New constraints on carbonation associated with brecciation in hyperextended margins (example of Iberia and Newfoundland margins)     

Suzanne Picazo  Romain Lafay  Vincent Faucheux  Torsten Vennemann 《地学学报》2019,31(4):317-331

The sequestration of CO₂ occurs naturally in (ultra)‐mafic rocks by carbonation processes and is commonly noted in areas of the seafloor where mantle lithologies are exhumed. As well as carbonation, mantle exhumation is also responsible for rock brecciation. The relationship between carbonation and brecciation is not well constrained. A temporal evolution from syn‐ to post‐tectonic carbonation and brecciation is proposed in line with progressive mantle exhumation. Using a petrological study of brecciated material from IODP drill cores of the Iberia–Newfoundland conjugated margins, we relate crack–seal veins to tectonic brecciation, authigenic calcite with scalenohedral structure to hydraulic brecciation and reworked clasts within cement to (tectono)‐sedimentary processes. Oxygen isotope compositions reveal late‐staged < 50°C carbonate generation in the proximal part of the ocean–continent transition, which have followed an earlier phase of sub‐seafloor carbonate generation. The results are crucial to understand CO₂ exchange within the reworked sub‐seafloor in passive margins and oceanic systems.  相似文献   

The transition from porphyry- to epithermal-style gold mineralization at Ladolam, Lihir Island, Papua New Guinea: a reconnaissance study   总被引：8，自引：0，他引：8  

Daniel Müller  Klaus Kaminski  Stephan Uhlig  Torsten Graupner  Peter M. Herzig  Steve Hunt 《Mineralium Deposita》2002,37(1):61-74

The exceptionally large gold resource at Ladolam (>1,300 metric tons of gold), Lihir Island, resulted from the transition of an early-stage, low-grade porphyry gold system to a low-sulfidation epithermal gold event. This transition was probably triggered by rapid decompression during the partial slope failure of Luise stratovolcano and accompanied by the ingress of seawater. The original porphyry stage is indicated by remnant hydrothermal breccia clasts of strongly biotite-magnetite altered monzodiorite with disseminated pyrite - chalcopyrite and poorly developed pyrite - quartz stockwork veins. The breccias are overprinted by biotite-magnetite alteration and their matrix is strongly mineralized with disseminated auriferous pyrite. The breccias are cut by late-stage epithermal quartz-chalcedony-illite-adularia-pyrite veins and associated illite-adularia alteration that locally contain bonanza gold grades of up to 120 g/t. Isotope data suggest a magmatic source of sulfur in the gold-bearing fluids at Ladolam. Electronic supplementary material to this paper can be obtained by using the Springer LINK server located at http://dx.doi.org/10.1007/s00126-001-0230-y  相似文献   

Luminescence dating of lacustrine sediments from Tangra Yumco (southern Tibetan Plateau) using post‐IR IRSL signals from polymineral grains          下载免费PDF全文

Hao Long  Torsten Haberzettl  Sumiko Tsukamoto  Ji Shen  Thomas Kasper  Gerhard Daut  Liping Zhu  Roland Mäusbacher  Manfred Frechen 《Boreas: An International Journal of Quaternary Research》2015,44(1):139-152

Radiocarbon dating of bulk organic matter is the most commonly used method for establishing chronologies of lake sediments for palaeoclimate reconstructions on the Tibetan Plateau. However, this method is likely to be problematic because the dated material often suffers from old carbon contamination. Recently, advances in luminescence‐based chronological techniques have provided new options for dating lacustrine sediments. In the current study, we tested for the first time the applicability of a new post‐IR IRSL (pIRIR) measurement protocol for dating fine‐grained polymineral material from a deep‐lake sediment core from the central part of Tangra Yumco, on the southern Tibetan Plateau. Our results show that: (i) radioactive disequilibria in the uranium decay chain were observed in the studied lake sediments, and thus taken into account for dose rate calculation by using a dynamic modelling approach; (ii) the suitability and robustness of the pIRIR protocol measured at 150°C (pIRIR₁₅₀) for our samples are confirmed by a set of luminescence characteristic tests as well as the agreement with an independent age control; (iii) turbidite deposition partly caused an insufficient resetting of luminescence signals and thus apparent overestimation in luminescence dating; (iv) compared with the luminescence‐based age‐depth model, the ¹⁴C ages of bulk organic matter from the studied core generally yielded an age difference of ～2 ka, which is attributed to hardwater reservoir effects in Tangra Yumco. This study highlights the need for multi‐dating approaches of lake sedimentary archives on the Tibetan Plateau.  相似文献   

Joint inversion of groundwater flow,heat, and solute state variables: a multipurpose approach for characterization and forecast of karst systems     

Kavousi  Alireza  Reimann  Thomas  Wöhling  Thomas  Birk  Steffen  Luhmann  Andrew J.  Kordilla  Jannes  Noffz  Torsten  Sauter  Martin  Liedl  Rudolf 《Hydrogeology Journal》2023,31(4):1005-1030

