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排序方式: 共有362条查询结果,搜索用时 265 毫秒
31.
Recent lifetime measurements on excited electronic states of neutral silicon (Beckeret al., Phys. Lett. In press, 1980) lead to a reassessment of widely used experimental transition probabilities Garz, Astron. Astrophys., 26, 471–477, 1973 of Si I lines. This translates into a 25% downward revision of the Si abundance determined from the solar spectrum.A solar atomic ratio, Si/Ca = 15.5 is inferred. This value coincides with that found in carbonaceous chondrites, but contrasts with ordinary and enstatite chondrites. 相似文献
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Katharina Marquardt Elena Petrishcheva Rainer Abart Emmanuel Gardés Richard Wirth Ralf Dohmen Hans-Werner Becker Wilhelm Heinrich 《Physics and Chemistry of Minerals》2010,37(10):751-760
In this study, we address volume diffusion of ytterbium in yttrium aluminum garnet (YAG) using thin-film single crystal diffusion
couples. We employ analytical transmission electron microscopy (ATEM) as a tool for combined microstructural and microchemical
analysis and compare the results to Rutherford backscattering (RBS) analysis. Given the high spatial resolution of the method,
we focus on microstructural changes of the thin-film diffusant source during the diffusion anneal. We evaluate the potential
influence of the associated changes in its transport properties on the evolution of concentration profiles in the single crystal
substrate. This approach allows us to test the reliability of determination of volume diffusion coefficients from thin-film
diffusion experiments. We found that for the chosen experimental setting, the influence of thin-film re-crystallization is
small when compared with the experimental uncertainty and good estimates for the volume diffusion coefficients of Yb in YAG
can be obtained using standard assumptions. Both Yb-concentration profiles analyzed with ATEM and with RBS give similar results.
At 1,450°C and 1 bar, we infer log D
Yb (m2/s) values of −19.37 ± 0.07 (TEM) and −19.84 ± 0.02 (RBS). Although the change in thin-film transport properties associated
with successive crystallization during the diffusion anneal does not play a major role for our experimental setup, this effect
cannot generally be ignored. 相似文献
34.
35.
Mass Fractions of S,Cu, Se,Mo, Ag,Cd, In,Te, Ba,Sm, W,Tl and Bi in Geological Reference Materials and Selected Carbonaceous Chondrites Determined by Isotope Dilution ICP‐MS 下载免费PDF全文
Zaicong Wang Harry Becker Frank Wombacher 《Geostandards and Geoanalytical Research》2015,39(2):185-208
Mass fractions of S, Cu, Se, Mo, Ag, Cd, In, Te, Ba, Sm, W and Tl were determined by isotope dilution sector field ICP‐MS in the same sample aliquot of reference materials using HF‐HNO3 digestion in PFA beakers in pressure bombs and glassy carbon vessels in a high‐pressure asher (HPA‐S) for comparison. Additionally, Bi was determined by internal standardisation relative to Tl. Because isobaric and oxide interferences pose problems for many of these elements, efficient chromatographic separation methods in combination with an Aridus desolvator were employed to minimise interference effects. Repeated digestion and measurement of geological reference materials (BHVO‐1, BHVO‐2, SCo‐1, MAG‐1, MRG‐1 and UB‐N) gave results with < 5% relative intermediate precision (1s) for most elements, except Bi. Replicates of NIST SRM 612 glass digested on a hot plate were analysed by the same methods, and the results agree with reference values mostly within 2% relative deviation. Data for the carbonaceous chondrites Allende, Murchison, Orgueil and Ivuna are also reported. Digestion in a HPA‐S was as efficient as in pressure bombs, but some elements displayed higher blank levels following HPA‐S treatment. Pressure bomb digestion yielded precise data for volatile S, Se and Te, but may result in high blanks for W. 相似文献
36.
