Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in sediments from Hong Kong   总被引：4，自引：0，他引：4  

Müller JF  Gaus C  Prange JA  Päpke O  Poon KF  Lam MH  Lam PK 《Marine pollution bulletin》2002,45(1-12):372-378

Concentrations of 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) were determined in 14 sediment samples collected from four sites in the Mai Po Marshes Nature Reserve (within a RAMSAR Site) and from another six sites in Victoria Harbour and along the Hong Kong coastline. Elevated levels of PCDDs, and particularly OCDD, were detectable in all samples collected from the Mai Po Marshes and five of the six sites. In contrast to PCDDs, PCDFs were mainly found in sediment samples collected from industrial areas (Kwun Tong and To Kwa Wan) in Victoria Harbour. PCDD/F levels and congener profiles in the samples from the Mai Po Marshes Nature Reserve in particular show strong similarities to those reported in studies which have attributed similar elevated PCDD concentrations to nonanthropogenic PCDD sources.  相似文献   

Amorphous copper and zinc sulfides in the metalliferous sediments of the Red Sea     

Olaf Brockamp  Evaristo Goulart  Hermann Harder  Annerose Heydemann 《Contributions to Mineralogy and Petrology》1978,68(1):85-88

Detailed studies on the copper and zinc distribution in metalliferous sediments from the Atlantis II Deep (Red Sea) demonstrate that beside chalcopyrite and sphalerite appreciable amounts of copper and zinc are found in X-ray amorphous copper and zinc sulfides not previously described. Only low contents of copper and zinc are present in nontronites, hydroxides and carbonates.  相似文献   

Identification of high energy gamma-ray sources and source populations in the era of deep all-sky coverage     

Olaf Reimer  Diego F. Torres 《Astrophysics and Space Science》2007,309(1-4):57-62

A large fraction of the anticipated source detections by the Gamma-ray Large Area Space Telescope (GLAST-LAT) will initially be unidentified. We argue that traditional approaches to identify individuals and/or populations of gamma ray sources will encounter procedural limitations. Those limitations are discussed on the background of source identifications from EGRET observations. Generally, our ability to classify (faint) source populations in the anticipated GLAST dataset with the required degree of statistical confidence will be hampered by sheer source wealth. A new paradigm for achieving the classification of gamma ray source populations is discussed.  相似文献   

INTEGRAL/XMM views on the MeV source GRO J1411-64     

Diego F. Torres  Shu Zhang  Olaf Reimer  Xavier Barcons  Amalia Corral  Valentí Bosch-Ramon  Josep M. Paredes  Gustavo E. Romero  Jin Qu  Werner Collmar  Volker Schönfelder  Yousaf Butt 《Astrophysics and Space Science》2007,309(1-4):17-21

The COMPTEL unidentified source GRO J 1411-64 was observed by INTEGRAL and XMM-Newton in 2005. The Circinus Galaxy is the only source detected within the 4σ location error of GRO J1411-64, but in here excluded as the possible counterpart. At soft X-rays, 22 reliable and statistically significant sources (likelihood >10) were extracted and analyzed from XMM-Newton data. Only one of these sources, XMMU J141255.6-635932, is spectrally compatible with GRO J1411-64 although the fact the soft X-ray observations do not cover the full extent of the COMPTEL source position uncertainty make an association hard to quantify and thus risky. At the best location of the source, detections at hard X-rays show only upper limits, which, together with MeV results obtained by COMPTEL suggest the existence of a peak in power output located somewhere between 300–700 keV for the so-called low state. Such a spectrum resembles those in blazars or microquasars, and might suggest at work by the models accordingly. However, an analysis using a microquasar model consisting on a magnetized conical jet filled with relativistic electrons, shows that it is hard to comply with all observational constrains. This fact and the non-detection at hard X-rays introduce an a-posteriori question mark upon the physical reality of this source, what is discussed here.  相似文献   

Autochthonous block fields in southern Norway: Implications for the geometry,thickness, and isostatic loading of the Late Weichselian Scandinavian ice sheet     

Atle Nesje  Svein Olaf Dahl 《第四纪科学杂志》1990,5(3):225-234

The consistent geographical and altitudinal distribution of autochthonous block fields (mantle of bedrock weathered in situ) and trimlines in southern Norway suggests a multi-domed and asymmetric Late Weichselian ice sheet. Low-gradient ice-sheet profiles in the southern Baltic region, in the North Sea, and along the outer fjord areas of southern Norway, are best explained by movement of ice on a bed of deforming sediment, although water lubricated sliding or a combination of the two, may not be excluded. The ice-thickness distribution of the Late Weichselian Scandinavian ice sheet is not in correspondence with the modern uplift pattern of Fennoscandia. Early Holocene crustal rebound was apparently determined by an exponential, glacio-isostatic rise. Later, however, crustal movements appear to have been dominated by large-scale tectonic uplift of the Fennoscandian Shield, centred on the Gulf of Bothnia, the region of maximum lithosphere thickness.  相似文献   

