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21.
The stability constants for sulfate, chloride and hydroxide ions with cerium (III) in the solution at ionic strength of 0.67 have been determined by cation exchange method, the values of
1 and
2 for sulfate complexes of cerium being 40±13 and 453±140, respectively and those for chloride complexes being 1.28±0.23 and 0.56±0.076, respectively. The values of
1,
2 and
3 for hydroxide complexes of cerium were (4.5±0.9)×107, (3.3±0.7)×1014 and (1.8±0.7)×1023, respectively.Using the above constants the ratios of individual chemical species of144Ce were calculated in a solution at ionic strength of 0.67 containing sulfate and chloride ions approximately the same as in seawater of 35 %. The result of calculation indicates that the dominant species of144Ce in this solution is Ce(OH)3
0 at pH 8. 相似文献
22.
Carbon and water cycling in a Bornean tropical rainforest under current and future climate scenarios
Tomoomi Kumagai Gabriel G. Katul Amilcare Porporato Taku M. Saitoh Mizue Ohashi Tomoaki Ichie Masakazu Suzuki 《Advances in water resources》2004,27(12):1844
We examined how the projected increase in atmospheric CO2 and concomitant shifts in air temperature and precipitation affect water and carbon fluxes in an Asian tropical rainforest, using a combination of field measurements, simplified hydrological and carbon models, and Global Climate Model (GCM) projections. The model links the canopy photosynthetic flux with transpiration via a bulk canopy conductance and semi-empirical models of intercellular CO2 concentration, with the transpiration rate determined from a hydrologic balance model. The primary forcing to the hydrologic model are current and projected rainfall statistics. A main novelty in this analysis is that the effect of increased air temperature on vapor pressure deficit (D) and the effects of shifts in precipitation statistics on net radiation are explicitly considered. The model is validated against field measurements conducted in a tropical rainforest in Sarawak, Malaysia under current climate conditions. On the basis of this model and projected shifts in climatic statistics by GCM, we compute the probability distribution of soil moisture and other hydrologic fluxes. Regardless of projected and computed shifts in soil moisture, radiation and mean air temperature, transpiration was not appreciably altered. Despite increases in atmospheric CO2 concentration (Ca) and unchanged transpiration, canopy photosynthesis does not significantly increase if Ci/Ca is assumed constant independent of D (where Ci is the bulk canopy intercellular CO2 concentration). However, photosynthesis increased by a factor of 1.5 if Ci/Ca decreased linearly with D as derived from Leuning stomatal conductance formulation [R. Leuning. Plant Cell Environ 1995;18:339–55]. How elevated atmospheric CO2 alters the relationship between Ci/Ca and D needs to be further investigated under elevated atmospheric CO2 given its consequence on photosynthesis (and concomitant carbon sink) projections. 相似文献
23.
24.
Taku Tsuchiya Takamitsu Yamanaka Masanori Matsui 《Physics and Chemistry of Minerals》1998,25(2):94-100
A two-body interatomic potential model for GeO2 polymorphs has been determined to simulate the structure change of them by semi-empirical procedure, total lattice energy
minimization of GeO2 polymorphs. Based on this potential, two polymorphs of GeO2; α-quartz-type and rutile-type, have been reproduced using the molecular dynamics (MD) simulation techniques. Crystal structures, bulk moduli, volume thermal expansion coefficients and enthalpies of these
polymorphs of GeO2 were simulated. In spite of the simple form of the potential, these simulated structural values, bulk moduli and thermal
expansivities are in excellent agreement with the reliable experimental data in respect to both polymorphs. Using this potential,
MD simulation was further used to study the structural changes of GeO2 under high pressure. We have investigated the pressure-induced amorphization. As reported in previous experimental studies,
quartz-type GeO2 undergoes pressure-induced crystalline-to-amorphous transformation at room temperature, the same as other quartz compounds;
SiO2, AlPO4. Under hydrostatic compression, in this study, α-quartz-type GeO2 transformed to a denser amorphous state at 7.4 GPa with change of the packing of oxygen ions and increase of germanium coordination.
At higher pressure still, rutile-type GeO2 transformed to a new phase of CaCl2-type structure as a post-rutile candidate.
Received: 29 July 1996 / Revised, accepted: 30 April 1997 相似文献
25.
