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The occurrence of corroded megacrysts and cumulates of olivine, clinopyroxene, orthopyroxene, plagioclase, ilmenite and apatite in near-saturated hawaiites from the mid-north coast of New South Wales point to the derivation of these hawaiites at elevated pressures. In an experimental study on one of these hawaiites under conditions ranging from 5–15 kb and 0–5% H2O, orthopyroxene was identified in only one run with 2% H2O at 1040° C and 6.5 kb. In this run it was associated with olivine, clinopyroxene and Fe-Ti oxide. The early appearance of plagioclase in the “dry” experimental runs and amphibole in runs with 5% H2O, indicates that the water content in the natural hawaiite was intermediate to these values. The near-duplication of the natural megacryst-cumulate assemblage suggests that the hawaiite host precipitated these phases at a depth of approximately 20–24 km, prior to rapid eruption to higher crustal levels.  相似文献   
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While finite-difference methods have been used extensively for many years to model wave propagation in elastic media, some of the more subtle effects observable in such models are very inadequately documented in the geophysical literature, especially in regard to their practical numerical consequences. In addition to the intended travelling waves, and the undesirable exponential instability revealed by the von Neumann test, typical second-order-time finite-difference equations also support drifting linear solutions, as can be verified, both theoretically and by numerical experiment. The necessity of these solutions, and their relationship to the incompleteness of the set of travelling-wave eigenfunctions of the finite-difference operator, can be exposed by a matrix-based analysis, and exact expressions for them can be obtained by using standard algebraic techniques. A further peculiarity of the finite-difference formulation is numerical anisotropy, which emerges in a grid of more than one spatial dimension, even when the modelled medium is intended to be isotropic. This anisotropy can be explained and quantified in terms of the exact eigenfunction solutions to the finite-difference equation, which, it is found, can be obtained in a simple, closed form, for a typical modern 3D staggered scheme.  相似文献   
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Clear evidence exists for a cordierite breakdown reaction to amphibole-kyanite-quartz in high-grade metamorphic rocks of the Arunta Complex, Australia. Using the natural minerals this reaction has been duplicated experimentally. It proceeds over a divariant band with a slope of 12±4 bars/°C, occurring between 8 and 10.4 kb at 750° C and between 9.5 and 11.3 kb at 850°C. The reaction is cut off at low temperature by the appearance of talc and at high temperature by the appearance of orthopyroxene. The maximum pressure stability of the amphibole-kyanite-quartz assemblage is about 20 kb. These data suggest that the natural rock was subjected to pressures of at least 8 kb at 750–850° C for high water fugacities. Other experimental data on the hydration of hypersthene and cordierite-hypersthene stability, point to a temperature below 820° C and an upper pressure limit of 9.5 kb at 750–820°C. Experiments at \(P_{{\text{H}}_{\text{2}} {\text{O}}}\) total indicate that the breakdown of cordierite to amphibole-kyanite-quartz is a hydration reaction, and occurred in the natural rock as a result of an increase of water fugacity at constant total pressure (8–9.5 kb) and temperature (750–820°C).  相似文献   
35.
