Nd and Sr isotope compositions in modern and fossil bones - Proxies for vertebrate provenance and taphonomy     

Thomas Tütken  Torsten W. Vennemann 《Geochimica et cosmochimica acta》2011,75(20):5951-8

Rare earth elements (REE), while not essential for the physiologic functions of animals, are ingested and incorporated in ppb concentrations in bones and teeth. Nd isotope compositions of modern bones of animals from isotopically distinct habitats demonstrate that the ¹⁴³Nd/¹⁴⁴Nd of the apatite can be used as a fingerprint for bedrock geology or ambient water mass. This potentially allows the provenance and migration of extant vertebrates to be traced, similar to the use of Sr isotopes. Although REE may be enriched by up to 5 orders of magnitude during diagenesis and recrystallization of bone apatite, in vivo¹⁴³Nd/¹⁴⁴Nd may be preserved in the inner cortex of fossil bones or enamel. However, tracking the provenance of ancient or extinct vertebrates is possible only for well-preserved archeological and paleontological skeletal remains with in vivo-like Nd contents at the ppb-level. Intra-bone and -tooth REE analysis can be used to screen for appropriate areas. Large intra-bone Nd concentration gradients of 10¹-10³ are often measured. Nd concentrations in the inner bone cortex increase over timescales of millions of years, while bone rims may be enriched over millenial timescales. Nevertheless, ε_Nd values are often similar within one ε_Nd unit within a single bone. Larger intra-bone differences in specimens may either reflect a partial preservation of in vivo values or changing ε_Nd values of the diagenetic fluid during fossilization. However, most fossil specimens and the outer rims of bones will record taphonomic ¹⁴³Nd/¹⁴⁴Nd incorporated post mortem during diagenesis. Unlike REE patterns, ¹⁴³Nd/¹⁴⁴Nd are not biased by fractionation processes during REE-uptake into the apatite crystal lattice, hence the ε_Nd value is an important tracer for taphonomy and reworking. Bones and teeth from autochthonous fossil assemblages have small variations of ±1 ε_Nd unit only. In contrast, fossil bones and teeth from over 20 different marine and terrestrial fossil sites have a total range of ε_Nd values from -13.0 to 4.9 (n = 80), often matching the composition of the embedding sediment. This implies that the surrounding sediment is the source of Nd in the fossil bones and that the specimens of this study seem not to have been reworked. Differences in ε_Nd values between skeletal remains and embedding sediment may either indicate reworking of fossils and/or a REE-uptake from a diagenetic fluid with non-sediment derived ε_Nd values. The latter often applies to fossil shark teeth, which may preserve paleo-seawater values. Complementary to ε_Nd values, ⁸⁷Sr/⁸⁶Sr can help to further constrain the fossil provenance and reworking.  相似文献   

Rock magnetic study of basic intrusions and massive sulphides in the Hercynian central Jebilets Massif (Occidental-Meseta), Morocco     

Najib El Goumi  Mohammed Jaffal  Christian Rolf  Christoph Grissemann  Frank Melcher  Azzouz Kchikach  Mohammed Hibti  Torsten Graupner 《Arabian Journal of Geosciences》2013,6(7):2581-2597

This paper describes a multidisciplinary study approach (petrography and rock magnetism) conducted on samples collected from the study area to characterise the magnetic mineralogy and to determine if the magnetisation of both lithologies were induced or retain a remnant component. Petrophysical, mineralogical and geochemical analyses confirm bimodal aspects, particularly in basic rocks; the two magnetic modes depend essentially on the mineralogical and geochemical characteristics of the samples. The ultramafic rocks comprise a highly altered primary mineralogy with chromite and magnetite as magnetic phases. The second type is of mafic composition with a less altered primary mineralogy and essentially magnetite and/or (hemo-ilmenite) as a carrier of magnetic mineralisation. Sulphides are characterised by high concentrations of Cu, Zn and Pb. The mineralogy is composed mainly of pyrrhotite (85% to 90%), sphalerite, galena, chalcopyrite, arsenopyrite and, occasionally, stannite. Monocline pyrrhotite seems to be the magnetic carrier of magnetisation in both Draa Sfar and Koudiat Aïcha. However, we suspect a different amount of hexagonal pyrrhotite as the cause of different magnetic behaviour. Paleomagnetic and thermomagnetic analyses reveal different. The calculated characteristic direction of natural remnant magnetisation for sulphides was used to model the magnetic anomaly of Draa Sfar. The proposed model match the geological features concluded from geological mapping and boreholes. Results from this work can be very useful for any modelling processes of magnetic anomalies suspected due to a sulphide mineralisation in an area with poor outcrops and no presence of boreholes information or of any geological or geochemical data.  相似文献   