Taku Sato Masato Kobayashi Takayuki Takebe Narisato Hirai Koichi Okuzawa Sayumi Sawaguchi Takahiro Matsubara Tomofumi Yamaguchi Rihito Shinoda Masahiko Koiso Kazuhisa Teruya 《Marine Ecology》2018,39(1)
Most behavioral studies on hermaphroditic fishes have focused on small‐sized species, which are tractable for research. Although many species of large hermaphroditic fishes are important fishery resources, their proximate mechanisms (visual, chemical and/or behavioral cues) in the social regulation of sex change have not been determined. Determination of these would inform resource management and aquaculture. In order to get closer to understanding the proximate mechanisms underlying the social regulation of female‐to‐male sex change in large hermaphroditic fishes, this study reports situations that induced female‐to‐male sex change in black‐spot tuskfish, Choerodon schoenleinii, a species of large protogynous fish, in massive laboratory tanks. The situations differed in the possibility of male‐to‐female tactile contact and in the group sex ratio, enabling us to infer plausible proximate mechanisms underlying sex change induction. Tactile contact between individuals is suspected to be closely related to the incidence of female‐to‐male sex change in C. schoenleinii. Visual and chemical cues alone may be insufficient to inhibit such sex changes. Male‐to‐female tactile contact may have an important influence on female‐to‐male sex change, i.e., inhibition of this sex change, in this species. The effect of sex ratio of a social group on the incidence of sex change may be due to the relative frequency and intensity of male tactile contact with each female, which may vary with the number of females. In the absence of a dominant male, tactile contact among females may affect the incidence of sex change, as well as determine which individuals change sex. 相似文献
26.
Recently, bivalves have been massively killed by anoxia or hypoxia in summer at the northern part of Isahaya Bay, Japan, which constituted a major problem for fisheries. However, the mechanism behind the occurrence of hypoxic water masses is unclear. It is known that the bottom water dissolved oxygen (DO) in this area is affected by the inflow of seawater into the northern mouth of Isahaya Bay. To understand the mechanism of hypoxia, it is necessary to determine the physical processes that cause changes in the bottom DO concentrations in this area. This study shows that there is a neap-spring tidal variation in bottom DO due to a change in vertical tidal mixing, and it also suggests that the decrease in bottom DO was generated by a baroclinic flow, which is due to the internal tide, and a shear flow, which is induced by the external tide in the bottom boundary layer. In addition, our study suggests that the source of cold and hypoxic water that appears in the bottom layer at low tide is the inner area of the Ariake Sea. 相似文献
27.
Machiko Yamada Eri Katsuki Mayuko Otsubo Mayumi Kawaguchi Kazuhiko Ichimi Hideki Kaeriyama Kuninao Tada Paul J. Harrison 《Journal of Oceanography》2010,66(6):755-771
Seven Skeletonema species were identified at one station in the industrial harbor Dokai Bay, Japan, in October 2007 and then monthly from January
2008 to December 2009 by morphological scanning electron microscopy observations and molecular analyses of mainly the large
subunit (LSU) rDNA. We refer to one species identified as S. dohrnii using LSU rDNA, but as S. marinoi using the small subunit (SSU) rDNA and consequently we use the term S. marinoi-dohrnii complex. This is the first time that S. ardens, S. costatum s.s., and S. pseudocostatum have been recorded in Japan and that S. menzelii and S. tropicum have been identified by molecular methods in Japan. The S. marinoi-dohrnii complex was isolated with high frequency all year-round, and S. japonicum was also isolated with high frequency but not so in summer. S. Tropicum was isolated from September to December, but S. ardens and S. costatum s.s. were isolated only when the water temperature exceeded 20°C. S. pseudocostatum bloomed just once, in summer, but S. menzelii was isolated in May and again in October. The continuous year-round occurrence of S. costatum s.l. in the bay is supported by the succession of these seven species. Six of the species, except S. menzelii, were important components of algal blooms in the bay. One to four species of Skeletonema were isolated every month. Monthly species diversity was higher when S. ardens, S. costatum s.s., and S. tropicum that are usually associated with tropical or subtropical waters, were isolated. In general, species diversity of the genus
Skeletonema was very high in Dokai Bay. 相似文献
28.
Evidence of microphytobenthic roles on coastal shallow water of the Seto Inland Sea,Japan 总被引:1,自引:0,他引:1
This study describes the temporal variation of microphytobenthic biomass and its controlling factors, as well as the impact
of microphytobenthic activities on coastal shallow sediment in the eastern Seto Inland Sea, Japan. The chlorophyll a (Chl a), phaeopigments and sedimentary biophilic element (C, N, P and Si) contents in surface sediments, as well as nutrient concentrations
at the sediment-water interface (overlying water and pore water) were observed monthly during November 2003 to May 2005 at
one site in Shido Bay (water depth ca. 7 m) and at one site in Harima-Nada (35 m). No correlation was observed between the sedimentary biophilic elements and other
parameters. The maximum chlorophyll a content of 48.2 μg g–1 was found in surface sediments under the photon flux reaching the seafloor of 537 μmol photon m–2 s–1 during the winter period when water transparency was the highest at station S (Shido Bay). Our results suggest that higher
chlorophyll a content in surface sediment was due to the fresh microphytobenthic biomass (mainly benthic diatom). We also found a significant
negative correlation between Chl a and inorganic nutrients in pore water during the low temperature period, especially silicic acid. This result suggests that
the silicic acid was assimilated largely during the increase of microphytobenthic biomass in surface sediment. This study
suggests that the microphytobenthic roles may have a great effect on nutrient budgets during the large supply of irradiance
(winter periods) for their photosynthetic growth in shallow coastal waters. 相似文献
29.