Lacustrine sediments and lichen transplants: two contrasting and complimentary environmental archives of natural and anthropogenic lead in the South Urals, Russia     

Baruch Spiro  Valery Udachin  Ben J. Williamson  O. William Purvis  Svetlana G. Tessalina  Dominik J. Weiss 《Aquatic Sciences - Research Across Boundaries》2013,75(2):185-198

Lead (Pb) concentrations and isotope ratios of two different geochemical archives are compared; lake sediment cores and lichens (Hypogymnia physodes, naturally growing and transplanted) from a ca. 80 km-long transect centred on the Cu smelter and former mining town of Karabash, Ural Mountains, Russia. Lead concentrations in sediment cores from 10 lakes were generally low near their base and show an abrupt increase in their upper portions interpreted to coincide with the onset of large-scale smelting operations in 1910. Lead isotope ratios derived from ²⁰⁴Pb, ²⁰⁶Pb, ²⁰⁷Pb, ²⁰⁸Pb of the bottom layers differed significantly from those of the top. The top sediments have isotope ratios that show distinct end members, one of which was the stack dust from the Karabash smelter, which is similar to the Pb derived from ores from Sibay, a major mine in the Urals. The composition of the bottom sediment layers generally fall slightly off a mixing line between the top sediments and average Earth’s upper crust. Lichens transplanted from a reference site, as well as naturally growing lichens, sampled from southwest of the smelter have isotope ratios similar to those of the stack dust. Lichens to the northeast contained Pb from the smelter, but are increasingly influenced by other sources probably leaded petrol and local soils, and a signature derived from a source enriched in ²⁰⁷Pb. Vegetables collected from local kitchen gardens contained Pb from an additional atmospheric source, possibly coal. Our work confirms that: (1) Pb isotopes in lake sediments provide a long-term record of inputs and allows the characterisation of natural and anthropogenic sources; (2) Pb isotopes in lichens provide a short-term record of local and long-range atmospheric deposition at high spatial resolution and short time scales as they replace their Pb content within a few months; (3) determination of all four stable Pb isotopes is necessary for the identification of the sources of Pb and is extremely sensitive for discerning minor source signatures, even in an area with a dominant source such as a smelter. Particularly significant for the Karabash area is that ore-smelter-derived airborne Pb is a major component in the lake sediments and lichens but its contribution reaches insignificant levels ca. 40 km from the smelter.  相似文献   

Motion of the fast exoplanets     

Valery A. Kotov 《Astrophysics and Space Science》2018,363(3):55

It is shown that a number of superfast, with periods \(< 2\) d, exoplanets revolve around parent stars with periods, near-commensurate with \(P_{E}\) and/or \(2 P_{E} / \pi\), where the exoplanet resonance timescale \(P_{E}=9603(85)\) s agrees fairly well with the period \(P_{0}= 9600.606(12)\) s of the so-called “cosmic oscillation” (the probability that the two timescales would coincide by chance is near \(3 \times10^{-4}\); the \(P_{0}\) period was discovered first in the Sun, and later on—in other objects of Cosmos). True nature of the exoplanet \(P_{0}\) resonance is unknown.  相似文献   

Formation of Libyan Desert Glass: Numerical simulations of melting of silica due to radiation from near‐surface airbursts     

Vladimir Svetsov  Valery Shuvalov  Igor Kosarev 《Meteoritics & planetary science》2020,55(4):895-910

Libyan Desert Glass contains meteoritic material and, therefore, its origin is most likely associated with an impact event. However, the impact crater has not been found. We performed numerical simulations of impacts of stony and cometary bodies in order to confirm the version that this glass was formed from silica heated by radiation from aerial bursts near the ground. Asteroids were treated as strengthless bodies from dunite with a density of 3.3 g cm^?3, and comets as icy bodies with a density of 1 g cm^?3. The simulations based on hydrodynamic equations included the equations of radiation transfer. Melting and vaporization of a silica target under action of radiation incident on a planar surface were modeled using a one‐dimensional hydrodynamic equation of energy and equations of radiation transfer in two‐flux approximation. We selected those variants of simulations in which a crater is not formed, a fireball touches the earth surface, and the area of a molten target corresponds to the area of the Libyan Desert Glass strewn field. Appropriate options include the impact of an asteroid with a diameter of 300 m, an entry speed of 35 km s^?1, and an entry angle of 8°, and cometary bodies with diameters from 150 to 300 m, speeds of 50–70 km s^?1, and entry angles from 15° to 45°. Impact options with crater formation are also discussed. The maximum depth of molten silica at ground zero reaches 10 cm with the cometary impacts and 3–4 cm with the asteroidal impact. Melting occurs during a period of time from 50 to 400 s.  相似文献   

