Eddy covariance measurements of carbon dioxide,latent and sensible energy fluxes above a meadow on a mountain slope     

Albin Hammerle  Alois Haslwanter  Michael Schmitt  Michael Bahn  Ulrike Tappeiner  Alexander Cernusca  Georg Wohlfahrt 《Boundary-Layer Meteorology》2007,122(2):397-416

Carbon dioxide, latent and sensible heat fluxes were measured by means of the eddy covariance method above a mountain meadow situated on a steep slope in the Stubai Valley in Austria, based on the hypothesis that, due to the low canopy height, measurements can be made in the shallow equilibrium layer where the wind field exhibits characteristics akin to level terrain. In order to test the validity of this hypothesis and to identify effects of complex terrain in the turbulence measurements, data were subjected to a rigorous testing procedure using a series of quality control measures established for surface-layer flows. The resulting high quality dataset comprised 36% of the original observations, the substantial reduction being mainly due to a change in surface roughness and associated fetch limitations in the wind sector dominating during nighttime and transition periods. The validity of the high quality dataset was further assessed by two independent tests: (i) a comparison with the net ecosystem carbon dioxide exchange measured by means of ecosystem chambers, and (ii) the ability of the eddy covariance measurements to close the energy balance. The net ecosystem CO₂ exchange measured by the eddy covariance method agreed reasonably well with ecosystem chamber measurements. The assessment of the energy balance closure showed that there was no significant difference in the correspondence between the meadow on the slope and another one situated on flat ground at the bottom of the Stubai Valley, available energy being underestimated by 28% and 29%, respectively. We thus conclude that, appropriate quality control provided, the eddy covariance measurements made above a mountain meadow on a steep slope are of similar quality as compared to flat terrain.  相似文献   

Driving forces of mid-Holocene vegetation shifts on the upper Tibetan Plateau,with emphasis on changes in atmospheric CO2 concentrations     

Ulrike Herzschuh  Jian Ni  H. John B. Birks  Jürgen Böhner 《Quaternary Science Reviews》2011,30(15-16):1907-1917

Numerous pollen records across the upper Tibetan Plateau indicate that in the early part of the mid-Holocene, Kobresia-rich high-alpine meadows invaded areas formerly dominated by alpine steppe vegetation rich in Artemisia. We examine climate, land-use, and CO₂ concentration changes as potential drivers for this marked vegetation change. The climatic implications of these vegetational shifts are explored by applying a newly developed pollen-based moisture-balance transfer-function to fossil pollen spectra from Koucha Lake on the north-eastern Tibetan Plateau (34.0°N; 97.2°E; 4540 m a.s.l.) and Xuguo Lake on the central Tibetan Plateau (31.97°N; 90.3°E; 4595 m a.s.l.), both located in the meadow-steppe transition zone. Reconstructed moisture-balances were markedly reduced (by ～150–180 mm) during the early mid-Holocene compared to the late-Holocene. These findings contradict most other records from the Indian monsoonal realm and also most non-pollen records from the Tibetan Plateau that indicate a rather wet early- and mid-Holocene. The extent and timing of anthropogenic land-use involving grazing by large herbivores on the upper Tibetan Plateau and its possible impacts on high-alpine vegetation are still mostly unknown due to the lack of relevant archaeological evidence. Arguments against a mainly anthropogenic origin of Kobresia high-alpine meadows are the discovery of the widespread expansion of obviously ‘natural’ Kobresia meadows on the south-eastern Tibetan Plateau during the Lateglacial period indicating the natural origin of this vegetation type and the lack of any concurrence between modern human-driven vegetation shifts and the mid-Holocene compositional changes. Vegetation types are known to respond to atmospheric CO₂ concentration changes, at least on glacial–interglacial scales. This assumption is confirmed by our sensitivity study where we model Tibetan vegetation at different CO₂ concentrations of 375 (present-day), 260 (early Holocene), and 650 ppm (future scenario) using the BIOME4 global vegetation model. Previous experimental studies confirm that vegetation growing on dry and high sites is particularly sensitive to CO₂ changes. Here we propose that the replacement of drought-resistant alpine steppes (that are well adapted to low CO₂ concentrations) by mesic Kobresia meadows can, at least, be partly interpreted as a response to the increase of CO₂ concentration since 7000 years ago due to fertilization and water-saving effects. Our hypothesis is corroborated by former CO₂ fertilization experiments performed on various dry grasslands and by the strong recent expansion of high-alpine meadows documented by remote sensing studies in response to recent CO₂ increases.  相似文献   

