Fe2+-Ti4+ charge transfer in stoichiometric Fe2+,Ti4+-minerals     

Stephanie M. Mattson  George R. Rossman 《Physics and Chemistry of Minerals》1988,16(1):78-82

Optical absorption spectra are presented for taramellite, traskite and neptunite, all of which have both Fe²⁺ and Ti⁴⁺ as major elements. The spectra of each of these minerals are dominated by a single, intense absorption band in the 415 to 460 nm region with 7000 to 9000 cm^?1 halfwidth. These transitions, assigned to Fe²⁺-Ti⁴⁺ intervalence charge transfer, showed little difference in intensity at 80 and 300 K and have molar absorptivities which range from ～100 to ～1300 M^?1 cm^?1. The Fe²⁺-Ti⁴⁺ absorptions in these standards generally compare well to other mineral spectra in which Fe²⁺ — Ti⁴⁺ intervalence absorption has previously been proposed with the exception of the most cited example, blue corundum.  相似文献   

Inverted-polarity electrical structures in thunderstorms in the Severe Thunderstorm Electrification and Precipitation Study (STEPS)     

W. David Rust  Donald R. MacGorman  Eric C. Bruning  Stephanie A. Weiss  Paul R. Krehbiel  Ronald J. Thomas  William Rison  Timothy Hamlin  Jeremiah Harlin 《Atmospheric Research》2005,76(1-4):247

Balloon-borne electric field soundings and lightning mapping data have been analyzed for three of the storms that occurred in the Severe Thunderstorm Electrification and Precipitation Study field program in 2000 to determine if the storms had inverted-polarity electrical structures. The polarities of all or some of the vertically stacked charge regions in such storms are opposite to the polarities observed at comparable heights in normal storms. Analyses compared the charge structures inferred from electric field soundings in the storms with charges inferred from three-dimensional lightning mapping data. Charge structures were inferred from electric field profiles by combining the one-dimensional approximation of Gauss's law with additional information from three-dimensional patterns in the electric field vectors. The three different ways of inferring the charge structure in the storms were found to complement each other and to be consistent overall. Charge deposition by lightning possibly occurred and increased the charge complexity of one of the storms.Many of the cloud flashes in each case were inverted-polarity flashes. Two storms produced ground flash activity comprised predominantly of positive ground flashes. One storm, which was an isolated thunderstorm, produced inverted-polarity cloud flashes, but no flashes to ground. The positive and negative thunderstorm charge regions were found at altitudes where, respectively, negative and positive charge would be found in normal-polarity storms. Thus, we conclude that these storms had anomalous and inverted-polarity electrical structures. Collectively, these three cases (along with the limited cases in the refereed literature) provide additional evidence that thunderstorms can have inverted-polarity electrical structures.  相似文献   

Time-Relative Positioning with a Single Civil GPS Receiver     

Stephanie Michaud  Rock Santerre 《GPS Solutions》2001,5(2):71-77

Time-relative positioning is a recent method for processing GPS phase observations. The operational method undertaken in this paper consists of the following steps: first, recording phase observations at a station of known coordinates; second, moving the GPS receiver to an unknown station (which can be located up to a few hundred meters away, dependint on what type of transportation – e. g., walking, motorcycle – is available) while continuously observing carrier phases; and, third, recording phase observations at a second station of unknown coordinates with a single GPS receiver. To obtain the position of the unknown station relative to the first (known) station, the processing method uses combined observations taken at two different epochs and two different stations with the same receiver. For this reason, the errors that vary between two epochs must be taken into account in an appropriate way, especially errors in satellite clock corrections and ephemerides, and errors related to tropospheric and ionospheric delays. Ionospheric modeling using IONEX files (the ionospheric maps calculated by the International GPS Service) was also tested to correct L1 phase observations. This method has been used to calculate short vectors with an accuracy of a few centimeters (for a processing interval of 30 s) using a single civil GPS receiver. ? 2001 John Wiley & Sons, Inc.  相似文献   

