Geochemistry and hydrology of perched groundwater springs: assessing elevated uranium concentrations at Pigeon Spring relative to nearby Pigeon Mine,Arizona (USA)     

Kimberly R. Beisner  Nicholas V. Paretti  Fred D. Tillman  David L. Naftz  Donald J. Bills  Katie Walton-Day  Tanya J. Gallegos 《Hydrogeology Journal》2017,25(2):539-556

The processes that affect water chemistry as the water flows from recharge areas through breccia-pipe uranium deposits in the Grand Canyon region of the southwestern United States are not well understood. Pigeon Spring had elevated uranium in 1982 (44 μg/L), compared to other perched springs (2.7–18 μg/L), prior to mining operations at the nearby Pigeon Mine. Perched groundwater springs in an area around the Pigeon Mine were sampled between 2009 and 2015 and compared with material from the Pigeon Mine to better understand the geochemistry and hydrology of the area. Two general groups of perched groundwater springs were identified from this study; one group is characterized by calcium sulfate type water, low uranium activity ratio ²³⁴U/²³⁸U (UAR) values, and a mixture of water with some component of modern water, and the other group by calcium-magnesium sulfate type water, higher UAR values, and radiocarbon ages indicating recharge on the order of several thousand years ago. Multivariate statistical principal components analysis of Pigeon Mine and spring samples indicate Cu, Pb, As, Mn, and Cd concentrations distinguished mining-related leachates from perched groundwater springs. The groundwater potentiometric surface indicates that perched groundwater at Pigeon Mine would likely flow toward the northwest away from Pigeon Spring. The geochemical analysis of the water, sediment and rock samples collected from the Snake Gulch area indicate that the elevated uranium at Pigeon Spring is likely related to a natural source of uranium upgradient from the spring and not likely related to the Pigeon Mine.  相似文献   

Contaminant transport in a fracture with spatially variable aperture in the presence of monodisperse and polydisperse colloids     

Scott C. James  Tanya K. Bilezikjian  Constantinos V. Chrysikopoulos 《Stochastic Environmental Research and Risk Assessment (SERRA)》2005,19(4):266-279

A quasi-three-dimensional particle tracking model is developed to characterize the spatial and temporal effects of advection, molecular diffusion, Taylor dispersion, fracture wall deposition, matrix diffusion, and co-transport processes on two discrete plumes (suspended monodisperse or polydisperse colloids and dissolved contaminants) flowing through a variable aperture fracture situated in a porous medium. Contaminants travel by advection and diffusion and may sorb onto fracture walls and colloid particles, as well as diffuse into and sorb onto the surrounding porous rock matrix. A kinetic isotherm describes contaminant sorption onto colloids and sorbed contaminants assume the unique transport properties of colloids. Sorption of the contaminants that have diffused into the matrix is governed by a first-order kinetic reaction. Colloids travel by advection and diffusion and may attach onto fracture walls; however, they do not penetrate the rock matrix. A probabilistic form of the Boltzmann law describes filtration of both colloids and contaminants on fracture walls. Ensemble-averaged breakthrough curves of many fracture realizations are used to compare arrival times of colloid and contaminant plumes at the fracture outlet. Results show that the presence of colloids enhances contaminant transport (decreased residence times) while matrix diffusion and sorption onto fracture walls retard the transport of contaminants. Model simulations with the polydisperse colloids show increased effects of co-transport processes.  相似文献   

Petrogenesis of peralkaline granite dykes of the Straumsvola complex,western Dronning Maud Land,Antarctica     

Chris?HarrisEmail authorView author&#;s OrcID profile  Tanya?Dreyer  Petrus?le?Roux 《Contributions to Mineralogy and Petrology》2018,173(1):8