Characterization of karst systems and forecast of their state variables are essential for groundwater management and engineering in karst regions. These objectives can be met by the use of process-based discrete-continuum models (DCMs). However, results of DCMs may suffer from inversion nonuniqueness. It has been demonstrated that the joint inversion of observations regulated by different natural processes can tackle the nonuniqueness issue in groundwater modeling. However, this has not been tested for DCMs thus far. This research proposes a methodology for the joint inversion of hydro-thermo-chemo-graphs, applying to two small-scale sink-to-spring experiments at Freiheit Spring, Minnesota, USA. In order to address conceptual uncertainty, a multimodel approach was implemented, featuring seven mutually exclusive variants. Spring hydro-thermo-chemo-graphs, for all the variants simulated by MODFLOW-CFPv2, were jointly inverted using a weighted least squares algorithm. Subsequently, models were compared in terms of inversion and forecast performances, as well as parameter uncertainties. Results reveal the suitability of the DCM approach for simultaneous inversion and forecast of hydro-physico-chemical behavior of karst systems, even at a scale of meters and seconds. The estimated volume of the tracer conduit passage ranges from approximately 46–51 m³, which is comparable to the estimate from the flood-pulse method. Moreover, it was demonstrated that the thermograph and hydrograph contain more information about aquifer characteristics than the chemograph. However, this finding can be site-specific and should depend on the analysis scale, the considered conceptual models, and the hydrological state, which are potentially affected by minor unaccountable processes and features.

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Speeding Up the Analytical Workflow for Coltan Fingerprinting by an Integrated Mineral Liberation Analysis/LA‐ICP‐MS Approach     

Hans‐Eike Gäbler  Frank Melcher  Torsten Graupner  Andreas Bahr  Maria A. Sitnikova  Friedhelm Henjes‐Kunst  Thomas Oberthür  Helene Brätz  Axel Gerdes 《Geostandards and Geoanalytical Research》2011,35(4):431-448

Coltan (the African trade name for columbite‐tantalite, a tantalum ore) is one of several raw materials that finance the civil wars in the eastern provinces of the Democratic Republic of the Congo. To improve the transparency along the tantalum trade chain, a ‘certificate of origin’ for so‐called ‘conflict minerals’ has been recommended by the United Nations. Accordingly, the German Federal Institute for Geosciences and Natural Resources (BGR) has developed an analytical fingerprint procedure for coltan. Mineral formation age, modal mineralogy and chemical composition are important fingerprint parameters. The original workflow to obtain these parameters was streamlined and is now based on mineral liberation analysis and LA‐ICP‐MS. The use of an ICP‐MS instrument with a detector system covering an extended linear dynamic range and the application of an internal standard‐independent calibration strategy allowed data for major and trace element determination and mineral formation age estimates to be obtained simultaneously. The analytical results of this new approach were compared with analytical techniques of the original workflow and showed excellent agreement in terms of mineralogical and chemical characterisation and mineral formation age of coltan samples. Within a test, samples of different origin were allocated correctly and simple, binary mixtures were also identified successfully.  相似文献   

Trace element depth profiles in presolar silicon carbide grains     

Ashley J. KING  Torsten HENKEL  Detlef ROST  Ian C. LYON 《Meteoritics & planetary science》2012,47(10):1624-1643

Abstract– We have analyzed eleven presolar SiC grains from the Murchison meteorite using time‐of‐flight secondary ion mass spectrometry. The Si isotopic compositions of the grains indicate that they are probably of an AGB star origin. The average abundances of Mg, Fe, Ca, Al, Ti, and V are strongly influenced by their condensation behavior into SiC in circumstellar environments. Depth profiles of Li, B, Mg, Al, K, Ca, Ti, V, Cr, and Fe in the SiC grains show that trace elements are not always homogenously distributed. In approximately half of the SiC grains studied here, the trace element distributions can be explained by condensation processes around the grains’ parent stars. These grains appear to have experienced only minimal processing before their arrival in the presolar molecular cloud, possibly due to short residence times in the interstellar medium. The remaining SiC grains contained elevated abundances of several elements within their outer 200 nm, which is attributed to the implantation of energetic ions accelerated by shockwaves in the interstellar medium. These grains may have spent a longer period of time in this region, hence increasing the probability of them passing through a shockfront. Distinct groups of presolar SiC grains whose residence times in the interstellar medium differ are consistent with previous findings based on noble gas studies, although some grains may also have been shielded from secondary alteration by protective outer mantles.  相似文献   

Hydraulic fracturing in unconventional gas reservoirs: risks in the geological system part 1   总被引：2，自引：2，他引：0  

Torsten Lange  Martin Sauter  Michael Heitfeld  Kurt Schetelig  Karolin Brosig  Wiebke Jahnke  Alexander Kissinger  Rainer Helmig  Anozie Ebigbo  Holger Class 《Environmental Earth Sciences》2013,70(8):3839-3853

