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91.
Stability constants were determined for60Co (II)-amino acid complexes in sodium perchlorate media at an ionic strength=0.67, using cation exchange resins. Stability constants were, for Co(II)-phenylalanine, log 1=4.4, log 2=8.2, log 3=11.7, for Co(II)-histidine, log 1=7.4. for Co(II)-valine, log 1=4.3, log 2=8.5, for Co(II)-proline, log 1=4.1, and for Co(II)-tyrosine, log 1=7.2, respectively. The abundance of Co(II)-amino acid complexes in seawater was calculated from these stability constants on the basis of chemical equilibrium, assuming the concentration of individual amino acid to be 10–7 to 10–8 mol l–1. It was inferred that the Co(II)-amino acid complexes are probably not formed abundantly in seawater while inorganic species of60Co(II) may still be dominant for a short period of time after discharge into seawater as liquid waste.  相似文献   
92.
Global Positioning System (GPS) measurements of the vertical displacement of fast ice near Syowa Station, Antarctica, were conducted between April and December 1998 to evaluate measurements of sea level variation derived with a conventional bottom pressure gauge (BPG). The BPG-derived sea level revealed a seasonal variation of about 0.13 m, with a high in April–June and a low in November–December. The GPS-derived sea level, combined with observed sea ice thickness, supported the BPG result, with an RMS error of 0.007 m. Our result also demonstrates that GPS is a powerful technique for monitoring sea level variations. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
93.
Abstract High-resolution seismic stratigraphy of the Yamato Basin, Japan Sea, was successfully established using core-log-seismic data integration. The construction of synthetic seismograms by the combination of physical properties and well-log data from the Ocean Drilling Program (ODP) Site 797 was the key to accomplishing the high-resolution seismic stratigraphy. To achieve resolution comparable with well-log data and core lithology, single channel seismic reflection data taken from ODP underway geophysics were reprocessed, and then carefully compared with synthetic seismogram, core and well log profiles to identify seismic units. Ten seismic stratigraphic units were identified at the site, and seismic stratigraphic interpretation was successfully extended from the site to the nearby area along the Yamato Basin margin. The opal-A/opal-CT (biogenic silica/metastable diagenetic silica) boundary has different appearances at places from strong to weak, and mostly discontinuous. One of the significant results achieved from this study is clear distinction of the opal-A/CT boundary from a very strong reflector, which appears at 22 m below the opal-A/CT boundary. Through well-log and physical properties characterization of the different units, resistivity was found to be the best indicator of diatom content and with gamma-ray it also is an indicator of chert layers in the opal-CT zone. Velocity is not greatly effected by diatom ooze in the opal-A zone, however, it shows strong peaks and has an indirect relationship with gamma-ray in the opal-CT zone. Finally, successful correlation of Gamma-ray Attenuation Porosity Evaluator density and resistivity peaks with strong seismic reflectors from upper and lower stratified layers may provide new information on the late Neogene paleoceanography of the Japan Sea in high-resolution scale.  相似文献   
94.
In the present study, we used catalyzed reporter deposition-fluorescence in situ hybridization to quantify the abundance of five bacterial (Alphaproteobacteria, SAR11, Gammaproteobacteria, SAR86, and Bacteroidetes) and two archaeal (Crenarchaeota and Euryarchaeota) phylotypes in the epipelagic layer (0–200 m) of the Central South Pacific Ocean along 170°W from 0° to 40°S. We found that the distribution patterns of these phylotypes differed from each other. All phylotypes except Gammaproteobacteria were particularly abundant at the surface water of the equatorial region, whereas Gammaproteobacteria was relatively abundant in the area from the southern part of the South Pacific Ocean. SAR11, affiliated with Alphaproteobacteria was the dominant phylotype at all depths, throughout the study area. The abundance of SAR11 significantly increased with chlorophyll a concentration, suggesting that phytoplankton could affect their distribution pattern. There was a positive correlation between Bacteroidetes abundance and water temperature, suggesting that the temperature gradient could be a critical factor determining their distribution in the South Pacific Ocean. Crenarchaeota and Euryarchaeota were more abundant at the equatorial region than in other study areas. Euryarchaeota abundance significantly decreased with depth, and increased with chlorophyll a concentration. This suggests that there was ecological interaction between Euryarchaeota and phytoplankton in the equatorial surface. Our data indicate that distinct hydrographic properties such as seawater temperature, salinity, and the concentrations of chlorophyll a and nutrients can principally control the basin-scale distribution of different prokaryotic phylotypes in the epipelagic layer of the Central South Pacific Ocean.  相似文献   
95.
