallow crustal magma chambers where they evolve and solidify to form cumulate gabbros. The adcumulus nature of the gabbros investigated here suggests slow cooling rates typical of large intrusions implying relatively large, but ephemeral magma chambers below segments of the Southwest Indian Ridge. 相似文献
Estimates of subsurface temperatures in the Archean craton of southern Africa during the Archean derived from diamond thermobarometry studies are remarkably similar to temperatures estimated for the same depths today, even though heat production in the earth and the mean global heat flow were probably substantially higher in the Archean. We present multi-dimensional numerical models for the thermal environment of the Archean craton in southern Africa during the Archean in which deep mantle heat is diverted away from the craton toward the surrounding oceanic lithosphere by a lithospheric root beneath the craton. Extrapolation of present-day models to thermal conditions appropriate for the Archean is inadequate to explain the similarity of present-day and Archean temperatures in the cratonic root. Reconciliation of the modern and ancient temperature estimates requires either relaxation of the constraints that the cratonic crustal heat production and/or the earth's mean mantle temperature were higher in the Archean than they are today, or that substantial “erosion” of the lithosphere comprising the cratonic root has occurred since the Archean. The latter possibility could perhaps result from revolatilization of the cratonic root in association with thermal perturbations in the mantle, for which there is evidence in southern Africa in the form of post-Archean tectonic and igneous activity. 相似文献
A numerical model of the cloudy marine boundary layer is described and used to investigate the role of entrainment instability on the developing boundary layer. In general, previous studies have been limited to boundary layers capped by convectively stable inversions or have described only cumulus fields. Here we extend a stratus-capped boundary-layer model to consider the transition to a convectively unstable cloud layer capped by an inversion across which there is a rapid decrease in wet-bulb or equivalent potential temperature. In this case, the inversion is very active and the entrainment rate is determined by the active instability at the interface, in contrast to the mean turbulent motion within the boundary layer.The model is used to interpret the observed boundary layer from the JASIN experiment. Cool, dry air is modified by prolonged passage over increasingly warmer ocean which leads to the development of a convectively unstable cloud layer. 相似文献