Reply to the comment by Stephenson “Discussion of de Lange, W.P. and Moon, V.G. 2005. Estimating long-term cliff recession rates from shore platform widths. Engineering Geology 80, 292–301”     

Vicki Moon  Willem de Lange 《Engineering Geology》2008,101(3-4):292-294

  相似文献   

THERIA_G: a software program to numerically model prograde garnet growth   总被引：6，自引：4，他引：2  

F. Gaidies  C. de Capitani  R. Abart 《Contributions to Mineralogy and Petrology》2008,155(5):657-671

We present the software program THERIA_G, which allows for numerical simulation of garnet growth in a given volume of rock along any pressure–temperature–time (P–T–t) path. THERIA_G assumes thermodynamic equilibrium between the garnet rim and the rock matrix during growth and accounts for component fractionation associated with garnet formation as well as for intracrystalline diffusion within garnet. In addition, THERIA_G keeps track of changes in the equilibrium phase relations, which occur during garnet growth along the specified P–T–t trajectory. This is accomplished by the combination of two major modules: a Gibbs free energy minimization routine is used to calculate equilibrium phase relations including the volume and composition of successive garnet growth increments as P and T and the effective bulk rock composition change. With the second module intragranular multi-component diffusion is modelled for spherical garnet geometry. THERIA_G allows to simulate the formation of an entire garnet population, the nucleation and growth history of which is specified via the garnet crystal size frequency distribution. Garnet growth simulations with THERIA_G produce compositional profiles for the garnet porphyroblasts of each size class of a population and full information on equilibrium phase assemblages for any point along the specified P–T–t trajectory. The results of garnet growth simulation can be used to infer the P–T–t path of metamorphism from the chemical zoning of garnet porphyroblasts. With a hypothetical example of garnet growth in a pelitic rock we demonstrate that it is essential for the interpretation of the chemical zoning of garnet to account for the combined effects of the thermodynamic conditions of garnet growth, the nucleation history and intracrystalline diffusion. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.

F. GaidiesEmail:

  相似文献   

A transdisciplinary analysis of water problems in the mountainous karst areas of Morocco     

C. de Jong  S. Cappy  M. Finckh  D. Funk 《Engineering Geology》2008,99(3-4):228

Water management and engineering in the karstic High Atlas of Morocco are difficult tasks under the prevailing geological, hydrogeological, geomorphological, vegetational and climatic conditions. It is important to be able to understand and predict the characteristics and availability of water for future water planning in the region under changing climatic and agricultural conditions. An interdisciplinary analysis of problems and adequate hydrological modelling tools developed by geologists, hydrologists and biologists are necessary. The karst areas of the High Atlas Mountains are characterised by impermeable triassic basalt underlying substantial subsurface reservoirs with high potential discharge rates. The karst groundwater aquifers are extensive but largely unknown in dimension, probably with a hierarchical network of groundwater flow paths. It is estimated that approximately 70% of the surface water is directly lost to groundwater. Steep landslide- and debris flow prone slopes exist next to coarse-grained, highly porous river beds. Infrequent, high intensity rainfall or snowmelt causes a particularly high flood risk to these karst areas. In addition, agriculture and land use changes have degraded the karst areas. The most important driving forces for degradation include permanent overgrazing even during droughts and the use of firewood by a continually growing population. Large scale degradation of vegetation has occurred in the oro-mediterranean (mountainous Mediterranean) zone, between 2600 and 3400 m which coincides with the most important zone for karstic groundwater creation. The combination of high amounts of groundwater flow and rapid surface flow due to sparse vegetation has increased the problems of flood flow.  相似文献   

Surface complexation effects on phosphate adsorption to ferric iron oxyhydroxides along pH and salinity gradients in estuaries and coastal aquifers   总被引：3，自引：0，他引：3  

Claudette Spiteri  Philippe Van Cappellen  Pierre Regnier 《Geochimica et cosmochimica acta》2008,72(14):3431-3445

