Geochemistry of volcanic fluids     

Salvatore Inguaggiato  Hiroshi Shinohara  Tobias Fischer 《Bulletin of Volcanology》2011,73(4):369-371

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Distribution of n-alkanes in lacustrine sediments from subtropical lake in Brazil     

Daniele Botelho de Souza  Karina Scurupa Machado  Sandro Froehner  Cristóvão Fernandes Scapulatempo  Tobias Bleninger 《Chemie der Erde / Geochemistry》2011,71(2):171-176

The geochemical composition of lake bed sediments of a tropical reservoir in Brazil have been investigated. The C, N, P composition showed almost no variation between the different sampling points. All samples contained inorganic phosphorus (IP) ranging from 52 to 70%. The Redfield ratios show that the lake is without significant anthropogenic inputs. Most of the organic matter is composed by higher plants decomposition revealed in the total organic carbon (TOC):nitrogen (N) ratio ranging from 15.4 to 57.2. Also, TOC:organic phosphorus (OP) ranged from 265.3 to 933.6, suggesting that most of the organic matter has terrestrial origin from wood plants. The ratios suggest that most organic matter is influenced by the terrestrial characteristics of the watershed. Furthermore, the relative abundance of n-alkane homologues in the sediments was investigated. All samples have been analyzed for the n-alkanes C₈ to C₄₀. The sediments were dominated by n-alkanes C₂₅–C₃₈. It is concluded that n-alkane in sediments mainly come from terrestrial plants, however there is a contribution of submerged aquatic plants, especially in those sites in deeper areas of the lake. On the basis of P_aq index the n-alkanes in sediments comes from terrestrial plants, however there is a contribution from emerged/floating plants.The investigated lake seems to be considered as meso to eutrophic. Because of the relatively high primary productivity in the lakes, there is a substantial organic-matter flux to the sediments, which rapidly becomes anoxic. According to the pristine/phytane ratio the sediments represent an anoxic environment with values found between 0.38 and 1.72.  相似文献   

Phosphate oxygen isotopes: Insights into sedimentary phosphorus cycling from the Benguela upwelling system   总被引：1，自引：0，他引：1  

Tobias Goldhammer  Benjamin Brunner  Stefano M. Bernasconi  Matthias Zabel 《Geochimica et cosmochimica acta》2011,75(13):3741-3756

Marine sediments are the main sink in the oceanic phosphorus (P) cycle. The activity of benthic microorganisms is decisive for regeneration, reflux, or burial of inorganic phosphate (P_i), which has a strong impact on marine productivity. Recent formation of phosphorites on the continental shelf and a succession of different sedimentary environments make the Benguela upwelling system a prime region for studying the role of microbes in P biogeochemistry. The oxygen isotope signature of pore water phosphate (δ¹⁸O_P) carries characteristic information of microbial P cycling: Intracellular turnover of phosphorylated biomolecules results in isotopic equilibrium with ambient water, while enzymatic regeneration of P_i from organic matter produces distinct offsets from equilibrium. The balance of these two processes is the major control for δ¹⁸O_P.Our study assesses the importance of microbial P cycling relative to regeneration of P_i from organic matter from a transect across the Namibian continental shelf and slope by combining pore water chemistry (sulfate, sulfide, ferrous iron, P_i), steady-state turnover rate modeling, and oxygen isotope geochemistry of P_i.We found δ¹⁸O_P values in a range from 12.8‰ to 26.6‰, both in equilibrium as well as pronounced disequilibrium with water. Our data show a trend towards regeneration signatures (disequilibrium) under low mineralization activity and low P_i concentrations, and microbial turnover signatures (equilibrium) under high mineralization activity and high P_i concentrations. These findings are opposite to observations from water column studies where regeneration signatures were found to coincide with high mineralization activity and high P_i concentrations. It appears that preferential P_i regeneration in marine sediments does not necessarily coincide with a disequilibrium δ¹⁸O_P signature. We propose that microbial P_i uptake strategies, which are controlled by P_i availability, are decisive for the alteration of the isotope signature. This hypothesis is supported by the observation of efficient microbial P_i turnover (equilibrium signatures) in the phosphogenic sediments of the Benguela upwelling system.  相似文献   