Thermal radiation from impact plumes     

Vladimir Svetsov  Valery Shuvalov 《Meteoritics & planetary science》2019,54(1):126-141

Plumes produced by the impacts of asteroids and comets consist of rock vapor and heated air. They emit visible light, ultraviolet, and infrared radiation, which can greatly affect the environment. We have carried out numerical simulations of the impacts of stony and cometary bodies with a diameter of 0.3, 1, and 3 km, which enter the atmosphere at various angles, using a hydrodynamic model supplemented by radiation transfer. We assumed that the cosmic object has no strength, and deforms, fragments, and vaporizes in the atmosphere. After the impact on the ground, the formation of craters and plumes was simulated, taking the internal friction of destroyed rocks and the trail formed in the atmosphere into account. The equation of radiative transfer, added to the equations of gas dynamics, was used in the approximation of radiative heat conduction or, if the Rosseland optical depth of a radiating volume of gas and vapor was less than unity, in the volume‐emission approximation. We used temperature and density distributions obtained in these simulations to calculate radiation fluxes on the Earth's surface by integrating the equation of radiative transfer along rays passing through a luminous region. We used tables of the equation of state of dunite and quartz (for stony impactors and a target) and air, as well as tables of absorption coefficients of air, vapor of ordinary chondrite, and vapor of cometary material. We have calculated the radiation impulse on the ground and the impact radiation efficiency (a ratio of thermal radiation energy incident on the ground to the kinetic energy of a body), which ranges from ~0.5% to ~9%, depending on the impactor size and the angle of entry into the atmosphere. Direct thermal radiation from fireballs and impact plumes, poses a great danger to people, animals, plants, and economic objects. After the impacts of asteroids at a speed of 20 km s^?1 at an angle of 45°, a fire can occur at a distance of 250 km if the asteroid has a diameter of 0.3 km, and at a distance of 2000 km if the diameter is 3 km.  相似文献   

Geographical extremes in the glacial history of northern Eurasia: post-QUEEN considerations     

Valery Astakhov 《Polar research》2008,27(2):280-288

This paper summarizes the principal results produced by the European Science Foundation's programme, Quaternary Environment of the Eurasian North (QUEEN). These results concern the distribution of late Quaternary glaciers of different ages across northern Eurasia. The pattern of glaciation is compared with the west–east climatic gradient of the continent. Of particular significance is the coincidence of the Late Weichselian ice margin with the modern 30°C difference between the July and January mean air temperatures. The difference between west and east in the annual amplitude of air temperature did not decrease during the Pleniglacial. The asymmetry of the glacial history suggests a progressive aridification of the Eurasian North, with the result that by marine isotope stage 2 significant ice volumes could only accumulate along the Atlantic seaboard. The different climatic signals of thermochrons and cryochrons of the extreme west and east of the continent are discussed. The growth of continentality eastwards restrains the applicability of pollen proxies for climatic reconstructions.  相似文献   

Comment on “A mechanistic model for interpretation of hydrogen and oxygen isotope ratios in tree-ring cellulose,” by J. S. Roden, G. Lin, and J. R. Ehleringer (2000) Geochim. Cosmochim. Acta, 64, 21-35     

Valery J Terwilliger∗ 《Geochimica et cosmochimica acta》2002,66(4):729-731

  相似文献   

Geodetic observations of ice flow velocities over the southern part of subglacial Lake Vostok, Antarctica, and their glaciological implications   总被引：1，自引：0，他引：1  

Jens Wendt  Reinhard Dietrich  Mathias Fritsche  Anja Wendt  Alexander Yuskevich  rey Kokhanov  Anton Senatorov  Valery Lukin  Kazuo Shibuya  Koichiro Doi 《Geophysical Journal International》2006,166(3):991-998

