Equilibrium constants of triethanolamine in major seawater salts     

I. Brandariz  P. Castro  M. Montes  F. Penedo  M.E. Sastre de Vicente 《Marine Chemistry》2006,102(3-4):291-299

Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl₂ or CaCl₂), with binary mixtures of MgCl₂ and CaCl₂, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl₂, while it is increased by the other electrolytes used in this work.  相似文献   

United Nations global conference on the sustainable development of Small Island Developing States     

Charlotte de Fontaubert 《Ocean & Coastal Management》1994,24(3)

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Upper temperature tolerances of exotic brackish-water mussel, Mytilopsis leucophaeata (Conrad): an experimental study   总被引：1，自引：0，他引：1  

Rajagopal S  Van der Gaag M  Van der Velde G  Jenner HA 《Marine environmental research》2005,60(4):512-530

The dark false mussel, Mytilopsis leucophaeata is an important mussel colonising the brackish-water systems of temperate and subtropical regions. Of late it has earned notoriety as a biofouling species in industrial cooling water systems. However, there are no published data on the temperature tolerance of this species. This paper presents data on the upper temperature tolerance of this mussel from the view point of biofouling control using thermal methods. In addition to mortality, response of physiological activities such as oxygen consumption, filtration rate, foot activity and byssus thread production were also studied at temperatures varying from 5 to 35 degrees C. Experiments were also carried out to understand the effect of mussel size, breeding condition, nutritional status and acclimation conditions (temperature and salinity) on the mortality pattern. The physiological activities were significantly reduced at temperatures beyond 27.5 degrees C and ceased at 35 degrees C. In 20 mm size group mussels exposed to 37 degrees C, 50% mortality was observed after 85 min and 100% mortality after 113 min. The effect of mussel size on mortality at different temperatures was significant, with the larger size group mussels showing greater resistance. M. leucophaeata collected during the non-breeding season (December-April) were more tolerant to temperature than those collected during the breeding season (June-October). Nutritional status of the mussel had no significant influence on the thermal tolerance of the mussel: fed and starved (non-fed) mussels succumbed to temperature at comparable rates. The effect of acclimation temperature and acclimation salinity on M. leucophaeata mortality at different temperatures was significant. Survival time increased with increasing acclimation temperature and decreased with increasing salinity. In comparison with other co-occurring species such as Mytilus edulis and Dreissena polymorpha, M. leucophaeata appears to be more tolerant to high temperature stress.  相似文献   

Zooplankton variability and climatic anomalies from 1994 to 2001 in the Balearic Sea (Western Mediterranean)     

Fernandez de Puelles  M. Luz; Valencia  Joaquin; Vicente  Laura 《ICES Journal of Marine Science》2004,61(4):492-500

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Pathways of clay mineral transport in the coastal zone of the Brazilian continental shelf from Ceará to the mouth of the Amazon River     

J. O. de Morais  M. Tintelnot  G. Irion  L. Souza Pinheiro 《Geo-Marine Letters》2006,26(1):16-22

The transport pathways of fine sediments (fraction <2 μm) along the Brazilian continental shelf from Ceará to the Amazon River mouth were studied by means of clay mineral analyses. On the continental shelf southeast of the Amazon mouth, fluctuations in clay mineral compositions reflect simple mixing between the suspended load of the North Brazil Current and sediment from several smaller rivers. Previously, clay mineral variations west of the Amazon mouth have been explained by variable settling velocities of different grain-size classes within the <2 μm fraction or by selective coagulation of individual clay mineral groups. By contrast, our experiments with river bank samples show that selective coagulation does not occur in Amazon River sediments. A more appropriate explanation for observed variations in clay mineral composition off the Amazon mouth seems to be, similarly to that for the shelf between Ceará and the Amazon mouth, a mixing of Amazon sediments with suspended material of the North Brazil Current. This interpretation is supported by data on clay mineral composition east and south of the Amazon mouth, showing more affinity to sediments of the North Brazil Current than to the suspended load of the Amazon River. Additionally, relatively low sedimentation rates and low concentrations of fine-grained sediments on the shelf suggest that high riverine input by the Amazon River does not overprint the sediments of the North Brazil Current in this region. The strong North Brazil Current shunts the Amazon suspended load in a north-westerly direction along the north-eastern coast of South America. Hence, stronger sedimentation of Amazon sediments would occur only west of the river mouth.  相似文献   

Nutrient budgets and trophic state in a hypersaline coastal lagoon: Lagoa de Araruama, Brazil     

Marcelo F. L. Souza  Bjrn Kjerfve  Bastiaan Knoppers  Weber F. Landim de Souza  Raimundo N. Damasceno 《Estuarine, Coastal and Shelf Science》2003,57(5-6):843-858