A case study on the correlation of micro-contaminants and potassium in the Leine River (Germany)   总被引：1，自引：0，他引：1  

Karsten Nödler  Tobias Licha  Steffi Fischer  Bianca Wagner  Martin Sauter 《Applied Geochemistry》2011,26(12):2172-2180

River monitoring with focus on the correlation of 41 micro-contaminants with K⁺ and its temporal and spatial variation was carried out in the Leine River (Germany). A positive correlation of concentrations of wastewater-related micro-contaminants and K⁺ is to be expected in receiving waters of wastewater treatment plant (WWTP) effluent since urine is a significant source of K⁺ in WWTP effluent. This correlation was found for compounds, which meet the following criteria: (1) WWTP effluent is the dominating source of the compound, (2) variability of its mass flux in the WWTP is negligible, and (3) the compound is persistent in WWTPs and in the environment. The excellent positive correlation of carbamazepine with K⁺ resulted in the fitting of a universal linear equation to the summer and winter data. For almost all other correlating compounds (1H-benzotriazole, citalopram, diclofenac, metoprolol, sotalol, sulfamethoxazole and tolyltriazole), slopes of the line fittings were steeper in winter (x-axis: K⁺, y-axis: respective micro-contaminant). This has been attributed to a presumed lower degree of degradation and attenuation within WWTPs and in the environment due to low temperatures as well as an increase in consumption of these compounds in the winter months. As part of this research, a sampling event along the entire flow path of the Leine River (∼280 km) was conducted to identify compounds demonstrating stable ratios of various respective micro-contaminants with K⁺. Among other compounds, carbamazepine, sulfamethoxazole, and tolyltriazole demonstrated the best correlations with R² > 0.89. Potassium-equivalents of the individual micro-contaminants depended on land use and population structure of the investigated river section.  相似文献   

Climate change effects on snow melt and discharge of a partly glacierized watershed in Central Switzerland (SoilTrec Critical Zone Observatory)     

Florian Kobierska  Tobias Jonas  Jan Magnusson  Massimiliano Zappa  Mathias Bavay  Thomas Bosshard  Frank Paul  Stefano M. Bernasconi 《Applied Geochemistry》2011

A comprehensive hydrological modeling study in the drainage area of a hydropower reservoir in central Switzerland is presented. Two models were tested to reproduce the measured discharge dynamics: (1) a detailed energy-balance model (ALPINE3D) primarily designed for snow simulations; (2) a conceptual runoff model system (PREVAH), including a distributed temperature-index snow and ice melt model. Considerable effort was put into distributing available meteorological station data to the model grids as forcing data. The recent EU regional climate modeling initiative ENSEMBLES provided up-to-date climate predictions for two 30-a periods in mid and late 21st century. These were used to estimate evolutions in the water supply of the hydropower reservoir in response to expected climate changes. The simulations suggest a shift of spring peak-flow by almost two months for the end of the century. Warmer winter temperatures will cause higher winter base-flow. Due to glacier retreat, late-summer flow will decrease at the end of the century.  相似文献   

Erratum to: Winter storm- and summer thunderstorm-related loss events with regard to climate change in Germany     

Friedrich-Wilhelm Gerstengarbe  Peter C. Werner  Hermann Österle  Tobias Pardowitz  Olaf Burghoff 《Theoretical and Applied Climatology》2013,114(3-4):729-729

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Alpine snow cover in a changing climate: a regional climate model perspective     

Christian Steger  Sven Kotlarski  Tobias Jonas  Christoph Schär 《Climate Dynamics》2013,41(3-4):735-754