http://www.sciencedirect.com/science/article/pii/S1674987112001065   总被引:2,自引:2,他引:0  
It has been thought that granitic crust,having been formed on the surface,must have survived through the Earth’s evolution because of its buoyancy.At subduction zones continental crust is predominantly created by arc magmatism and is returned to the mantle via sediment subduction,subduction erosion, and continental subduction.Granitic rocks,the major constituent of the continental crust,are lighter than the mantle at depths shallower than 270 km,but we show here,based on first principles calculations, that beneath 270 km they have negative buoyancy compared to the surrounding material in the upper mantle and transition zone,and thus can be subducted in the depth range of 270-660 km.This suggests that there can be two reservoirs of granitic material in the Earth,one on the surface and the other at the base of the mantle transition zone(MTZ).The accumulated volume of subducted granitic material at the base of the MTZ might amount to about six times the present volume of the continental crust.Our calculations also show that the seismic velocities of granitic material in the depth range from 270 to 660 km are faster than those of the surrounding mantle.This could explain the anomalous seismic-wave velocities observed around 660 km depth.The observed seismic scatterers and reported splitting of the 660 km discontinuity could be due to jadeite dissociation,chemical discontinuities between granitic material and the surrounding mantle,or a combination thereof.  相似文献   
96.
Rising saline shallow groundwater and associated soil salinization problems are widespread especially in arid and semiarid areas. There have been numerous studies on groundwater-associated salinity, but more information is required on the effects of groundwater frequent and high fluctuations on soil salinization. In the present study, laboratory experiments and numerical simulations using HYDRUS-1D model were carried out for this purpose. The experimental and modeling results showed that groundwater fluctuation caused not only the accumulation of more salt in the soil profile compared to stable groundwater, but also an enhancement of the mechanism. Water table fluctuation induced a much greater spreading of the bromide (Br) tracer within the column than the constant water table. The Br content was on average five orders of magnitude greater under a fluctuating water table than under a constant one. Further, the numerical simulations showed that an increase in the groundwater fluctuation frequency brought about an increase in soil surface salinization under the same evaporation boundary conditions. Additional simulations with HYDRUS-1D were used to study the effects of various management strategies on soil salinization induced by shallow groundwater. Hence, by reducing the evaporation rate through the application of surface mulching, a significant reduction of salt concentration at the soil surface was observed. Moreover, frequent irrigations with small quantities were effective to reduce soil surface salt accumulation induced by saline shallow groundwater.  相似文献   
97.
Abstract— The possibility of ocean water invasion into the Chicxulub crater following the impact at the Cretaceous/Tertiary boundary was investigated based on examination of an impactite between approximately 794.63 and 894.94 m in the Yaxcopoil‐1 (Yax‐1) core. The presence of cross lamination in the uppermost part of the impactite suggests the influence of an ocean current at least during the sedimentation of this interval. Abundant occurrence of nannofossils of late Campanian to early Maastrichtian age in the matrices of samples from the upper part of the impactite suggests that the carbonate sediments deposited on the inner rim margin and outside the crater were eroded and transported into the crater most likely by ocean water that invaded the crater after its formation. The maximum grain size of limestone lithics and vesicular melt fragments, and grain and bulk chemical compositions show a cyclic variation in the upper part of the impactite. The upward fining grain size and the absence of erosional contact at the base of each cycle suggest that the sediments were derived from resuspension of units elsewhere in the crater, most likely by high energy currents association with ocean water invasion.  相似文献   
98.
The annual distribution and dispersal of early‐stage phyllosoma of the Japanese spiny lobster Panulirus japonicus were examined in the East China Sea and the Sea of Japan off western Japan. Early‐stage larvae were sampled mainly in summer and relatively near the coast off western Kyusyu Island. Few larvae were found in the other three seasons in the East China Sea and the Sea of Japan. This finding suggests that P. japonicus larvae are retained in coastal areas for a few months after hatching until stage V and are transported offshore until autumn, before they grow to stage VI. Examination of archival drifter data off western Kyusyu Island during the spawning season of P. japonicus supported the relatively rapid dispersal of the larvae from the East China Sea near Japan to the Pacific Ocean or the Sea of Japan. Larval transport from the East China Sea to the Pacific Ocean, which is considered to be a main distribution area of middle‐ and late‐stage larvae, would occur in the south at approximately 32–33°N in the East China Sea near western Kyusyu Island.  相似文献   
99.
The stability and equation of state for the cotunnite phase in TiO2 were investigated up to a pressure of about 70 GPa by high-pressure in situ X-ray diffraction measurements using a laser-heated diamond anvil cell. The transition sequence under high pressure was rutile → α-PbO2 phase → baddeleyite phase → OI phase → cotunnite phase with increasing pressure. The cotunnite phase was the most stable phase at pressures from 40 GPa to at least 70 GPa. The equation of state parameters for the cotunnite phase were established on the platinum scale using the volume data at pressures of 37–68 GPa after laser annealing, in which the St value, an indicator of the magnitude of the uniaxial stress component in the samples, indicates that these measurements were performed under quasi-hydrostatic conditions. The third-order Birch-Murnaghan equation of state at K 0′ = 4.25 yields V 0 = 15.14(5) cm3/mol and K 0 = 294(9), and the second-order Birch-Murnaghan equation of state yields V 0 = 15.11(5) cm3/mol and K 0 = 306(9). Therefore, we conclude that the bulk modulus for the cotunnite phase is not comparable to that of diamond.  相似文献   
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