Structural variations in derivatives of the bacteriochlorophylls of Chlorobiaceae: impact of stratigraphic resolution on depth profiles as revealed by methanolysis     

Michael A. Wilson  Dominic A. Hodgson  Brendan J. Keely   《Organic Geochemistry》2004,35(11-12):1299

Bacteriochlorophylls c and d, recovered from two sedimentary sequences, were converted to bacteriophaeophorbide methyl esters by methanolysis and analysed by atmospheric pressure chemical ionisation liquid chromatography-multistage mass spectrometry (APCI LC-MSⁿ). The distributions in both settings, a moderately consolidated sediment from Kirisjes Pond, Antarctica, and in a finely laminated microbial mat from Les Salines de la Trinitat, Spain, show significant variations within a narrow depth interval. The overall bacteriophaeophorbide c to d ratios in the two sediments are different, as are the ratios of particular C-3¹ diastereoisomers, indicating distinct differences between the bacterial communities that contributed to each sediment. Furthermore, a shift towards more extensive alkylation in homologues within each sediment is consistent either with changing environmental conditions in the depositional environments, or development-related changes in the structure of the bacterial community, leading to increased competition for light or nutrients.  相似文献   

Further examples of ventifacts and unusual patterned ground from the Falkland Islands, South Atlantic     

Peter Wilson  Emma J. Edwards 《Geografiska Annaler: Series A, Physical Geography》2004,86(1):107-115

Abstract Examples of ventifacts and forms of unusual patterned ground that differ in situation, characteristics and/or origin to types reported previously are described from the Falkland Islands, South Atlantic. The ventifacts, represented by clasts projecting from an eroding tillite shore platform, have been grooved by the passage of windblown sand. The patterned ground forms comprise stone polygons on clay loam regolith, stone polygons on peat, peat‐filled desiccation cracks on peat, and clusters of on‐edge clasts (stone packings) on a gravel beach. Aeolian transport of particles is considered responsible for the infill of the polygonal cracks. The clusters of on‐edge clasts are thought to have developed as a result of wave action, in particular backwash and/or undertow. Although these features occupy small surface areas they provide useful information about local geomorphic processes and testify to the marked diversity of such features in nature.  相似文献   

Using Direct-Push Tools to Map Hydrostratigraphy and Predict MTBE Plume Diving     

John T. Wilson  Randall R. Ross  Steven Acree 《Ground Water Monitoring & Remediation》2005,25(3):93-102

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Hydrological excitations of polar motion, 1993–2002     

J. L. Chen  C. R. Wilson 《Geophysical Journal International》2005,160(3):833-839

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Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths   总被引：5，自引：1，他引：5  

Marcel Guillong  Kathrin Hametner  Eric Reusser  Stephen A. Wilson  Detlef Günther 《Geostandards and Geoanalytical Research》2005,29(3):315-331

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.  相似文献   

Lake District hillslopes     

Peter Wilson 《Geology Today》2011,27(4):149-153

The Lake District is a region of great scenic beauty in north‐west England that has inspired artists and poets alike, and which comes high on the list of classic geological localities in Great Britain in terms of both bedrock and geomorphological features. With its inspiring views, the Lake District is often portrayed as the product of repeated glaciation, mainly because of the clarity of the erosional and depositional features that can be seen there. But since the last glaciers disappeared other processes have been modifying the landscape, processes that have superimposed their own signatures on to the glacial features. Hillslopes in particular have undergone significant changes, as a result of slope failures in both bedrock and superficial sediments. Although these landforms are not unknown, they have not received the same level of investigation as the glacial features, resulting in a limited appreciation of their spatial distribution and significance in reshaping the landscape. This article outlines the characteristics and origins of some slope failure types, and demonstrates that there is still much to learn about the Lake District landscape.  相似文献   

Soil pipe flow tracer experiments: 1. Connectivity and transport characteristics          下载免费PDF全文

G. V. Wilson  J. R. Rigby  M. Ursic  S. M. Dabney 《水文研究》2016,30(8):1265-1279

Much debate has occurred in catchment hydrology regarding the connectivity of flow paths from upslope areas to catchment outlets. This study was conducted in two catchments, one with three upper branches, in a loess soil with a fragipan that fosters lateral flow and exhibits an extensive distribution of soil pipe collapse features. The study aimed to determine the connectivity of multiple soil pipe networks as well as determine pipe flow velocities during storm events. Fluorescein dye was injected directly into soil pipes at the upper most pipe collapse feature of four different hillslopes. Breakthrough curves (BTC) were determined by sampling multiple pipe collapse features downslope. The BTCs were used to determine the ‘average’ (centre of mass) and ‘maximum’ (first arrival) flow velocities. This study confirmed that these catchments contain individual continuous soil pipe networks that extend over 190 m and connect the upper most hillslopes areas with the catchment outlet. While the flow paths are continuous, the individual pipe networks consist of alternating reaches of subsurface flow through soil pipes and reaches of surface flow through gullies formed by pipe collapses. In addition, flow can be occurring both through the subsurface soil pipes simultaneous with surface flow generated by artesian flow from the soil pipes. The pipe flow velocities were as high as 0.3 m/s, which was in the range of streamflow velocities. These pipe flow velocities were also in the range of velocities observed in pinhole erosion tests suggesting that these large, mature soil pipes are still actively eroding. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Intra-community implications of implementing multiple tsunami-evacuation zones in Alameda,California     

Jeff Peters  Nathan Wood  Rick Wilson  Kevin Miller 《Natural Hazards》2016,80(2):975-995

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Agricultural impact assessment and management after three widespread tephra falls in Patagonia,South America     

Heather Craig  Thomas Wilson  Carol Stewart  Gustavo Villarosa  Valeria Outes  Shane Cronin  Susanna Jenkins 《Natural Hazards》2016,82(2):1167-1229

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Using a Thermal Proxy to Examine Sediment–Water Exchange in Mid-Continental Shelf Sandy Sediments     

William B. Savidge  Alicia Wilson  Gwendolyn Woodward 《Aquatic Geochemistry》2016,22(5-6):419-441

Fluid exchange across the sediment–water interface in a sandy open continental shelf setting was studied using heat as a tracer. Summertime tidal oscillation of cross-shelf thermal fronts on the South Atlantic Bight provided a sufficient signal at the sediment–water interface to trace the advective and conductive transport of heat into and out of the seabed, indicating rapid flushing of ocean water through the upper 10–40 cm of the sandy seafloor. A newly developed transport model was applied to the in situ temperature data set to estimate the extent to which heat was transported by advection rather than conduction. Heat transported by shallow 3-D porewater flow processes was accounted for in the model by using a dispersion term, the depth and intensity of which reflected the depth and intensity of shallow flushing. Similar to the results of past studies in shallower and more energetic nearshore settings, transport of heat was greater when higher near-bed velocities and shear stresses occurred over a rippled bed. However, boundary layer processes by themselves were insufficient to promote non-conductive heat transport. Advective heat transport only occurred when both larger boundary layer stresses and thermal instabilities within the porespace were present. The latter process is dependent on shelf-scale heating and cooling of bottom water associated with upwelling events that are not coupled to local-scale boundary layer processes.  相似文献