In the austral summer seasons 2001/02 and 2002/03, Global Positioning System (GPS) data were collected in the vicinity of Vostok Station to determine ice flow velocities over Lake Vostok. Ten GPS sites are located within a radius of 30 km around Vostok Station on floating ice as well as on grounded ice to the east and to the west of the lake. Additionally, a local deformation network around the ice core drilling site 5G-1 was installed.
The derived ice flow velocity for Vostok Station is  2.00 m a⁻¹± 0.01 m a⁻¹  . Along the flowline of Vostok Station an extension rate of about 10⁻⁵ a⁻¹ (equivalent to 1 cm km⁻¹ a⁻¹) was determined. This significant velocity gradient results in a new estimate of 28 700 years for the transit time of an ice particle along the Vostok flowline from the bedrock ridge in the southwest of the lake to the eastern shoreline. With these lower velocities compared to earlier studies and, hence, larger transit times the basal accretion rate is estimated to be 4 mm a⁻¹ along a portion of the Vostok flowline. An assessment of the local accretion rate at Vostok Station using the observed geodetic quantities yields an accretion rate in the same order of magnitude. Furthermore, the comparison of our geodetic observations with results inferred from ice-penetrating radar data indicates that the ice flow may not have changed significantly for several thousand years.  相似文献   

Gas Chromatographic Determination of Extractable Compounds Composition and Emission Rate of Volatile Terpenes from Larch Needle Litter     

Valery?IsidorovEmail author  Vera?Vinogorova  Krzysztof?Rafa?owski 《Journal of Atmospheric Chemistry》2005,50(3):263-278

A combination of solid-phase microextraction (SPME) and gas chromatography can be successfully used both for establishing the qualitative composition of volatile organic compounds (VOC) emitted by leaf litter and for determining their emission rates. Taking as an example European larch litter, it is shown that dead plant material contains considerable amounts of volatile components as well as non-volatile compounds that can be VOC precursors formed as a result of enzymatic reactions. It is proposed to include the determination of extractable compounds into the methodology of studying litter as a source of atmospheric VOC. Some data on litter mass are reported and it is concluded that this data may be included into special models for emission evaluation. In this work the distribution coefficients of monoterpene hydrocarbons between the gas phase and polydimethylsiloxane fiber coating necessary for quantitative determinations in SPME were estimated.  相似文献   

Light propagation in a universe with spatial inhomogeneities     

Victor?LamburtEmail author  Dmitry?Sokoloff  Valery?Tutubalin 《Astrophysics and Space Science》2005,298(3):409-418

A light propagation in a universe which is homogeneous only in average systematically differs from a light propagation in a strictly homogeneous Universe. We demonstrate a link between this effect and the general theory of transport phenomenon in random media. The effective spatial curvature of a universe which is homogeneous only in average is introduced. This curvature is governing a light propagation in such universe. We show that the effective spatial curvature is lower than the average curvature. It implies that a universe with critical mean density looks like a space with negative curvature.  相似文献   

The relative importance of water and diet for uptake and subcellular distribution of cadmium in the deposit-feeding polychaete, Capitella sp. I     

Selck H  Forbes VE 《Marine environmental research》2004,57(4):261-279

The impact of dietary and water exposure on the accumulation and distribution of cadmium (Cd) in subcellular components of the polychaete Capitella sp. I was investigated. Worms were exposed to either dissolved Cd alone ('Water-Only' treatments; WO) or diet-bound Cd alone ('Algae-bound Only' treatments; AO). Thus, WO worms were starved and AO worms were fed. Differential centrifugation was used to fractionate worm homogenates into debris- (DE), mitochondrial- (MI), microsomal- (MC) and cytosolic- (CY) fractions, and the concentration of Cd in these fractions was quantified by radiometric analysis using the specific activity of the (109)Cd radioisotope. Neither exposure route nor Cd exposure affected the total protein content in the worms. However, fed, but not starved worms relocated proteins from the mitochondria to the cytosol in response to Cd exposure. In systems without Cd addition, starvation likewise influenced the distribution of protein between mitochondria and cytosol. Cutaneous uptake and accumulation of Cd from the water was related to surface area while dietary uptake was influenced by the amount of sediment passing through the gut. Irrespective of exposure route, Cd was accumulated primarily in the debris fraction although comparisons between the treatments indicated that relatively less Cd was located in DE and more in MI, MC and CY fractions in worms in AO compared to worms in WO. Cd per unit protein in DE and MI fractions was twice as high as in MC and CY fractions in WO, whereas MC contained the highest Cd content followed by MI, DE and CY fractions in AO worms. Our results stress the importance of exposure route for the internal distribution and toxicity of Cd to deposit feeders such as Capitella sp. I.  相似文献