Persistence of Artemisia steppe in the Tangra Yumco Basin,west-central Tibet,China: despite or in consequence of Holocene lake-level changes?     

Sabine Miehe  Georg Miehe  Jacqueline F. N. van Leeuwen  Claudia Wrozyna  Willem O. van der Knaap  La Duo  Torsten Haberzettl 《Journal of Paleolimnology》2014,51(2):267-285

The closed Tangra Yumco Basin underwent the strongest Quaternary lake-level changes so far recorded on the Tibetan Plateau. It was hitherto unknown what effect this had on local Holocene vegetation development. A 3.6-m sediment core from a recessional lake terrace at 4,700 m a.s.l., 160 m above the present lake level of Tangra Yumco, was studied to reconstruct Holocene flooding phases (sedimentology and ostracod analyses), vegetation dynamics and human influence (palynology, charcoal and coprophilous fungi analyses). Peat at the base of the profile proves lake level was below 4,700 m a.s.l. during the Pleistocene/Holocene transition. A deep-lake phase started after 11 cal ka BP, but the ostracod record indicates the level was not higher than ~4,720 m a.s.l. (180 m above present) and decreased gradually after the early Holocene maximum. Additional sediment ages from the basin suggest recession of Tangra Yumco from the coring site after 2.6 cal ka BP, with a shallow local lake persisting at the site until ~1 cal ka BP. The final peat formation indicates drier conditions thereafter. Persistence of Artemisia steppe during the Holocene lake high-stand resembles palynological records from west Tibet that indicate early Holocene aridity, in spite of high lake levels that may have resulted from meltwater input. Yet pollen assemblages indicate humidity closer to that of present potential forest areas near Lhasa, with 500–600 mm annual precipitation. Thus, the early mid-Holocene humidity was sufficient to sustain at least juniper forest, but Artemisia dominance persisted as a consequence of a combination of environmental disturbances such as (1) strong early Holocene climate fluctuations, (2) inundation of habitats suitable for forest, (3) extensive water surfaces that served as barriers to terrestrial diaspore transport from refuge areas, (4) strong erosion that denuded the non-flooded upper slopes and (5) increasing human influence since the late glacial.  相似文献   

Potential influence of the chemical composition of water on the stable oxygen isotope composition of continental ostracods     

Laurent Decrouy  Torsten Walter Vennemann 《Journal of Paleolimnology》2013,50(4):577-582

Many studies in continental areas have successfully used the oxygen isotope composition of fossil ostracod valves to reconstruct past hydrological conditions associated with large changes in climate. Yet, ostracods are known to crystallise their valves out of isotopic equilibrium for oxygen and they generally have higher ¹⁸O contents compared to inorganic calcite grown at equilibrium under the same conditions. A review of vital offsets determined for continental ostracods indicates that vital offsets might change from site to site, questioning a potential influence of environmental conditions on oxygen isotope fractionation in ostracods. Results from the literature suggest that pH has no influence on ostracod vital offset. A re-evaluation of results from Li and Liu (J Paleolimnol 43:111–120, 2010) suggests that salinity may influence oxygen isotope fractionation in ostracods, with lower vital offsets for higher salinities. Such a relationship was also observed for the vital offsets determined by Chivas et al. (The ostracoda—applications in quaternary research. American Geophysical Union, Washington, DC, 2002). Yet, when results of all studies are compiled, the correlation between vital offsets and salinity is low while the correlation between vital offsets and host water Mg/Ca is higher, suggesting that ionic composition of water and/or relative abundance of major ions may also control oxygen isotope fractionation in ostracods. Lack of data on host water ionic composition for the different studies precludes more detailed examination at this stage. Further studies such as natural or laboratory cultures done under strictly controlled conditions are needed to better understand the potential influence of varying environmental conditions on oxygen isotope compositions of ostracod valves.  相似文献   