Peralkaline syenite and granite dykes cut the Straumsvola nepheline syenite pluton in Western Dronning Maud Land, Antarctica. The average peralkalinity index (PI?=?molecular Al/[Na?+?K]) of the dykes is 1.20 (n?=?29) and manifests itself in the presence of the Zr silicates eudialyte, dalyite and vlasovite, and the Na–Ti silicate, narsarsukite. The dykes appear to have intruded during slow cooling of the nepheline syenite pluton, and the petrogenetic relationship of the dykes and the pluton cannot be related to closed-system processes at low pressure, given the thermal divide that exists between silica-undersaturated and oversaturated magmas. Major and trace element variations in the dykes are consistent with a combination of fractional crystallization of parental peralkaline magma of quartz trachyte composition, and internal mineral segregation prior to final solidification. The distribution of accessory minerals is consistent with late-stage crystallization of isolated melt pockets. The dykes give an Rb–Sr isochron age of 171?±?4.4 Ma, with variable initial ⁸⁷Sr/⁸⁶Sr ratio (0.7075?±?0.0032), and have an average ε _Nd of ? 12.0. Quartz phenocrysts have δ¹⁸O values of 8.4–9.2‰, which are generally in O-isotope equilibrium with bulk rock. Differences in the δ¹⁸O values of quartz and aegirine (average Δ_{quartz?aegirine} = 3.5‰) suggest aegirine formation temperatures around 500 °C, lower than expected for a felsic magma, but consistent with poikilitic aegirine that indicates subsolidus growth. The negative ε _Nd (< ? 10) and magma δ¹⁸O values averaging 8.6‰ (assuming Δ_quartz?magma = 0.6‰) are inconsistent with a magma produced by closed-system fractional crystallization of a mantle-derived magma. By contrast, the nepheline syenite magma had mantle-like δ¹⁸O values and much less negative ε _Nd (average ??3.1, n?=?3). The country rock has similar δ¹⁸O values to the granite dykes (average 8.0‰, n?=?108); this means that models for the petrogenesis of the granites by assimilation are unfeasible, unless an unexposed high-δ¹⁸O contaminant is invoked. Instead, it is proposed that the peralkaline syenite and granite dykes formed by partial melting of alkali-metasomatised gneiss that surrounds the nepheline syenite, followed by fractional crystallization.  相似文献   

An updated method for estimating landslide‐event magnitude          下载免费PDF全文

Hakan Tanyaş  Kate E. Allstadt  Cees J. van Westen 《地球表面变化过程与地形》2018,43(9):1836-1847

Summary statistics derived from the frequency–area distribution (FAD) of inventories of triggered landslides allows for direct comparison of landslides triggered by one event (e.g. earthquake, rainstorm) with another. Such comparisons are vital to understand links between the landslide‐event and the environmental characteristics of the area affected. This could lead to methods for rapid estimation of landslide‐event magnitude, which in turn could lead to estimates of the total triggered landslide area. Previous studies proposed that the FAD of landslides follows an inverse power‐law, which provides the basis to model the size distribution of landslides and to estimate landslide‐event magnitude (mLS), which quantifies the severity of the event. In this study, we use a much larger collection of earthquake‐induced landslide (EQIL) inventories (n=45) than previous studies to show that size distributions are much more variable than previously assumed. We present an updated model and propose a method for estimating mLS and its uncertainty that better fits the observations and is more reproducible, robust, and consistent than existing methods. We validate our model by computing mLS for all of the inventories in our dataset and comparing that with the total landslide areas of the inventories. We show that our method is able to estimate the total landslide area of the events in this larger inventory dataset more successfully than the existing methods. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   

Detailed mineralogy and petrology of highly shocked poikilitic shergottite Northwest Africa 6342     

Tanya V. Kizovski  Kimberly T. Tait  Veronica E. Di Cecco  Lee F. White  Desmond E. Moser 《Meteoritics & planetary science》2019,54(4):768-784

Northwest Africa (NWA) 6342 is an intermediate, poikilitic shergottite, found in Algeria in 2010. It is comprised of two distinct petrographic areas; poikilitic domains with rounded Mg‐rich olivine chadacrysts enclosed by large low‐Ca pyroxene oikocrysts, and a nonpoikilitic domain mainly comprised of subhedral olivine and vesicular recrystallized plagioclase. Oxygen fugacity conditions become more oxidizing during crystallization from the poikilitic to the nonpoikilitic domain (QFM?3.0 to QFM?2.2). As such, it is likely that NWA 6342 experienced a two‐stage (polybaric) crystallization history similar to that of the enriched poikilitic shergottites. NWA 6342 also experienced relatively high levels of shock metamorphism in comparison to most other poikilitic shergottites as evidenced by the fine‐grained recrystallization texture in olivine, as well as melting and subsequent crystallization of plagioclase. The recrystallization of plagioclase requires an extended period of postshock thermal metamorphism for NWA 6342 and similarly shocked intermediate poikilitic shergottites NWA 4797 and Grove Mountains 99027 most likely due to launch from Mars. The similarities in petrology, chemistry, and shock features between these three meteorites indicate that they have similar crystallization and shock histories; possibly originating from the same source area on Mars.  相似文献   