The Chemical Quality of Self-Supplied Domestic Well Water in the United States     

Michael J. Focazio  Deborah Tipton  Stephanie Dunkle Shapiro  Linda H. Geiger 《Ground Water Monitoring & Remediation》2006,26(3):92-104

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Perspectives on present-day sea level change: a tribute to Christian le Provost     

Alix Lombard  Anny Cazenave  Pierre Yves Le Traon  Stephanie Guinehut  Cécile Cabanes 《Ocean Dynamics》2006,56(5-6):445-451

In this paper, we first discuss the controversial result of the work by Cabanes et al. (Science 294:840–842, 2001), who suggested that the rate of past century sea level rise may have been overestimated, considering the limited and heterogeneous location of historical tide gauges and the high regional variability of thermal expansion which was supposed to dominate the observed sea level. If correct, this conclusion would have solved the problem raised by the IPCC third assessment report [Church et al, Cambridge University Press, Cambridge, pp 881, 2001], namely, the factor two difference between the 20th century observed sea level rise and the computed climatic contributions. However, recent investigations based on new ocean temperature data sets indicate that thermal expansion only explains part (about 0.4 mm/year) of the 1.8 mm/year observed sea level rise of the past few decades. In fact, the Cabanes et al.’s conclusion was incorrect due to a contamination of abnormally high ocean temperature data in the Gulf Stream area that led to an overestimate of thermal expansion in this region. In this paper, we also estimate thermal expansion over the last decade (1993–2003), using a new ocean temperature and salinity database. We compare our result with three other estimates, two being based on global gridded data sets, and one based on an approach similar to that developed here. It is found that the mean rate of thermosteric sea level rise over the past decade is 1.5±0.3 mm/year, i.e. 50% of the observed 3 mm/year by satellite altimetry. For both time spans, past few decades and last decade, a contribution of 1.4 mm/year is not explained by thermal expansion, thus needs to be of water mass origin. Direct estimates of land ice melt for the recent years account for about 1 mm/year sea level rise. Thus, at least for the last decade, we have moved closer to explaining the observed rate of sea level rise than the IPCC third assessment report.  相似文献   

Indicators of Climate Warming in Minnesota: Lake ICE Covers and Snowmelt Runoff   总被引：2，自引：1，他引：2  

Stephanie L. Johnson  Heinz G. Stefan 《Climatic change》2006,75(4):421-453

Records of hydrologic parameters, especially those parameters that are directly linked to air temperature, were analyzed to find indicators of recent climate warming in Minnesota, USA. Minnesota is projected to be vulnerable to climate change because of its location in the northern temperate zone of the globe. Ice-out and ice-in dates on lakes, spring (snowmelt) runoff timing, spring discharge values in streams, and stream water temperatures recorded up to the year 2002 were selected for study. The analysis was conducted by inspection of 10-year moving averages, linear regression on complete and on partial records, and by ranking and sorting of events. Moving averages were used for illustrative purposes only. All statistics were computed on annual data. All parameters examined show trends, and sometimes quite variable trends, over different periods of the record. With the exception of spring stream flow rates the trends of all parameters examined point toward a warming climate in Minnesota over the last two or three decades. Although hidden among strong variability from year to year, ice-out dates on 73 lakes have been shifting to an earlier date at a rate of −0.13 days/year from 1965 to 2002, while ice-in dates on 34 lakes have been delayed by 0.75 days/year from 1979 to 2002. From 1990 to 2002 the rates of change increased to −0.25 days/year for ice-out and 1.44 days/year for ice-in. Trend analyses also show that spring runoff at 21 stream gaging sites examined occurs earlier. From 1964 to 2002 the first spring runoff (due to snowmelt) has occurred −0.30 days/year earlier and the first spring peak runoff −0.23 days/year earlier. The stream water temperature records from 15 sites in the Minneapolis/St Paul metropolitan area shows warming by 0.11^∘C/year, on the average, from 1977 to 2002. Urban development may have had a strong influence. The analysis of spring stream flow rates was inconclusive, probably because runoff is linked as much to precipitation and land use as to air temperature. Ranking and sorting of annual data shows that a disproportionately large number of early lake ice-out dates has occurred after 1985, but also between 1940 and 1950; similarly late lake ice-in has occurred more frequently since about 1990. Ranking and sorting of first spring runoff dates also gave evidence of earlier occurrences, i.e. climate warming in late winter. A relationship of changes in hydrologic parameters with trends in air temperature records was demonstrated. Ice-out dates were shown to correlate most strongly with average March air temperatures shifting by −2.0 days for a 1^°C increase in March air temperature. Spring runoff dates also show a relationship with March air temperatures; spring runoff dates shift at a rate of −2.5 days/1^°C minimum March air temperature change. Water temperatures at seven river sites in the Minneapolis/St Paul metropolitan area show an average rise of 0.46^°C in river temperature/1^°C mean annual air temperature change, but this rate of change probably includes effects of urban development. In conclusion, records of five hydrologic parameters that are closely linked to air temperature show a trend that suggests recent climate warming in Minnesota, and especially from 1990 to 2002. The recent rates of change calculated from the records are very noteworthy, but must not be used to project future parameter values, since trends cannot continue indefinitely, and trend reversals can be seen in some of the long-term records.  相似文献   