Lagoa de Araruama in the state of Rio de Janeiro, Brazil, is a hypersaline lagoon with salinity varying spatially from 45 to 56. We collected water samples during monthly cruises throughout the lagoon, and along the streams feeding the system, from April 1991 to March 1992. Nutrients and other water quality parameters exhibited great spatial and temporal variations. Mass balance calculations indicate large amounts of anthropogenic nutrient inputs. The data indicate that the lagoon currently is oligotrophic but is in a state of transition to become a mesotrophic system. Molar dissolved inorganic nitrogen:dissolved inorganic phosphorus (DIN/DIP) varied between 2.2:1 and 659:1 with a volume-weighted average of 22:1. The high DIN/DIP ratio contrasts with that found in nearby lagoons, suggesting that phytoplankton primary production is limited by phosphorus in Lagoa de Araruama. The major loss of DIP is apparently driven by biological assimilation and diagenic reactions in the sediments. Calculations indicate that the lagoon is slightly net autotrophic at +0.9 mol C m⁻² yr⁻¹. This suggests that the biomass of the primary producers is restricted by phosphorus availability. Phosphorus retention in the sediment and the hypersaline state of the lagoon prevent changes in autotrophic communities and the formation of eutrophic conditions.  相似文献   

Correlative changes in metabolism and DNA damage in turbot (Scophthalmus maximus) exposed to benzo[a]pyrene     

Telli-Karakoç F  Ruddock PJ  Bird DJ  Hewer A  Van Schanke A  Phillips DH  Peters LD 《Marine environmental research》2002,54(3-5):511-515

Juvenile turbot (Scophthalmus maximus) were injected intraperitoneally with either corn oil or 5 mg/kg benzo[a]pyrene (BaP) dissolved in corn oil and sampled I and 3 days after injection. After 1 day, no elevation of 7-ethoxyresorufin O-deethylase (EROD) activity was observed, however bile metabolites (BaP-7,8 dihydrodiol representing 70% of the total metabolites) and a single hepatic DNA adduct spot (0.47 adducts/10(8) nucleotides) identified by 32P-postlabelling were formed. No BaP metabolites or DNA adducts were observed in either control or carrier control fish. Fish sampled after 3 days reported 5-fold higher (P < 0.05) levels of EROD activity, a shift in the bile metabolite profile towards BaP phenol formation (1OH and 30H BaP comprising up to 60% of total metabolites detected) and the formation of two adduct spots (0.86 and 0.71 adducts/10(8) nucleotides). These results show that BaP can be metabolised and form hydrophobic DNA adducts in turbot without EROD elevation. Following EROD elevation, a shift in the profile of both BaP metabolites and BaP metabolite-DNA interactions occurs indicative of other oxidative processes.  相似文献   

Size of flatfish larvae at transformation, functional demands and historical constraints     

J. W. M. Osse  J. G. M. Van den Boogaart 《Journal of Sea Research》1997,37(3-4)

At hatching the larvae of flatfish closely resemble the bilateral symmetric larvae of other teleosts, especially perciforms. Literature data show that transformation to asymmetric benthic juveniles normally occurs at body lengths between 10 and 25 mm. Unexpectedly, minimal size at its completion (including eye migration) can be 4.1 mm SL and maximal size is over 72 mm. In this paper we consider the functional requirements for a successful switch from a symmetric pelagic larva to a typical asymmetric juvenile benthic flatfish partly based on evidence from other teleosts. The unfavourable period of eye migration and transition to a benthic habitat requires some food reserves and rewiring and/or recalibration of vision and gravity-associated structures utilised previously by the still symmetric larvae for e.g. food detection. Binocular fixation of the prey probably occurs in that stage. Critical or sensitive periods occurring during development of fish larvae suggest that a completely functional symmetric stage of development must precede transformation. The normal size range in flatfish larvae at transformation seems to confirm our considerations. Recent data on temperature effects during development provide an explanation for metamorphosis at the minimal size. Some evidence for paedomorphic heterochrony in flatfish larvae is presented.  相似文献   

A device to extract energy from water waves     

A.J. Hermans  E. Van Sabben  J.A. Pinkster 《Applied Ocean Research》1990,12(4):175-179

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A correcting “prism” for underwater viewpoints     

W.J. Van Sciver 《Ocean Engineering》1973,2(5):223-229

The angular field observable in water by an observer in air depends on the configuration of the air-water interface. When the interface is a plane, the absolute limit to observable field is about from the normal to the interface. A practical limit, because of lateral chromatic aberration is considerably less, approximately 30°. A conventionally used configuration in research submersibles, is a polymethyl methacrylate port with inner and outer surfaces parallel. This has the same optical limitations as the plane air-water interface. It is shown that if the inner and outer surfaces are not required to be parallel to each other, there are solutions which permit extending the observable field to nearly a full hemisphere with acceptably small distortion and lateral chromatic aberration.  相似文献