Geostandards and Geoanalytical Research Bibliographic Review 2009     

Klaus P. Jochum  Xiaohong Wang  Regina Mertz-Kraus  Uwe Nohl  Steffen Schmidt  Beate Schwager  Brigitte Stoll  Qichao Yang  Ulrike Weis 《Geostandards and Geoanalytical Research》2010,34(4):407-410

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A combined paleolimnological/genetic analysis of diatoms reveals divergent evolutionary lineages of Staurosira and Staurosirella (Bacillariophyta) in Siberian lake sediments along a latitudinal transect     

Kathleen R. Stoof-Leichsenring  Nadine Bernhardt  Luidmila A. Pestryakova  Laura S. Epp  Ulrike Herzschuh  Ralph Tiedemann 《Journal of Paleolimnology》2014,52(1-2):77-93

Diatom diversity in lakes of northwest Yakutia (Siberia) was investigated by microscopic and genetic analysis of surface and cored lake sediments, to evaluate the use of sedimentary DNA for paleolimnological diatom studies and to identify obscure genetic diversity that cannot be detected by microscopic methods. Two short (76 and 73 bp) and one longer (577 bp) fragments of the ribulose 1,5-bisphosphate carboxylase/oxygenase (rbcL) gene, encoding the large subunit of the rbcL, were used as genetic markers. Diverse morphological assemblages of diatoms, dominated by small benthic fragilarioid taxa, were retrieved from the sediments of each lake. These minute fragilarioid taxa were examined by scanning electron microscopy, revealing diverse morphotypes in Staurosira and Staurosirella from the different lakes. Genetic analyses indicated a dominance of haplotypes that were assigned to fragilarioid taxa and less genetic diversity in other diatom taxa. The long rbcL_577 amplicon identified considerable diversification among haplotypes clustering within the Staurosira/Staurosirella genera, revealing 19 different haplotypes whose spatial distribution appears to be primarily related to the latitude of the lakes, which corresponds to a vegetation and climate gradient. Our rbcL markers are valuable tools for tracking differences between diatom lineages that are not visible in their morphologies. These markers revealed putatively high genetic diversity within the Staurosira/Staurosirella species complex, at a finer scale than is possible to resolve by microscopic determination. The rbcL markers may provide additional reliable information on the diversity of barely distinguishable minute benthic fragilarioids. Environmental sequencing may thus allow the tracking of spatial and temporal diversification in Siberian lakes, especially in the context of diatom responses to recent environmental changes, which remains a matter of controversy.  相似文献   

Inter-laboratory comparison of oxygen isotope compositions from biogenic silica     

Bernhard Chapligin  Melanie J. Leng  Anne Alexandre  Akira Ijiri  Aldo Shemesh  Ulrike Herzschuh  Hanno Meyer  Yusuke Okazaki  Zachary D. Sharp  Corinne Sonzogni  Florence Sylvestre  Ruth Yam 《Geochimica et cosmochimica acta》2011,75(22):7242-7256

Several techniques have been introduced in the last decades for the dehydration and release of O₂ from biogenic silica (opal-A) for oxygen-isotope analysis. However, only one silica standard is universally available: a quartz standard (NBS28) distributed by the IAEA, Vienna. Hence, there is a need for biogenic silica working standards. This paper compares the existing methods of oxygen-isotope analyses of opal-A and aims to characterize additional possible working standards to calibrate the δ¹⁸O values of biogenic silica. For this purpose, an inter-laboratory comparison was organized. Six potential working standard materials were analysed repeatedly against NBS28 by eight participating laboratories using their specific analytical methods. The materials cover a wide range of δ¹⁸O values (+23 to +43‰) and include diatoms (marine, lacustrine), phytoliths and synthetically-produced hydrous silica. To characterize the proposed standards, chemical analyses and imaging by scanning electron microscopy (SEM) were also performed. Despite procedural differences at each laboratory, all methods are in reasonable agreement with a standard deviation (SD) for δ¹⁸O values between 0.3‰ and 0.9‰ (1σ). Based on the results, we propose four additional biogenic silica working standards (PS1772-8: 42.8‰; BFC: 29.0‰; MSG60: 37.0‰; G95-25-CL leaves: 36.6‰) for δ¹⁸O analyses, available on request through the relevant laboratories.  相似文献   