Cassini SAR, radiometry, scatterometry and altimetry observations of Titan’s dune fields     

A. Le Gall  M.A. Janssen  A.G. Hayes  C. Savage  R.D. Lorenz  R.L. Kirk  S. Wall  E.R. Stofan  the Cassini Radar Team 《Icarus》2011,213(2):608-624

Large expanses of linear dunes cover Titan’s equatorial regions. As the Cassini mission continues, more dune fields are becoming unveiled and examined by the microwave radar in all its modes of operation (SAR, radiometry, scatterometry, altimetry) and with an increasing variety of observational geometries. In this paper, we report on Cassini’s radar instrument observations of the dune fields mapped through May 2009 and present our key findings in terms of Titan’s geology and climate. We estimate that dune fields cover ∼12.5% of Titan’s surface, which corresponds to an area of ∼10 million km², roughly the area of the United States. If dune sand-sized particles are mainly composed of solid organics as suggested by VIMS observations (Cassini Visual and Infrared Mapping Spectrometer) and atmospheric modeling and supported by radiometry data, dune fields are the largest known organic reservoir on Titan. Dune regions are, with the exception of the polar lakes and seas, the least reflective and most emissive features on this moon. Interestingly, we also find a latitudinal dependence in the dune field microwave properties: up to a latitude of ∼11°, dune fields tend to become less emissive and brighter as one moves northward. Above ∼11° this trend is reversed. The microwave signatures of the dune regions are thought to be primarily controlled by the interdune proportion (relative to that of the dune), roughness and degree of sand cover. In agreement with radiometry and scatterometry observations, SAR images suggest that the fraction of interdunes increases northward up to a latitude of ∼14°. In general, scattering from the subsurface (volume scattering and surface scattering from buried interfaces) makes interdunal regions brighter than the dunes. The observed latitudinal trend may therefore also be partially caused by a gradual thinning of the interdunal sand cover or surrounding sand sheets to the north, thus allowing wave penetration in the underlying substrate. Altimetry measurements over dunes have highlighted a region located in the Fensal dune field (∼5° latitude) where the icy bedrock of Titan is likely exposed within smooth interdune areas. The hemispherical assymetry of dune field properties may point to a general reduction in the availability of sediments and/or an increase in the ground humidity toward the north, which could be related to Titan’s asymmetric seasonal polar insolation. Alternatively, it may indicate that either the wind pattern or the topography is less favorable for dune formation in Titan’s northern tropics.  相似文献   

Correlations between VIMS and RADAR data over the surface of Titan: Implications for Titan’s surface properties     

F. Tosi  R. Orosei  A. Coradini  G. Filacchione  F. Capaccioni  A. Adriani  A. Negrão  R.H. Brown  M. Janssen  J.W. Barnes  R.N. Clark  T.B. McCord  J.M. Soderblom  The Cassini VIMS  RADAR Teams 《Icarus》2010,208(1):366-384