Non-conservative behavior of dissolved inorganic phosphate (DIP) in estuaries is generally ascribed to desorption from iron and aluminum (hydr)oxides with increasing salinity. Here, we assess this hypothesis by simulating the reversible adsorption of phosphate onto a model oxide (goethite) along physico-chemical gradients representative of surface and subsurface estuaries. The simulations are carried out using a surface complexation model (SCM), which represents the main aqueous speciation and adsorption reactions of DIP, plus the ionic strength-dependent coulombic interactions in solution and at the mineral-solution interface. According to the model calculations, variations in pH and salinity alone are unlikely to explain the often reported production of DIP in surface estuaries. In particular, increased aqueous complexation of phosphate by Mg²⁺ and Ca²⁺ ions with increasing salinity is offset by the formation of ternary Mg-phosphate surface complexes and the drop in electrical potential at the mineral-water interface. However, when taking into account the downstream decrease in the abundance of sorption sites, the model correctly simulates the observed release of DIP in the Scheldt estuary. The sharp increase in pH accompanying the admixing of seawater to fresh groundwater should also cause desorption of phosphate from iron oxyhydroxides during seawater intrusion in coastal aquifers. As for surface estuaries, the model calculations indicate that significant DIP release additionally requires a reduction in the phosphate sorption site density. In anoxic aquifers, this can result from the supply of seawater sulfate and the subsequent reductive dissolution of iron oxyhydroxides coupled to microbial sulfate reduction.  相似文献   

Water and sanitation in the Buenos Aires metropolitan region: Fragmented markets, splintering effects?     

Sarah Botton  Bernard de Gouvello 《Geoforum》2008,39(6):1859-1870

This paper discusses the provision of water and sanitation services and the related urban impacts in Buenos Aires circa 2005. The first part of the paper focuses on the metropolitan region (BAMR) which is larger than the area served by the Aguas Argentinas S.A. (AASA) concession (i.e. the capital and its conurbano). It highlights a form of institutional fragmentation that is reflected in the diverse management practices of the numerous service providers and results in differentiated levels of and access to services. The paper discusses the technical, economic and regulatory factors that have historically resulted in this institutional fragmentation. The second part of the article focuses on AASA’s water concession agreement. It demonstrates that, although the agreement had an in-built splintering logic, its implementation led to a more “integrated approach” based on the “reality on the ground”. On the whole, the conclusion regarding the application of the splintering urbanism concept to Buenos Aires is a mixed one and depends on the scale of observation. Although at regional level (BAMR), a form of “institutional fragmentation” would appear to be obvious, it is the result of a long and complex historical process and, while recent neo-liberal reforms in service provisions have “cemented” this fragmentation, they did not actually cause it. If we take the AASA service area in isolation, the trend in the decade following the contracting out of the service has been one of improved service provision and access—although this was not achieved through increased integration of the supply system. Finally, in the case of the Buenos Aires metropolitan region, the splintering urbanism thesis defended by Marvin and Graham needs to be nuanced in several significant ways.  相似文献   

A consistent geochemical modelling approach for the leaching and reactive transport of major and trace elements in MSWI bottom ash     

Joris J. Dijkstra  Johannes C.L. Meeussen  Hans A. Van der Sloot  Rob N.J. Comans 《Applied Geochemistry》2008

  相似文献   

Leaching mechanisms of oxyanionic metalloid and metal species in alkaline solid wastes: A review     

Geert Cornelis  C. Anette Johnson  Tom Van Gerven  Carlo Vandecasteele 《Applied Geochemistry》2008

An overview is presented on possible mechanisms that control the leaching behaviour of the oxyanion forming elements As, Cr, Mo, Sb, Se, V and W in cementituous systems and alkaline solid wastes, such as municipal solid waste incinerator bottom ash, fly ash and air pollution control residues, coal fly ash and metallurgical slags. Although the leachability of these elements generally depends on their redox state, speciation measurements are not common. Therefore, experimental observations available in the literature are combined with a summary of the thermal behaviour of these elements to assess possible redox states in freshly produced alkaline wastes, given their origin at high temperature. Possible redox reactions occurring at room temperature, on the other hand, are reviewed because these may alter the initial redox state in alkaline wastes and their leachates. In many cases, precipitation of oxyanions as a pure metalate cannot provide a satisfactory explanation for their leaching behaviour. It is therefore highly likely that adsorption and solid solution formation with common minerals in alkaline waste and cement reduce the leachate concentration of oxyanions below pure-phase solubility.  相似文献   