Holocene variability in climate and oceanic conditions in the winter rainfall zone of South Africa—inferred from a high resolution diatom record from Verlorenvlei     

Kelly L. Kirsten  Thomas Kasper  Hayley C. Cawthra  Paul Strobel  Lynne J. Quick  Michael E. Meadows  Torsten Haberzettl 《第四纪科学杂志》2020,35(4):572-581

We present a diatom record from a well-dated 15.25 m composite sedimentary core from Verlorenvlei, a shallow coastal lake on the west coast of South Africa. We show that fluctuations in the diatom record occur in response to changes in sea level, ocean–atmosphere interactions and latitudinal shifts in the wind belts. During the early to mid-Holocene, the system primarily responds to sea level changes. A marine community that favours high nutrients is evident, particularly during 9200–8000, 7420–7000 and 6200–5600 cal a bp , corroborating periods of Benguela upwelling linked to fluctuations in the southeast trade winds. Increases in bioproductivity (%TOC, C/N) and fresher-water diatoms are associated with wetter conditions over the region and the northward migration of the southern westerly wind belt, most notably between 8000 and 7500 cal a bp and over the last 700 years. The latter trends are concomitant with changes in the extent of Antarctic sea ice and availability of moisture in southern South America. During the late Holocene, as sea levels stabilised to modern levels, climate variability is more strongly evident. The body of evidence further reveals the sensitivity of the region to high-latitude atmospheric mechanisms, but also showcases the significance of the southeast trade winds.  相似文献   

A high‐resolution record of Holocene climate and vegetation dynamics from the southern Cape coast of South Africa: pollen and microcharcoal evidence from Eilandvlei          下载免费PDF全文

Lynne J. Quick  Brian M. Chase  Michael Wündsch  Kelly L. Kirsten  Manuel Chevalier  Roland Mäusbacher  Michael E. Meadows  Torsten Haberzettl 《第四纪科学杂志》2018,33(5):487-500

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Dietary niche partitioning in a piscivorous fish guild in response to stocking of an additional competitor - The role of diet specialisation     

Torsten Schulze  Hendrik Dörner  Uli BaadeFranz Hölker 《Limnologica》2012,42(1):56-64

Species belonging to the same ecological guild can coexist only if there are differences in their responses to limiting resources. Thus, competitor introductions may modify the niches of the resident competitors, but empirical studies are rare. The extent of niche modification might further depend on the species’ trophic specialisation along the specialists-to-generalists axis. In this study, we performed a semi-natural experiment by introducing a trophically specialised piscivorous fish (pikeperch) to the resident predator guild of a trophic generalist (perch) and a trophic specialist (pike) in a temperate freshwater lake. Individual diet data were used to calculate total niche hypervolume and inter- and intraspecific dietary niche overlap to evaluate strength of competitive interactions before and after pikeperch introduction. In both pike and perch, there was a moderate niche compression in response to pikeperch stocking. Furthermore, whereas perch diet hypervolume did not overlap at all with that of pikeperch, the intersection of niche space between the two trophic specialists was highly asymmetrical in favour of pike due to its less specialised diet composition in comparison with pikeperch. The intraspecific dietary niche overlap between perch size classes reflected an enhanced partitioning, whereas that of pike size classes was found almost unchanged in response to pikeperch stocking. These empirical results corroborate that competitive interactions and the degree of specialisation may strongly shape the success of introductions of top-predators in freshwater ecosystems. The most specialised species may persist only if the competitors belong rather to the generalists along the specialisation continuum.  相似文献   

Analysis of thunderstorm and lightning activity associated with sprites observed during the EuroSprite campaigns: Two case studies     