The behavior of molybdenum and its isotopes across the chemocline and in the sediments of sulfidic Lake Cadagno, Switzerland   总被引：1，自引：0，他引：1  

Tais W. Dahl  Ariel D. Anbar  Minik T. Rosing  Donald E. Canfield 《Geochimica et cosmochimica acta》2010,74(1):144-274

Molybdenum (Mo) isotope studies in black shales can provide information about the redox evolution of the Earth’s oceans, provided the isotopic consequences of Mo burial into its major sinks are well understood. Previous applications of the Mo isotope paleo-ocean redox proxy assumed quantitative scavenging of Mo when buried into sulfidic sediments. This paper contains the first complete suite of Mo isotope fractionation observations in a sulfidic water column and sediment system, the meromictic Lake Cadagno, Switzerland, a small alpine lake with a pronounced oxygen-sulfide transition reaching up to H₂S ∼ 200 μM in the bottom waters (or about 300 μM total sulfide: ΣS²⁻ = H₂S + HS⁻ + S²⁻). We find that Mo behaves conservatively in the oxic zone and non-conservatively in the sulfidic zone, where dissolved Mo concentrations decrease from 14 nM to 2-8 nM across this transition. Dissolved Mo in the upper oxic waters has a δ⁹⁸Mo_oxic = 0.9 ± 0.1‰, which matches that of the riverine input, δ⁹⁸Mo_river = 0.9 ± 0.1‰. In the deeper sulfidic waters, a subaquatic source delivers Mo at 1.55 ± 0.1‰, but the dissolved Mo is even heavier at δ⁹⁸Mo_sulfidic = 1.8‰. Sediment traps in the sulfidic zone of the lake collect particles increasingly enriched in Mo with depth, with δ⁹⁸Mo values significantly fractionated at −0.8‰ to −1.2‰ both near the chemocline and in the deepest trap. Suspended particulates in the sulfidic waters carry lighter Mo than the ambient dissolved Mo pool by ∼0.3-1.5‰. Sedimentary Mo concentrations correlate with total organic carbon and yield Mo levels which are two orders of magnitude higher than typical crustal values found in rocks from the catchment area. Solid-phase Mo in the sediment shows a slightly positive δ⁹⁸Mo trend with depth, from δ⁹⁸Mo = 1.2‰ to 1.4‰ while the pore waters show dramatic enrichments of Mo (>2000 nM) with a relatively light isotope signature of δ⁹⁸Mo = 0.9-1.0‰.These data are explained if Mo is converted to particle-reactive oxythiomolybdates in the sulfidic waters and is fractionated during removal from solution onto particles. Isotope fractionation is expressed in the water column, despite the high sulfide concentrations, because the rate of Mo removal is fast compared to the slow reaction kinetics of thiomolybdate formation. However, elemental and isotopic mass balances show that Mo is indeed quantitatively removed to the lake sediments and thus the isotopic composition of the sediments reflects sources to the sulfidic water. This efficient Mo drawdown is expected to occur in settings where H₂S is very much in excess over Mo or in a restricted setting where the water renewal rate is slow compared to the Mo burial rate. We present a model for the Mo isotope fractionation in sulfidic systems associated with the slow reaction kinetics and conclude that quantitative removal will occur in highly sulfidic and restricted marine systems.  相似文献   

A new particulate Mn-Fe-P-shuttle at the redoxcline of anoxic basins   总被引：1，自引：0，他引：1  

Olaf Dellwig  Thomas Leipe  Michael Glockzin  Bernhard Schnetger  Michael E. Böttcher 《Geochimica et cosmochimica acta》2010,74(24):7100-7115