The robustness of the Zr-in-rutile and Ti-in-zircon thermometers during high-temperature metamorphism (Ivrea-Verbano Zone, northern Italy)   总被引：3，自引：0，他引：3  

Tanya A. Ewing  Jörg Hermann  Daniela Rubatto 《Contributions to Mineralogy and Petrology》2013,165(4):757-779

This study investigates the behaviour of the Zr-in-rutile and Ti-in-zircon thermometers in granulite facies metapelites from the Ivrea-Verbano Zone lower crustal section. U–Pb ages of zircon constrain the timing of regional amphibolite–granulite facies metamorphism to 316 ± 3 Ma and record zircon recrystallisation and resetting of U–Pb ages at 276 ± 4 Ma and 258 ± 3 Ma. Zr-in-rutile thermometry records peak contact metamorphic temperatures related to intrusion of mafic magmatic rocks and gives peak temperatures between 900–930 °C and 1,000–1,020 °C that are consistent with the geological settings of the samples. Ti-in-zircon temperatures of 700–800 °C and 810–870 °C record growth or re-equilibration of zircon after cooling from peak temperatures. Ti-in-quartz thermometry for one sample records both peak and retrograde temperatures. Some rutiles in all samples record resetting of Zr-in-rutile temperatures at ~750–800 °C. Electron microprobe profiles across individual rutiles demonstrate that Zr expulsion occurred by recrystallisation rather than by diffusive exchange. Exsolution of small needles of baddelyite or zircon from rutile is an important method of Zr redistribution, but results in no net Zr loss from the grain. The demonstration that Zr-in-rutile thermometry can robustly record peak temperatures that are not recorded by any other thermometer emphasises the relevance of this technique to investigating the evolution of high-grade metamorphic terranes, such as those that characterise the lower crust.  相似文献   

Chemical constraints on the petrogenesis of mildly alkaline lavas from Vestmannaeyjar,Iceland: the Eldfell (1973) and Surtsey (1963–1967) eruptions     

Tanya Furman  Fred A. Frey  Kye-Hun Park 《Contributions to Mineralogy and Petrology》1991,109(1):19-37

The Vestmannaeyjar archipelago is composed of alkalic lavas erupted at the southern end of the active, southward propagating, Eastern Volcanic Zone. Recent eruptions include the most primitive (Surtsey) and most evolved (Eldfell) compositions found in this area. We studied time-stratigraphic sample suites from both eruptions to characterize the magmatic environment of Vestmannacyjar. All samples are nearly homogeneous in radiogenic isotopic ratios (⁸⁷Sr/⁸⁶Sr 0.70304 to 0.70327;¹⁴³Nd/¹⁴⁴Nd 0.51301 to 0.50307;²⁰⁶Pb/²⁰⁴Pb 18.96 to 19.18;²⁰⁷Pb/²⁰⁴Pb 15.50 to 15.53;²⁰⁸Pb/²⁰⁴Pb 38.47 to 38.76; KH Park and A Zindler, in preparation). Compositional trends of lavas from the two eruptions are not consistent with fractionation in a near-surface environment, but indicate rather moderate pressure evolution of small magma batches. At Eldfell, mugearite lavas can be modeled by 30% closed-system fractional crystallization of olivine+plagioclase+clinopyroxene+Fe–Ti oxides from parental hawaiite. The phase proportions are consistent with an experimentally determined moderate pressure (8 kbar) cotectic in mildly alkaline systems (Mahood and Baker 1986). Compositional variations of Surtsey lavas can be modeled by crystallization of clinopyroxene+olivine+plagioclase+minor Fe–Ti oxides. The presence of sodic plagioclase megacrysts and clinopyroxene with 8 wt% Al₂O₃ in xenoliths from Surtsey lavas are consistent with a moderate pressure fractionation event. Based on major-element and REE data the most primitive Surtsey lavas formed by small degrees of melting of a lherzolite source. The alkaline nature of Vestmannaeyjar lavas is not the result of assimilation of lower crustal melts (cf. Oskarsson et al. 1985; Steinthorsson et al. 1985).  相似文献   

Natural attenuation of TCE, As, Hg linked to the heterogeneous oxidation of Fe(II): an AFM study   总被引：1，自引：0，他引：1  

Laurent Charlet  Dirk Bosbach  Tanya Peretyashko   《Chemical Geology》2002,190(1-4):303-319