GSD‐1G and MPI‐DING Reference Glasses for In Situ and Bulk Isotopic Determination     

Klaus Peter Jochum  Steven A. Wilson  Wafa Abouchami  Marghaleray Amini  Jérome Chmeleff  Anton Eisenhauer  Ernst Hegner  Linda M. Iaccheri  Bruno Kieffer  Joachim Krause  William F. McDonough  Regina Mertz‐Kraus  Ingrid Raczek  Roberta L. Rudnick  Denis Scholz  Grit Steinhoefel  Brigitte Stoll  Andreas Stracke  Sonia Tonarini  Dominique Weis  Ulrike Weis  Jon D. Woodhead 《Geostandards and Geoanalytical Research》2011,35(2):193-226

This paper contains the results of an extensive isotopic study of United States Geological Survey GSD‐1G and MPI‐DING reference glasses. Thirteen different laboratories were involved using high‐precision bulk (TIMS, MC‐ICP‐MS) and microanalytical (LA‐MC‐ICP‐MS, LA‐ICP‐MS) techniques. Detailed studies were performed to demonstrate the large‐scale and small‐scale homogeneity of the reference glasses. Together with previously published isotopic data from ten other laboratories, preliminary reference and information values as well as their uncertainties at the 95% confidence level were determined for H, O, Li, B, Si, Ca, Sr, Nd, Hf, Pb, Th and U isotopes using the recommendations of the International Association of Geoanalysts for certification of reference materials. Our results indicate that GSD‐1G and the MPI‐DING glasses are suitable reference materials for microanalytical and bulk analytical purposes.  相似文献   

Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines     

Klaus Peter Jochum  Ulrike Weis  Brigitte Stoll  Dmitry Kuzmin  Qichao Yang  Ingrid Raczek  Dorrit E. Jacob  Andreas Stracke  Karin Birbaum  Daniel A. Frick  Detlef Günther  Jacinta Enzweiler 《Geostandards and Geoanalytical Research》2011,35(4):397-429

We present new reference values for the NIST SRM 610–617 glasses following ISO guidelines and the International Association of Geoanalysts’ protocol. Uncertainties at the 95% confidence level (CL) have been determined for bulk‐ and micro‐analytical purposes. In contrast to former compilation procedures, this approach delivers data that consider present‐day requirements of data quality. New analytical data and the nearly complete data set of the GeoReM database were used for this study. Data quality was checked by the application of the Horwitz function and by a careful investigation of analytical procedures. We have determined quantitatively possible element inhomogeneities using different test portion masses of 1, 0.1 and 0.02 μg. Although avoiding the rim region of the glass wafers, we found moderate inhomogeneities of several chalcophile/siderophile elements and gross inhomogeneities of Ni, Se, Pd and Pt at small test portion masses. The extent of inhomogeneity was included in the determination of uncertainties. While the new reference values agree with the NIST certified values with the one exception of Mn in SRM 610, they typically differ by as much as 10% from the Pearce et al. (1997) values in current use. In a few cases (P, S, Cl, Ta, Re) the discrepancies are even higher.  相似文献   

Listric versus planar normal fault geometry: an example from the Eisenstadt-Sopron Basin (E Austria)   总被引：1，自引：0，他引：1  

Darko Spahić  Ulrike Exner  Michael Behm  Bernhard Grasemann  Alexander Haring  Herbert Pretsch 《International Journal of Earth Sciences》2011,100(7):1685-1695