We apply a multivariate statistical method to Titan data acquired by different instruments onboard the Cassini spacecraft. We have searched through Cassini/VIMS hyperspectral cubes, selecting those data with convenient viewing geometry and that overlap with Cassini/RADAR scatterometry footprints with a comparable spatial resolution. We look for correlations between the infrared and microwave ranges the two instruments cover. Where found, the normalized backscatter cross-section obtained from the scatterometer measurement, corrected for incidence angle, and the calibrated antenna temperature measured along with the scatterometry echoes, are combined with the infrared reflectances, with estimated errors, to produce an aggregate data set, that we process using a multivariate classification method to identify homogeneous taxonomic units in the multivariate space of the samples.In medium resolution data (from 20 to 100 km/pixel), sampling relatively large portions of the satellite’s surface, we find regional geophysical units matching both the major dark and bright features seen in the optical mosaic. Given the VIMS cubes and RADAR scatterometer passes considered in this work, the largest homogeneous type is associated with the dark equatorial basins, showing similar characteristics as each other on the basis of all the considered parameters.On the other hand, the major bright features seen in these data generally do not show the same characteristics as each other. Xanadu, the largest continental feature, is as bright as the other equatorial bright features, while showing the highest backscattering coefficient of the entire satellite. Tsegihi is very bright at 5 μm but it shows a low backscattering coefficient, so it could have a low roughness on a regional scale and/or a different composition. Another well-defined region, located southwest of Xanadu beyond the Tui Regio, seems to be detached from the surrounding terrains, being bright at 2.69, 2.78 and 5 μm but having a low radar brightness. In this way, other units can be found that show correlations or anti-correlations between the scatterometric response and the spectrophotometric behavior, not evident from the optical remote sensing data.  相似文献   

Evaluating techniques for sampling stream crayfish (Paranephrops planifrons)     

Charles F. Rabeni  Kevin J. Collier  Stephanie M. Parkyn  Brendan J. Hicks 《新西兰海洋与淡水研究杂志》2013,47(5):693-700

We evaluated several capture and analysis techniques for estimating abundance and size structure of freshwater crayfish (Paranephrops planifrons) (koura) from a forested North Island, New Zealand stream to provide a methodological basis for future population studies. Direct observation at night and collecting with baited traps were not considered useful. A quadrat sampler was highly biased toward collecting small individuals. Handnetting at night and estimating abundances using the depletion method were not as efficient as handnetting on different dates and analysing by a mark‐recapture technique. Electrofishing was effective in collecting koura from different habitats and resulted in the highest abundance estimates, and mark‐recapture estimates appeared to be more precise than depletion estimates, especially if multiple recaptures were made. Handnetting captured more large crayfish relative to electrofishing or the quadrat sampler.  相似文献   

Thermochronometric constraints on the tectonic evolution of the Serifos detachment, Aegean Sea, Greece   总被引：1，自引：0，他引：1  

Stephanie Brichau  Stuart Thomson  Uwe Ring 《International Journal of Earth Sciences》2010,99(2):379-393

We constrain the timing and kinematics of the Serifos detachment in the southwestern Cyclades, Greece, using low-temperature thermochronometry. Fission-track dating shows that the Serifos detachment was active between ~13 and 6 Ma and that the Serifos granodiorite in its footwall intruded at or before ~12–11 Ma into the extensional shear zone and initially cooled very rapidly at rates >180°C per million year. The mylonite zone at the top of the granodiorite and mylonitic structures in its country rocks record a consistent top-SSW shear sense in the ductile crust. In the brittle regime top-NNE shear-sense indicators occur as well. Conjugate top-SSW and top-NNE high-angle normal faults are the youngest deformational features and cut across the detachment. Age–distance relationships for the fission-track data display a relatively flat pattern. We discuss a model advocating initial top-SSW movement on the Serifos detachment before and during emplacement of the granodiorite. Updoming of the detachment during exhumation and cooling caused subsequent bivergent extension in the brittle crust.  相似文献