Controlling geological and hydrogeological processes in an arsenic contaminated aquifer on the Red River flood plain,Vietnam   总被引：1，自引：0，他引：1  

Flemming Larsen  Nhan Quy Pham  Nhan Duc Dang  Dieke Postma  Søren Jessen  Viet Hung Pham  Thao Bach Nguyen  Huy Duc Trieu  Luu Thi Tran  Hoan Nguyen  Julie Chambon  Hoan Van Nguyen  Dang Hoang Ha  Nguyen Thi Hue  Mai Thanh Duc  Jens Christian Refsgaard 《Applied Geochemistry》2008

  相似文献   

Weed species diversity on arable land of the dryland areas of central Tanzania: impacts of continuous application of traditional tillage practices     

Riziki S. Shemdoe  Frank M. Mbago  Idris S. Kikula  Patrick L. Van Damme 《GeoJournal》2008,71(2-3):107-115

This paper presents findings from a study that assessed influence of continuous application of a particular traditional tillage practice on weed species richness, diversity and composition and identifies weed species with positive benefits to the communities in semi-arid areas of Mpwapwa district, central Tanzania. In this area farmers apply three different traditional tillage practices which are no-till (NT), shallow tillage (ST) and Ridging System (RT). A total of 36 farm fields were surveyed in 2006/2007 cropping season where 63 weed species from 26 families were identified. Analysis of variance indicated significant differences between practices (p < 0.05), with NT practice having highest weed species richness and diversity. Among the five more prevalent weed species appearing, Bidens lineariloba was observed to exist in all the three practices. Community representatives during focus group discussions indicated 9 weed species out of 63 identified to have beneficial uses. These species are Cleome hirta, Amaranthus graecizans, Bidens lineoriloba, Bidens pilosa, Dactyloctenium aegyptium, Launaea cornuta, Heteropogon contortus, Tragus berteronianus and Trichodesma zeylanicum. Their main uses include leaf-vegetable, medicines, fodder and materials for thatching. From this study NT has highest weed species richness and diversity which therefore suggests that much more time is needed for weeding in this practice compared to other practice which was the farmers’ concern. It was also noted that although weed species have negative effects in crop production and production costs, they still play a vital role in food security and for the health of different people in marginal areas as well as for the complete ecosystem including micro and macrofauna.  相似文献   

Flexural isostatic response of the Alps to increased Quaternary erosion recorded by foreland basin remnants,SE France     

Jean‐Daniel Champagnac  Peter Van Der Beek  Gaël Diraison  Samuel Dauphin 《地学学报》2008,20(3):213-220

We test the hypothesis that flexural isostatic compensation of the mass removed by enhanced Quaternary erosion is responsible for uplift of the Western European Alps and their forelands. We use two well‐preserved and well‐dated (1.8 Ma) abandonment surfaces of foreland basin remnants in SE France (the Chambaran and Valensole plateaux) as passive benchmarks for tilting of the foreland. Estimating their initial slope from morphometric scaling relationships, we determine bulk post‐depositional tilting of 0.5–0.8% for these surfaces. The calculated isostatic response of the Alpine lithosphere to erosional unloading, using the method recently proposed by Champagnac et al. [Geology 35 (2007) 195–198] , yields a predicted tilting of 0.3–0.4% in the considered areas, explaining approximately half of the determined post‐depositional tilting. Such long‐term deformation being insensitive to cyclic loading/unloading because of glaciations, we suspect the other half to be related to as yet undetermined long‐wavelength and long‐lived tectonic process(es).  相似文献