Pelagic redoxclines of anoxic basins and deeps form the suboxic transition between oxygenated surface and anoxic or even sulfidic bottom waters. Intense element cycling, favoured by elevated microbial activity, causes steep gradients of physico-chemical parameters, nutrients and redox-sensitive trace metals. This study presents a conceptual model for authigenic particle formation at pelagic redoxclines, which is based on the tight coupling of Mn, Fe, and P cycles. Besides the well-known occurrence of Mn-oxides, textural (SEM-EDX) and geochemical (ICP-OES, ICP-MS) analyses of particles from the redoxclines of the Black Sea and the Baltic Sea (Gotland Basin, Landsort Deep) evidence the existence of earlier postulated Fe-oxyhydroxo-phosphates and emphasize mixed phases consisting of Mn-oxides and Fe-oxyhydroxo-phosphates as a new solid species. Most of the analyzed particles are star-shaped, of about 5 μm in size, and occur as single particles or aggregates without any morphological differences between Mn-oxides, Fe-oxyhydroxo-phosphates, and mixed phases. Throughout the redoxcline, these minerals show a general succession with maximum abundance of Mn-oxides above the redoxcline followed by mixed phases and almost pure Fe-phosphates within and below the redoxcline, respectively. Molar Fe/P ratios of single particles argue against the formation of known pure Fe-phosphates like vivianite or strengite at the lower end of the redox transition zone, but are consistent with recent experimental findings for colloidal P-bearing hydrous ferric oxides. Moreover, morphological similarities suggest the formation of irregular Fe-oxyhydroxo coatings due to oxidation of upward diffusing Fe²⁺ by oxygen and stepwise replacement of Mn(IV) by Fe(III) on sinking MnO_x particles followed by immediate adsorption or even co-precipitation of phosphate. Batch-type experiments using biogenic MnO_x particles demonstrate the efficient potential of Fe²⁺ oxidation by sinking MnO_x particles. When entering sulfidic waters MnO_x particles are progressively reduced leading to an increasing relative abundance of Fe- and P-rich particles. In deeper parts of the water column these particles are also reductively dissolved, thereby releasing Fe²⁺ and phosphate to the water column. This Mn-Fe-P-shuttle likely affects phosphate transport throughout the water column and thus impacts primary production at least over longer time scales. Furthermore, the particulate Mn-Fe-P-shuttle must have played an important role for the cycling of P and certain trace metals in ancient ocean basins, e.g., during certain periods of Cretaceous black shale formation and should be considered in future mass balances and modeling approaches dealing with oxic/anoxic interfaces of aquatic ecosystems.  相似文献   

Visualisation in environmental sciences     

Karsten Rink  Gerik Scheuermann  Olaf Kolditz 《Environmental Earth Sciences》2014,72(10):3749-3751

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Holocene relative sea level changes in the Västervik-Gamlebyviken region on the southeast coast of Sweden,southern Baltic Sea     

Christos Katrantsiotis  Martin Dahl  Veronica Palm  Johan Rönnby  Thomas Andrén  Elinor Andrén 《Boreas: An International Journal of Quaternary Research》2023,52(2):206-222

We reconstruct the Holocene shore displacement of the Västervik-Gamlebyviken area on the southeast coast of Sweden, characterised by a maritime cultural landscape and archaeological significance since the Mesolithic. Sediment cores were retrieved from four lake basins that have been raised above sea level due to the postglacial land uplift and eustatic sea level changes after the melting of the Fennoscandian Ice Sheet. The cores were radiocarbon dated and analysed for loss on ignition and diatoms. The isolation thresholds of the basins were determined using LiDAR data. The results provide evidence for the initiation of the first Littorina Sea transgression in this area at 8.5 thousand calibrated years before present (cal. ka BP). A relative sea level rise by ∼7 m a.s.l. is recorded between 8.0 and 7.5 cal. ka BP with a highstand at ∼22 m a.s.l. between 7.5 and 6.2 cal. ka BP. These phases coincide with the second and third Littorina Sea transgressions, respectively, in the Blekinge area, southern Sweden and are consistent with the final deglaciation of North America. After 6.2 cal. ka BP, the relative sea level dropped below 22 m a.s.l., and remained at ∼20 m a.s.l. until 4.6 cal. ka BP coinciding with the fourth Littorina Sea transgression in Blekinge. From 4.6 to 4.2 cal. ka BP, the shore displacement shows a regression rate of 10 mm a⁻¹ followed by a slowdown with a mean value of 4.6 mm a⁻¹ until 1.6 cal. ka BP, when the relative sea level dropped below 3.3 m a.s.l. The Middle to Late Holocene highstand and other periods of minor sea level transgressions and/or higher salinity between 6.2 and 1.7 cal. ka BP are attributed to a combination of warmer climate and higher inflow of saline waters in the southern Baltic Sea due to stronger westerlies, caused by variations in the North Atlantic atmospheric patterns.  相似文献   

Some experiments and considerations for development of Doppler-based riverine sonars     

Dahl  P. Mathison  O. 《Oceanic Engineering, IEEE Journal of》1984,9(3):214-217

Sonar counting devices have been utilized by fisheries biologists to estimate annual spawning migrations of anadromous salmon. Recent developments in signal detection based on the Doppler principle, and new information on fish sound scattering characteristics at the high frequencies used in riverine sonar, should result in much improved detection and classification capability. These are discussed along with some practical considerations for the deployment of sonar devices for counting fish in rivers.  相似文献