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41.
The joint research project CLEAN was conducted in the years 2008?C2011 by a German research and development (R&D) alliance of 16 partners from science and industry. The project was set-up as pilot project to investigate the processes relevant to enhanced gas recovery (EGR) by the injection of CO2 into a subfield of the almost depleted Altmark natural gas field. Despite the setback that permission for active injection was not issued by the mining authority during the period of the project, important results fostering the understanding of processes linked with EGR were achieved. Work carried out led to a comprehensive evaluation of the EGR potential of the Altmark field and the Altensalzwedel subfield in particular. The calculated safety margins emphasize that technical well integrity of the 12 examined boreholes is given for EGR without a need for any further intervention. The laboratory and field tests confirm that the Altensalzwedel subfield is suitable for the injection of 100,000?t of CO2. Numerical simulations provide sound predictions for the efficiency and safety of the EGR technology based on the CO2 injection. The development and testing of different monitoring techniques facilitate an improved surveying of CO2 storage sites in general. The CLEAN results provide the technological, logistic and conceptual prerequisites for implementing a CO2-based EGR project in the Altmark and provide a benchmark for similar projects in the world.  相似文献   
42.
An assessment of water quality measurements during a long‐lasting low water period in the Elbe River is presented. Weekly samples were taken from May to December 2003 at a sampling site in the middle part of the Elbe River. For multivariate data analysis, 34 parameters of 46 samplings were considered. As a result of this analysis, 78% of the variance of the data set is explained by five factors. They can be assigned to the following latent variables: season (37.5%) > tributaries (12.7%) > re‐suspension (10.4%) > discharge (9.4%) > complexation (8.5%). For the investigated sampling site, two key processes were identified as dominating factors on the water quality during low water conditions. First, seasonal phytoplankton development caused changes in redox conditions with consequences for re‐solution of pollutants from sediments. Second, tributaries have a higher impact on the main stream, due to changes in mixing processes. Therefore, in addition to flood investigations, monitoring strategies, and management plans should be developed in order to survey changes in water quality during low water conditions.  相似文献   
43.
Stable isotope measures in organic matter are frequently used as indicators of past climate change. Although such analyses can provide valuable information, there is considerable uncertainty associated with studies of organic-rich sediments, especially those from Arctic lakes and bogs. We studied stable isotopes of carbon and nitrogen, and magnetic properties in a sediment core from a small alkaline lake with a high sedimentation rate, Lake Nattmålsvatn, Norway. There is good correspondence among the different sediment variables during the late glacial, and they seemingly reflect major climate variations such as the Allerød Interstade and the Younger Dryas, as well as the transition into the current interglacial. During the early Holocene, however, these relationships are more complex and δ13C and δ15N values do not stabilize until ~7,500 cal year BP. A significant excursion in all variables occurs between 6,850 and 6,500 cal year BP and is interpreted to represent climate deterioration. Holocene δ13C values vary little and indicate that isotopically-depleted dissolved inorganic carbon (DIC) in the lake, possibly influenced by methanotrophy and high pCO2, dominated the lake’s carbon cycle. Holocene δ15N is similarly muted, likely due to the availability of abundant dissolved nitrogen. Bulk organic matter is probably dominated by phytoplankton remains produced beneath the ice cover in late spring and during ice breakup when isotopically-depleted DIC, pCO2 and ammonium availability were maximal. Thus, use of δ13C and δ15N as indicators of Holocene paleoclimate and paleoproductivity variation can be challenging in a lake such as Nattmålsvatn, where ice cover isolates the basin for large parts of the year, allowing dissolved respiratory gases to accumulate in the water column. In contrast, magnetic variables appear to better track climate variations. In particular, runoff-driven influx of minerogenic sediments shows high variability that can be attributed to regional changes in Holocene winter precipitation. The most striking shifts occur between 4,000 and 2,300 cal year BP.  相似文献   
44.