Hydraulic fracturing of unconventional gas reservoirs rapidly developed especially in the USA to an industrial scale during the last decade. Potential adverse effects such as the deterioration of the quality of exploitable groundwater resources, areal footprints, or even the climate impact were not assessed. Because hydraulic fracturing has already been practised for a long time also in conventional reservoirs, the expansion into the unconventional domain was considered to be just a minor but not a technological step, with potential environmental risks. Thus, safety and environmental protection regulations were not critically developed or refined. Consequently, virtually no baseline conditions were documented before on-site applications as proof of evidence for the net effect of environmental impacts. Not only growing concerns in the general public, but also in the administrations in Germany promoted the commissioning of several expert opinions, evaluating safety, potential risks, and footprints of the technology in focus. The first two publications of the workgroup “Risks in the Geological System” of the independent “Information and Dialogue process on hydraulic fracturing” (commissioned by ExxonMobil Production Deutschland GmbH) comprises the strategy and approaches to identify and assess the potential risks of groundwater contamination of the exploitable groundwater system in the context of hydraulic fracturing operations in the Münsterland cretaceous basin and the Lower Saxony Basin, Germany. While being specific with respect to local geology and the estimation of effective hydraulic parameters, generalized concepts for the contamination risk assessment were developed. The work focuses on barrier effectiveness of different units of the overburden with respect to the migration of fracking fluids and methane, and considers fault zones as potential fluid pathway structures.  相似文献   

Modeling the effect of stratification on cemented layer formation in sulfide-bearing mine tailings     

Jeannet A. Meima  Torsten GraupnerDieter Rammlmair 《Applied Geochemistry》2012

Reactive transport simulations have been applied to investigate possible effects of stratification on the potential of sulfide-bearing mine tailings to form protective cemented layers. The simulations are based on characteristic strata found at a German tailings site, including sulfide-enriched heavy mineral layers, mica-enriched silt layers, and homogeneously mixed layers. The simulated secondary phases (jarosite, gypsum, amorphous ferric arsenate, amorphous Fe hydroxide, alunite, amorphous silica, and kaolinite) are similar to those observed in the field. Using scanning electron microscope analyses of cemented layers, it has been observed that the pore area becomes disconnected if the porosity is decreased to values below 15%, which would indicate a strong decrease in permeability. Stratification was found to play a crucial role in cemented layer formation. Cemented layers are absent or insignificant in systems with a homogeneous distribution of Fe-bearing sulfides. They are extensively developed in systems with (a) an arsenopyrite-rich layer or (b) a mica-enriched layer situated immediately below an Fe-sulfide enriched layer. The modeling results have clearly demonstrated that the key processes operating in scenario (a) are very different from the key processes in scenario (b). In scenario (a), the oxidation of arsenopyrite is followed by the precipitation of amorphous ferric arsenate, which can be solely responsible for significant pore reduction. In scenario (b), the presence of a large amount of reactive aluminosilicates (e.g. biotite and Ca-bearing plagioclase) immediately below the Fe-sulfide rich layer appears to be crucial. Key processes are extensive formation of Acid Rock Drainage (ARD) followed by enhanced (pH-driven) weathering of aluminosilicates, resulting in the accumulation of secondary phases directly below the Fe-sulfide rich layer. In both scenarios, a cemented layer is formed that effectively retards the further downward movement of the oxidation front. The presented details on the role of stratification in the formation of cemented layers could be considered in the construction of mining heaps as a possible measure to stimulate natural attenuation.  相似文献   

How much information is geospatially referenced? Networks and cognition     

Stefan Hahmann  Dirk Burghardt 《International journal of geographical information science》2013,27(6):1171-1189

The aim of this article is to provide a basis in evidence for (or against) the much-quoted assertion that 80% of all information is geospatially referenced. For this purpose, two approaches are presented that are intended to capture the portion of geospatially referenced information in user-generated content: a network approach and a cognitive approach. In the network approach, the German Wikipedia is used as a research corpus. It is considered a network with the articles being nodes and the links being edges. The Network Degree of Geospatial Reference (NDGR) is introduced as an indicator to measure the network approach. We define NDGR as the shortest path between any Wikipedia article and the closest article within the network that is labeled with coordinates in its headline. An analysis of the German Wikipedia employing this approach shows that 78% of all articles have a coordinate themselves or are directly linked to at least one article that has geospatial coordinates. The cognitive approach is manifested by the categories of geospatial reference (CGR): direct, indirect, and non-geospatial reference. These are categories that may be distinguished and applied by humans. An empirical study including 380 participants was conducted. The results of both approaches are synthesized with the aim to (1) examine correlations between NDGR and the human conceptualization of geospatial reference and (2) to separate geospatial from non-geospatial information. From the results of this synthesis, it can be concluded that 56–59% of the articles within Wikipedia can be considered to be directly or indirectly geospatially referenced. The article thus describes a method to check the validity of the ‘80%-assertion’ for information corpora that can be modeled using graphs (e.g., the World Wide Web, the Semantic Web, and Wikipedia). For the corpus investigated here (Wikipedia), the ‘80%-assertion’ cannot be confirmed, but would need to be reformulated as a ‘60%-assertion’.  相似文献   

Magnetic field seeding by galactic winds     

Serena Bertone  Corina Vogt  Torsten Enßlin 《Monthly notices of the Royal Astronomical Society》2006,370(1):319-330

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