Austin H. Becker Michele Acciaro Regina Asariotis Edgard Cabrera Laurent Cretegny Philippe Crist Miguel Esteban Andrew Mather Steve Messner Susumu Naruse Adolf K. Y. Ng Stefan Rahmstorf Michael Savonis Dong-Wook Song Vladimir Stenek Adonis F. Velegrakis 《Climatic change》2013,120(4):683-695
With 80 % of world trade carried by sea, seaports provide crucial linkages in global supply-chains and are essential for the ability of all countries to access global markets. Seaports are likely to be affected directly and indirectly by climatic changes, with broader implications for international trade and development. Due to their coastal location, seaports are particularly vulnerable to extreme weather events associated with increasing sea levels and tropical storm activity, as illustrated by hurricane “Sandy”. In view of their strategic role as part of the globalized trading system, adapting ports in different parts of the world to the impacts of climate change is of considerable importance. Reflecting the views of a diverse group of stakeholders with expertise in climate science, engineering, economics, policy, and port management, this essay highlights the climate change challenge for ports and suggests a way forward through the adoption of some initial measures. These include both “soft” and “hard” adaptations that may be spearheaded by individual port entities, but will require collaboration and support from a broad range of public and private sector stakeholders and from society at large. In particular, the essay highlights a need to shift to more holistic planning, investment and operation. 相似文献
37.
Tobias Lung Alessandro Dosio William Becker Carlo Lavalle Laurens M. Bouwer 《Climatic change》2013,120(1-2):211-227
Despite an increasing understanding of potential climate change impacts in Europe, the associated uncertainties remain a key challenge. In many impact studies, the assessment of uncertainties is underemphasised, or is not performed quantitatively. A key source of uncertainty is the variability of climate change projections across different regional climate models (RCMs) forced by different global circulation models (GCMs). This study builds upon an indicator-based NUTS-2 level assessment that quantified potential changes for three climate-related hazards: heat stress, river flood risk, and forest fire risk, based on five GCM/RCM combinations, and non-climatic factors. First, a sensitivity analysis is performed to determine the fractional contribution of each single input factor to the spatial variance of the hazard indicators, followed by an evaluation of uncertainties in terms of spread in hazard indicator values due to inter-model climate variability, with respect to (changes in) impacts for the period 2041–70. The results show that different GCM/RCM combinations lead to substantially varying impact indicators across all three hazards. Furthermore, a strong influence of inter-model variability on the spatial patterns of uncertainties is revealed. For instance, for river flood risk, uncertainties appear to be particularly high in the Mediterranean, whereas model agreement is higher for central Europe. The findings allow for a hazard-specific identification of areas with low vs. high model agreement (and thus confidence of projected impacts) within Europe, which is of key importance for decision makers when prioritising adaptation options. 相似文献
38.
Michael De Becker Gregor Rauw Jean-Pierre Swings 《Astrophysics and Space Science》2005,297(1-4):291-298
We present the results of an intensive spectroscopic campaign in the optical waveband revealing that Cyg OB2 #8A is an O6+O5.5
binary system with a period of about 21.9 days. Cyg OB2 #8A is a bright X-ray source, as well as a non-thermal radio emitter.
We discuss the binarity of this star in the framework of a campaign devoted to the study of non-thermal emitters, from the
radio waveband to γ-rays. In this context, we attribute the non-thermal radio emission from this star to a population of relativistic
electrons, accelerated by the shock of the wind-wind collision. These relativistic electrons could also be responsible for
a putative γ-ray emission through inverse Compton scattering of photospheric UV photons, thus contributing to the yet unidentified
EGRET source 3EG J2033+4118.
Based partly on data Obtained at the Observatoire de Haute-Provence, France. 相似文献
39.
40.
The fragmentation of SO2 following dissociative electron impact excitation has been studied under single collision conditions for incident electron energies up to 500 eV. The emission spectrum in the far v.u.v. spectral range (450–1100Å) shows many features arising from excited neutral oxygen and ionized oxygen and sulphur fragments. Absolute emission cross sections have been measured for the most intense lines and the maximum values were found to range from 1–12 × 10?19 cm2 with an uncertainty of approx. ± 35%. Dissociation mechanisms are discussed and in some cases the dissociation path could be uniquely identified. The striking differences between the v.u.v. emission spectrum produced by single step dissociation of SO2 and the spectra emitted by the plasma torus around Jupiter are discussed. 相似文献