During carbon steel manufacture, slag residues are generated to remove material impurities from liquid metal and thus control the quality of carbon steel. As the utilization of secondary metallurgical slags is not as efficient as those of primary slags, a comprehensive characterization of steel ladle slag was performed. Pseudo-total concentrations of a wide range of elements were determined during a 6-week sampling period with relevant physical and chemical properties, sequential extraction of trace elements, and parallel mineralogical characterization of extraction residues from a representative combined sample. According to the results, only Cr and V occurred in elevated concentrations with respective 6-week mean values of 198 and 310 mg kg?1 (d.w.). The residual standard deviation of the weekly pseudo-total concentration values of the aforementioned elements (24 and 31 %, respectively) indicated that significant variation in the concentration of trace elements can occur due to fluctuation in process conditions and/or slag characteristics. The sequential extraction procedure suggested potential phytoavailability of V (123 mg kg?1, d.w., amounting to 41 % of the respective pseudo-total concentration) through, e.g., changes in prevailing redox conditions. Although the analytical approach was validated by the analysis of a certified reference material and the calculation of extraction recoveries, the mineralogical characterization of parallel extraction residues indicated non-selectivity of the procedure coupled with potential redistribution phenomena during extraction with hydrogen peroxide and ammonium acetate.  相似文献   
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Over the course of hydrological research projects often a large number of heterogeneous data sets are acquired from sources as diverse as boreholes, gauging stations or satellite imagery. This data then need to be integrated into models for the simulation of hydrological processes. We propose a framework for exploration of geoscientific data and visually guided preparation of such models. Data sets from a large number of sources can be imported, combined and validated to avoid potential problems due to artefacts or inconsistencies between data sets in a subsequent simulation. Boundary conditions and domain discretisations for surface and subsurface models can be created and tested regarding criteria indicating possible numerical instabilities. All data sets including simulation results can be integrated into a user-controlled 3D scene and aspects of the data can be enhanced using a number of established visualisation techniques including thresholding and user-defined transfer functions. We present the application of this framework for the preparation of a model for simulation of groundwater flow in a river catchment in southwest Germany investigated in the scope of the WESS project.  相似文献   
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In this comment we present a re-analysis of the analytical solution presented by Cirpka and Valocchi for steady-state concentrations of dissolved bioreactive compounds and bacterial biomass in porous media. We discuss the validity range of the analytical solution. In particular, the criterion used to determine the sustainability of biomass is revisited. This re-analysis shows that the ωω criterion used by Cirpka and Valocchi is only a necessary but not a sufficient criterion to determine the bioreactive zones. As a consequence, the analytical solution does not provide the exact distribution of compounds throughout the domain, but can serve as upper or lower boundaries for species concentrations at a given location. These conclusions are supported by the simulation results obtained from an established reactive transport model.  相似文献   
50.
In the German State Brandenburg, water clarity and the concentrations of the water quality components chlorophyll a, seston and gelbstoff were measured in 27 lakes. Correlation analysis showed, that spectral beam attenuation at 662 and 514 nm was mainly dependent on changes in chlorophyll a concentrations. In the UV-channel at 360 nm, beam attenuation depended mostly on gelbstoff.

Multiple linear regression provided a direct model of beam attenuation at 514 nm with the inputs of inorganic seston, chlorophyll a and gelbstoff. The specific beam attenuation coefficients were comparable to other natural waters around the world. An inverse model is presented, from which gelbstoff and chlorophyll a could be predicted with some accuracy from the inputs of beam attenuation coefficients at 514 and 360 nm. However, it became obvious that biological variability put major constraints on the predictive capacity of both the direct and the inverse model.

Furthermore, we observed a good correspondence of Secchi depth and the inverse of beam attenuation at 514 nm. The predictions of Secchi depth and chlorophyll a concentration from the inverse model were assessed in perspective of using this instrument instead of laborious chemical analysis for future trophic status classification according to LAWA (Länderarbeitsgemeinschaft Wasser). Predictions of trophic status were principally good when using calibrated models, however, quality of classification critically depended on predictions of chlorophyll a.  相似文献   

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