Serge Soula  Oscar van der Velde  Joan Montany  Torsten Neubert  Olivier Chanrion  Michal Ganot 《Atmospheric Research》2009,91(2-4):514-528

During the summers of 2003 to 2006 sprites were observed over thunderstorms in France by cameras on mountain tops in Southern France. The observations were part of a larger coordinated effort, the EuroSprite campaigns, with data collected simultaneously from other sources including the French radar network for precipitation structure, Meteosat with images of cloud top temperature and the Météorage network for detection of cloud-to-ground (CG) flash activity. In this paper two storms are analyzed, each producing 27 sprite events. Both storms were identified as Mesoscale Convective Systems (MCS) with a trailing stratiform configuration (ST) and reaching a maximum cloud area of ~ 120,000 km². Most of the sprites were produced while the stratiform area was clearly developed and during periods of substantial increase of rainfall in regions with radar reflectivity between 30 and 40 dBZ. The sprite-producing periods followed a maximum in the CG lightning activity and were characterized by a low CG flash rate with a high proportion of + CG flashes, typically around 50%. All sprites were associated with + CGs except one which was observed after a − CG as detected by the Météorage network. This − CG was estimated to have − 800 C km charge moment change. The peak current of sprite-producing + CG (SP + CG) flashes was twice the average value of + CGs and close to 60 kA with little variation between the periods of sprite activity. The SP + CG flashes were further characterized by short time intervals before a subsequent CG flash (median value < 0.5 s) and with clusters of several CG flashes which suggest that SP + CG flashes often are part of multi-CG flash processes. One case of a lightning process associated with a sprite consisted of 7 CG flashes.  相似文献   

Idealized Mesoscale Model Simulations of Open Cellular Convection Over the Sea     

Claire L. Vincent  Andrea N. Hahmann  Mark C. Kelly 《Boundary-Layer Meteorology》2012,142(1):103-121

The atmospheric conditions during an observed case of open cellular convection over the North Sea were simulated using the Weather Research and Forecasting (WRF) numerical model. Wind, temperature and water vapour mixing ratio profiles from the WRF simulation were used to initialize an idealized version of the model, which excluded the effects of topography, surface inhomogeneities and large-scale weather forcing. Cells with an average diameter of 17.4 km developed. Simulations both with and without a capping inversion were made, and the cell-scale kinetic energy budget was calculated for each case. By considering all sources of explicit diffusion in the model, the budgets were balanced. In comparison with previous work based on observational studies, the use of three-dimensional, gridded model data afforded the possibility of calculating all terms in the budgets, which showed that the important terms in the budgets were buoyancy, pressure balance and inter-scale transfer to subgrid scales. Cells were also composited to calculate the average cell-scale flow and each of the budget terms on two-dimensional cross-sections through the cells, parallel and perpendicular to the mean wind direction.  相似文献   

Quartz Reference Materials for Oxygen Isotope Analysis by SIMS          下载免费PDF全文

Susanne Seitz  Lukas P. Baumgartner  Anne‐Sophie Bouvier  Benita Putlitz  Torsten Vennemann 《Geostandards and Geoanalytical Research》2017,41(1):69-75

Two quartz samples of igneous origin, UNIL‐Q1 (Torres del Paine Intrusion, Chile) and BGI‐Q1 (Shandong province, China), were calibrated for their oxygen isotope composition for SIMS measurements. UNIL‐Q1 and BGI‐Q1 were evaluated for homogeneity using SIMS. Their reference δ¹⁸O values were determined by CO₂ laser fluorination. The average δ¹⁸O value found for UNIL‐Q1 is 9.8 ± 0.06‰ and that for BGI‐Q1 is 7.7 ± 0.11‰ (1s). The intermediate measurement precision of SIMS oxygen isotope measurements was 0.32–0.41‰ (2s; UNIL‐Q1) and 0.40–0.48‰ (2s; BGI‐Q1), respectively. While less homogeneous in its oxygen isotope composition, BGI‐Q1 is also suitable for SIMS trace element measurements.  相似文献