We present an X-ray analysis of the radio-quiet cool-core galaxy group NGC 4325  ( z = 0.026)  based on Chandra and ROSAT observations. The Chandra data were analysed using xspec deprojection, 2D spectral mapping and forward-fitting with parametric models. Additionally, a Markov Chain Monte Carlo method was used to perform a joint Bayesian analysis of the Chandra and ROSAT data. The results of the various analysis methods are compared, particularly those obtained by forward-fitting and deprojection. The spectral mapping reveals the presence of cool gas displaced up to 10 kpc from the group centre. The Chandra X-ray surface brightness shows the group core to be highly disturbed, and indicates the presence of two small X-ray cavities within 15 kpc of the group core. The xspec deprojection analysis shows that the group has a particularly steep entropy profile, suggesting that an active galactic nucleus (AGN) outburst may be about to occur. With the evidence of prior AGN activity, but with no radio emission currently observed, we suggest that the group in a pre-outburst state, with the cavities and displaced gas providing evidence of a previous, weak AGN outburst.  相似文献   
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About 1.02 × 106 m3 of chlorinated municipal drinking water was injected into a confined aquifer, 94–137 m below Roseville, California, between December 2005 and April 2006. The water was stored in the aquifer for 438 days, and 2.64 × 106 m3 of water were extracted between July 2007 and February 2008. On the basis of Cl data, 35% of the injected water was recovered and 65% of the injected water and associated disinfection by-products (DBPs) remained in the aquifer at the end of extraction. About 46.3 kg of total trihalomethanes (TTHM) entered the aquifer with the injected water and 37.6 kg of TTHM were extracted. As much as 44 kg of TTHMs remained in the aquifer at the end of extraction because of incomplete recovery of injected water and formation of THMs within the aquifer by reactions with free-chlorine in the injected water. Well-bore velocity log data collected from the Aquifer Storage Recovery (ASR) well show as much as 60% of the injected water entered the aquifer through a 9 m thick, high-permeability layer within the confined aquifer near the top of the screened interval. Model simulations of ground-water flow near the ASR well indicate that (1) aquifer heterogeneity allowed injected water to move rapidly through the aquifer to nearby monitoring wells, (2) aquifer heterogeneity caused injected water to move further than expected assuming uniform aquifer properties, and (3) physical clogging of high-permeability layers is the probable cause for the observed change in the distribution of borehole flow. Aquifer heterogeneity also enhanced mixing of native anoxic ground water with oxic injected water, promoting removal of THMs primarily through sorption. A 3 to 4-fold reduction in TTHM concentrations was observed in the furthest monitoring well 427 m downgradient from the ASR well, and similar magnitude reductions were observed in depth-dependent water samples collected from the upper part of the screened interval in the ASR well near the end of the extraction phase. Haloacetic acids (HAAs) were completely sorbed or degraded within 10 months of injection.  相似文献   
39.
Mangakino, the oldest rhyolitic caldera centre delineated in the Taupo Volcanic Zone of New Zealand, generated two very large (super-sized) ignimbrite eruptions, the 1.21 ± 0.04 Ma >500 km3 Ongatiti and ~1.0 Ma ~1,200 km3 Kidnappers events, the latter of which was followed after a short period of erosion by the ~200 km3 Rocky Hill eruption. We present U/Pb ages and trace-element analyses on zircons from pumice clasts from these three eruptions by Secondary Ion Mass Spectrometry (SIMS) using SHRIMP-RG instruments to illustrate the evolution of the respective magmatic systems. U–Pb age spectra from the Ongatiti imply growth of the magmatic system over ~250 kyr, with a peak of crystallisation around 1.32 Ma, ~100 kyr prior to eruption. The zircons are inferred to have then remained stable in a mush with little crystallisation and/or dissolution before later rejuvenation of the system at the lead-in to eruption. The paired Kidnappers and Rocky Hill eruptions have U–Pb zircon ages and geochemical signatures that suggest they were products of a common system grown over ~200 kyr. The Kidnappers and Rocky Hill samples show similar weakly bimodal age spectra, with peaks at 1.1 and 1.0 Ma, suggesting that an inherited antecrystic population was augmented by crystals grown at ages within uncertainty of the eruption age. In the Kidnappers, this younger age peak is dominantly seen in needle-shaped low U grains with aspect ratios of up to 18. In all three deposits, zircon cores show larger ranges and higher absolute concentrations of trace elements than zircon rims, consistent with zircon crystallisation from evolving melts undergoing crystal fractionation involving plagioclase and amphibole. Abundances and ratios of many trace elements frequently show variations between different sectors within single grains, even where there is no visible sector zoning in cathodoluminescence (CL) imaging. Substitution mechanisms, as reflected in the molar (Sc + Y + REE3+)/P ratio, differ in the same growth zone between the sides (along a-axis and b-axis: values approaching 1.0) and tips (c-axis: values between 1.5 and 5.0) of single crystals. These observations have implications for the use of zircons for tracking magmatic processes, particularly in techniques where CL zonation within crystals is not assessed and small analytical spot sizes cannot be achieved. These observations also limit applicability of the widely used Ti-in-zircon thermometer. The age spectra for the Ongatiti and Kidnappers/Rocky Hill samples indicate that both magmatic systems were newly built in the time-breaks after respective previous large eruptions from Mangakino. Trace element variations defining three-component mixing suggest that zircons, sourced from multiple melts, contributed to the population in each system.  相似文献   
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