An analysis is presented of an ensemble of regional climate model (RCM) experiments from the ENSEMBLES project in terms of mean winter snow water equivalent (SWE), the seasonal evolution of snow cover, and the duration of the continuous snow cover season in the European Alps. Two sets of simulations are considered, one driven by GCMs assuming the SRES A1B greenhouse gas scenario for the period 1951–2099, and the other by the ERA-40 reanalysis for the recent past. The simulated SWE for Switzerland for the winters 1971–2000 is validated against an observational data set derived from daily snow depth measurements. Model validation shows that the RCMs are capable of simulating the general spatial and seasonal variability of Alpine snow cover, but generally underestimate snow at elevations below 1,000 m and overestimate snow above 1,500 m. Model biases in snow cover can partly be related to biases in the atmospheric forcing. The analysis of climate projections for the twenty first century reveals high inter-model agreement on the following points: The strongest relative reduction in winter mean SWE is found below 1,500 m, amounting to 40–80 % by mid century relative to 1971–2000 and depending upon the model considered. At these elevations, mean winter temperatures are close to the melting point. At higher elevations the decrease of mean winter SWE is less pronounced but still a robust feature. For instance, at elevations of 2,000–2,500 m, SWE reductions amount to 10–60 % by mid century and to 30–80 % by the end of the century. The duration of the continuous snow cover season shows an asymmetric reduction with strongest shortening in springtime when ablation is the dominant factor for changes in SWE. We also find a substantial ensemble-mean reduction of snow reliability relevant to winter tourism at elevations below about 1,800 m by mid century, and at elevations below about 2,000 m by the end of the century.  相似文献   

Mapping global land system archetypes   总被引：1，自引：0，他引：1  

Tomáš Václavík  Sven Lautenbach  Tobias Kuemmerle  Ralf Seppelt 《Global Environmental Change》2013,23(6):1637-1647

Land use is a key driver of global environmental change. Unless major shifts in consumptive behaviours occur, land-based production will have to increase drastically to meet future demands for food and other commodities. One approach to better understand the drivers and impacts of agricultural intensification is the identification of global, archetypical patterns of land systems. Current approaches focus on broad-scale representations of dominant land cover with limited consideration of land-use intensity. In this study, we derived a new global representation of land systems based on more than 30 high-resolution datasets on land-use intensity, environmental conditions and socioeconomic indicators. Using a self-organizing map algorithm, we identified and mapped twelve archetypes of land systems for the year 2005. Our analysis reveals similarities in land systems across the globe but the diverse pattern at sub-national scales implies that there are no ‘one-size-fits-all’ solutions to sustainable land management. Our results help to identify generic patterns of land pressures and environmental threats and provide means to target regionalized strategies to cope with the challenges of global change. Mapping global archetypes of land systems represents a first step towards better understanding the global patterns of human–environment interactions and the environmental and social outcomes of land system dynamics.  相似文献   

Does the Fornax dwarf spheroidal have a central cusp or core?     

Tobias Goerdt  Ben Moore  J. I. Read  Joachim Stadel  Marcel Zemp 《Monthly notices of the Royal Astronomical Society》2006,368(3):1073-1077

The dark matter dominated Fornax dwarf spheroidal has five globular clusters orbiting at ∼1 kpc from its centre. In a cuspy cold dark matter halo the globulars would sink to the centre from their current positions within a few Gyr, presenting a puzzle as to why they survive undigested at the present epoch. We show that a solution to this timing problem is to adopt a cored dark matter halo. We use numerical simulations and analytic calculations to show that, under these conditions, the sinking time becomes many Hubble times; the globulars effectively stall at the dark matter core radius. We conclude that the Fornax dwarf spheroidal has a shallow inner density profile with a core radius constrained by the observed positions of its globular clusters. If the phase space density of the core is primordial then it implies a warm dark matter particle and gives an upper limit to its mass of ∼0.5 keV, consistent with that required to significantly alleviate the substructure problem.  相似文献   

Attaining m s<Superscript>−1</Superscript> level intrinsic Doppler precision with RHEA,a low-cost single-mode spectrograph     

Tobias Feger  Michael J. Ireland  Christian Schwab  Joao Bento  Carlos Bacigalupo  David W. Coutts 《Experimental Astronomy》2016,42(3):285-300

We present RHEA, a compact and inexpensive single-mode spectrograph which is built to exploit the capabilities of modest-sized telescopes in an economic way. The instrument is fed by up to seven optical waveguides with the aim of achieving an efficient and modal-noise-free unit, suitable for attaining extreme Doppler precision. The cross-dispersed layout features a wavelength coverage from 430–650 nm, with spectral resolution of R ～75,000. When coupled to small telescopes using fast tip/tilt control, our instrument is well-suited to sensitive spectroscopy. Example science cases are accurate radial velocity studies of low to intermediate-mass giant stars with the purpose of searching for giant plants and using asteroseismology to simultaneously measure the host star parameters. In this paper we describe the final instrument design and present first results from testing the internal stability.  相似文献