In a gravel pit at the eastern margin of the Eisenstadt-Sopron Basin, a satellite of Vienna Basin (Austria), Neogene sediments are exposed in the hanging wall of a major normal fault. The anticlinal structure and associated conjugated secondary normal faults were previously interpreted as a rollover anticline above a listric normal fault. The spatial orientation and distribution of sedimentary horizons and crosscutting faults were mapped in detail on a laser scan of the outcrop wall. Subsequently, in order to assess the 3D distribution and geometry of this fault system, a series of parallel ground penetrating radar (GPR) profiles were recorded behind the outcrop wall. Both outcrop and GPR data were compiled in a 3D structural model, providing the basis for a kinematic reconstruction of the fault plane using balanced cross-section techniques. However, the kinematic reconstruction results in a geologically meaningless normal fault cutting down- and up-section. Additionally, no evidence for a weak layer serving as ductile detachment horizon (i.e. salt or clay horizon) can be identified in stratigraphic profiles. Instead, the observed deflection of stratigraphic horizons may be caused by a displacement gradient along a planar master fault, with a maximum displacement in the fault centre, decreasing towards the fault tips. Accordingly, the observed deflection of markers in the hanging wall—and in a nearby location in the footwall of the normal fault—is interpreted as large-scale fault drag along a planar fault that records a displacement gradient, instead of a rollover anticline related to a listric fault.  相似文献   

Spatial variability of Holocene changes in the annual precipitation pattern: a model-data synthesis for the Asian monsoon region     

A. Dallmeyer  M. Claussen  Y. Wang  U. Herzschuh 《Climate Dynamics》2013,40(11-12):2919-2936

This study provides a detailed analysis of the mid-Holocene to present-day precipitation change in the Asian monsoon region. We compare for the first time results of high resolution climate model simulations with a standardised set of mid-Holocene moisture reconstructions. Changes in the simulated summer monsoon characteristics (onset, withdrawal, length and associated rainfall) and the mechanisms causing the Holocene precipitation changes are investigated. According to the model, most parts of the Indian subcontinent received more precipitation (up to 5 mm/day) at mid-Holocene than at present-day. This is related to a stronger Indian summer monsoon accompanied by an intensified vertically integrated moisture flux convergence. The East Asian monsoon region exhibits local inhomogeneities in the simulated annual precipitation signal. The sign of this signal depends on the balance of decreased pre-monsoon and increased monsoon precipitation at mid-Holocene compared to present-day. Hence, rainfall changes in the East Asian monsoon domain are not solely associated with modifications in the summer monsoon circulation but also depend on changes in the mid-latitudinal westerly wind system that dominates the circulation during the pre-monsoon season. The proxy-based climate reconstructions confirm the regional dissimilarities in the annual precipitation signal and agree well with the model results. Our results highlight the importance of including the pre-monsoon season in climate studies of the Asian monsoon system and point out the complex response of this system to the Holocene insolation forcing. The comparison with a coarse climate model simulation reveals that this complex response can only be resolved in high resolution simulations.  相似文献   

Single-crystal structure and Raman spectroscopy of synthetic titanite analog CaAlSiO<Subscript>4</Subscript>F     

Hannes Krüger  Daniel M. Többens  Peter Tropper  Udo Haefeker  Volker Kahlenberg  Martin R. Fuchs  Vincent Olieric  Ulrike Troitzsch 《Mineralogy and Petrology》2015,109(5):631-641

Synthetic CaAlSiO₄F, the Al-F analog of titanite, has been investigated using single-crystal synchrotron diffraction experiments at Beamline X06DA (Swiss Light Source, Paul Scherrer Institute, Villigen, Switzerland) and Raman spectroscopy. The presented structural model with 40 parameters was refined against 506 unique reflections to a final R _{o b s} of 0.026 (space group A2/a, a = 6.9120(11), b = 8.5010(10), c = 6.435(2) Å, β = 114.670(11)°, and Z = 4) and exhibits less distorted coordination polyhedra than earlier models from powder data. Vibrational spectra were calculated in harmonic approximation at the Γ point from fully relaxed energy optimisations of the crystal structure, using 3D-periodic density functional theory with Gaussian basis sets and the software CRYSTAL06. The lattice parameters of the fully relaxed structure were in good agreement with the experimental values, with the calculated values 0.8 ± 0.4 % too large; the monoclinic angle was calculated 0.4° too large. The agreement of the calculated Raman frequencies with the observed ones was very good, with standard deviation ±3 cm^?1 and maximum deviations of ±7 cm^?1. Furthermore, a detailed discussion of the atomic displacements associated with each Raman mode is given.  相似文献