Hydrous ferric oxide (HFO) colloids formed, in strictly anoxic conditions upon oxidation of Fe²⁺ ions adsorbed on mineral surface, were investigated under in situ conditions by contact mode atomic force microscopy (AFM). Freshly cleaved and acid-etched large single crystals of near endmember phlogopite were pre-equilibrated with dissolved Fe(II) and then reacted with Hg(II), As(V) and trichlorethene (TCE)-bearing solutions at 25 °C and 1 atm. HFO structures are found to be of nanometer scale. The As(V)–Fe(II) and Hg(II)–Fe(II) reaction products are round (25 nm) microcrystallites located predominantly on the layer edges and are indicative of an accelerated Fe(II) oxidation rate upon formation of Fe(II) inner sphere surface complexes with the phyllosilicate edge surface sites. On the other hand, TCE–Fe(II)–phlogopite reaction products are needle-shaped (45 nm long) particles located on the basal plane along the Periodic Bond Chains (PCBs) directions. Experiments with additions of sodium chloride confirm the importance of the Fe(II) adsorption step in the control of the overall heterogeneous Fe(II)–TCE electron transfer reaction.

Kinetic measurements at the nanomolar level of Hg° formed upon reduction of Hg(II) by Fe(II) in presence of phlogopite particles provide further convincing evidence for reduction of Hg(II)_aq coupled to the oxidation of Fe(II) adsorbed at the phlogopite–fluid interface, and indicate that sorption of Fe(II) to mineral surfaces enhances the reduction rate of Hg(II) species. The Hg(II) reduction reaction follows a first-order kinetic law. Under our experimental conditions, which were representative of many natural systems, 80% of the mercury is transferred to the atmosphere as Hg° in less than 2 h.

The reduction of a heavy metal (Hg), a toxic oxyanion (arsenate ion) and a chlorinated solvent (TCE) thus appear to be driven by the high reactivity of adsorbed Fe(II). This is of environmental relevance since these three priority pollutants are that way reductively transformed to a volatile, an immobilizable and a biodegradable species, respectively. Such kinetic data and reaction pathways are important in the evaluation of natural evaluation scenarios, in the optimization of Fe(II)/mineral mixtures as reductants in technical systems, and in general, in predicting the fate and transport of pollutants in natural systems.  相似文献   

Comment on Lockwood and Davis, “On the longitudinal extent of magnetopause reconnection pulses”     

W. J. Heikkila 《Annales Geophysicae》1999,17(2):173-177

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Criticism of reconnection models of the magnetosphere     

Walter J. Heikkila 《Planetary and Space Science》1978,26(2):121-129

Reconnection involves singular lines called X-lines on the day and night sides of the magnetosphere, and the reconnection rate is proportional to the component of the electric field along the X-line. Although there is some indirect support for this model, nevertheless direct support is totally lacking. However, there are two distinct pieces of clearly contradictory observational evidence on the dayside. First is the failure to account for the implied energy dissipation by the magnetopause current, over 10¹¹ W, which should be easily observable as heating or enhanced flow of the plasma near the magnetopause. In marked contrast to this prediction, HEOS-2 satellite data reveal a plasma with decreased energy density and reduced flow. Second, the boundary of closed magnetic field lines is in the wrong location. In the reconnection process the plasma outflow would cut across open field lines toward higher latitudes; there should be a band of open field lines equatorward of the cleft. Observations of trapped energetic particles indicate closed field lines within the entry layer and cleft. Either one of these pieces of evidence is sufficient by itself to require drastic revision, even rejection, of the reconnection model. There is also contradictory evidence on the night side. The last closed field line capable of trapping energetic particles is poleward of auroral arcs. The implication is that the X-line is at the distant magnetopause, and not in the plasma sheet. Consequently, even if the reconnection process were operative at the nightside X-line, it would be isolated from steady state plasma sheet and auroral processes. On the other hand, substorm phenomena, in which stored magnetic energy is converted into particle kinetic energy, necessarily involve an induced electric field; that is excluded in theories of the reconnection process in which it is assumed that curl E = 0. Nevertheless, the observed easy access of energetic solar flare particles to the polar caps, and especially the preservation of interplanetary anisotropies as differences between the two polar caps, argues strongly for an open magnetosphere, with interconnection between geomagnetic and inter-planetary magnetic field lines. It is suggested that the resolution of this apparent paradox involves electric fields parallel to the magnetic field lines somewhere on the dawn and dusk sides of the magnetosphere, with an equipotential dayside magnetopause.  相似文献