X-ray absorption fine structure study of As(V) and Se(IV) sorption complexes on hydrous Mn oxides     

Andrea L. Foster  Gordon E. Brown Jr.  George A. Parks 《Geochimica et cosmochimica acta》2003,67(11):1937-1953

X-ray absorption fine structure (XAFS) spectroscopic analysis at the As, Se, and Mn K-edges was used to study arsenate [As(V)O₄³⁻] and selenite [Se(IV)O₃²⁻] sorption complexes on the synthetic hydrous manganese oxides (HMOs) vernadite (δ-MnO₂) and K-birnessite (nominal composition: K₄Mn₁₄O₂₇ · 9H₂O). No significant changes were observed in sorption complex structure as a function of sorbent, pH (5 to 8), surface coverage (0.04 to 0.73 μmol/m²), or reaction time (5 to 22 h) in the arsenate or selenite systems. In the arsenate/HMO system, extended XAFS parameters indicate an average second-neighbor As(V) coordination of 2.0 ± 0.4 Mn at an average distance of 3.16 ± 0.01 Å, which is consistent with formation of As(V)O₄ sorption complexes sharing corners with two adjacent Mn(IV)O₆ surface species (i.e., bidentate, binuclear). In the selenite/HMO system, selenite surface complexes are surrounded by two shells of Mn atoms, which could represent two different adsorption complexes or a precipitate. The first shell consists of 1.6 ± 0.4 Mn at 3.07 ± 0.01 Å, which is consistent with the selenite anion forming bidentate (mononuclear) edge-sharing complexes with Mn(II)O₆ or Mn(III)O₆ octahedra. The second shell consists of 1.4 ± 0.4 Mn at 3.49 ± 0.03 Å, consistent with selenite forming monodentate, corner-sharing complexes with Mn(II)O₆ or Mn(III)O₆ octahedra. Pauling bond valence analysis that uses the extended XAFS-derived bond lengths for As(V)-O, Se(IV)-O, and Mn-O bonds indicates that the proposed surface complexes of selenite and arsenate on HMOs should be stable. Although a nearly identical Se(IV) coordination environment is found in a crystalline Mn(II)-Se(IV) precipitate (which has a structure similar to that of MnSeO₃ · H₂O), there are significant differences in the X-ray absorption near-edge structure and extended XAFS spectra of this precipitate and the selenite/HMO sorption samples. These differences coupled with transmission electron microscopy results suggest that if a precipitate is present it lacks long-range order characteristic of crystalline MnSeO₃ · H₂O.  相似文献   

Clinoform quantification for assessing the effects of external forcing on continental margin development     

Vanessa Kertznus  Ben Kneller 《Basin Research》2009,21(5):738-758

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Relationship between geoacoustic properties and chemical content of submarine polymetallic crusts from offshore Brazil     

Arthur Ayres Neto  Vanessa Alves da Costa  Clara Pinto Ferreira Maia Porto  Thais Cristina Vargas Garrido  Jean-Pierre Hermand 《Marine Georesources & Geotechnology》2020,38(4):437-449

Abstract

Marine mining is the ocean’s new exploration frontier, and polymetallic crusts (PMCs) and ferromanganese nodules are considered a strategic resource for the future. Acoustic geophysical methods are a valuable tool for oceanic research and have been employed for several decades in the exploration of marine resources and environmental evaluations. The main objective of this work was to investigate the correlation between the chemical composition of PMCs from three different areas along the Brazilian continental margin and their physico-acoustic attributes (P-wave velocity, density and acoustic impedance). The results show that the geoacoustic properties of PMCs are correlated to their chemical composition. Measurements showed positive and negative trends between acoustic impedance and studied elements (Fe, Mn, Co, Cu, Zn, W and Ni) according to the direction of measurement, indicting high anisotropy levels. Our study sheds initial light on the correlation between acoustic properties and metal content of PMCs. The study facilitates assessments of the acoustic responses of PMCs allowing more efficient prospection and exploitation compared to ship-board geophysical techniques that are too qualitative to identify PMCs. The results can contribute to determining the best procedures and techniques for more efficient future exploration of this resource.  相似文献   

Leachate Geochemistry at a Municipal Landfill, Memphis, Tennessee   总被引：2，自引：0，他引：2  

June E. Mirecki  William S. Parks 《Ground water》1994,32(3):390-398

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The Schlömilch matrix in wave power theory—Facts and conjectures     

Patrick C. Parks 《Applied Ocean Research》1983,5(1):45-48

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On the timing and causes of illite formation and remagnetization in the Cretaceous Marias River Shale, Disturbed Belt, Montana     

W. Crawford Elliott  Stephen G. Osborn  Vanessa J. O'Brien  R. Douglas Elmore  Michael H. Engel  J. Marion Wampler   《Journal of Geochemical Exploration》2006,89(1-3):92

In this study, we test a burial model for diagenetic illite and whether illitization is related to the acquisition of a chemical remanent magnetization (CRM). A prefolding, reversed polarity, secondary magnetization is found in carbonate concretions in diagenetically altered Upper Cretaceous rocks in the disturbed belt of Montana. Stratigraphically equivalent unaltered rocks to the east do not contain the magnetization. The magnetization could be a CRM or a thermoviscous remagnetization. The pole position is generally consistent with the Early Tertiary K–Ar ages of diagenetic illite–smectite formed under thrust loading, but it is not constrained well enough for a precise age comparison. If this magnetization is a CRM, it could be related to illitization. Alternatively, if the prefolding CRM had been acquired prior to thrust loading then the magnetization is not related to illitization. Geochemical studies are currently underway to test if the magnetization could be related to fluid alteration.  相似文献   

Effective dispersion in a chemically heterogeneous medium under temporally fluctuating flow conditions     

Vanessa Zavala-Sanchez  Marco Dentz  Xavier Sanchez-Vila 《Advances in water resources》2007

We investigate effective solute transport in a chemically heterogeneous medium subject to temporal fluctuations of the flow conditions. Focusing on spatial variations in the equilibrium adsorption properties, the corresponding fluctuating retardation factor is modeled as a stationary random space function. The temporal variability of the flow is represented by a stationary temporal random process. Solute spreading is quantified by effective dispersion coefficients, which are derived from the ensemble average of the second centered moments of the normalized solute distribution in a single disorder realization. Using first-order expansions in the variances of the respective random fields, we derive explicit compact expressions for the time behavior of the disorder induced contributions to the effective dispersion coefficients. Focusing on the contributions due to chemical heterogeneity and temporal fluctuations, we find enhanced transverse spreading characterized by a transverse effective dispersion coefficient that, in contrast to transport in steady flow fields, evolves to a disorder-induced macroscopic value (i.e., independent of local dispersion). At the same time, the asymptotic longitudinal dispersion coefficient can decrease. Under certain conditions the contribution to the longitudinal effective dispersion coefficient shows superdiffusive behavior, similar to that observed for transport in s stratified porous medium, before it decreases to its asymptotic value. The presented compact and easy to use expressions for the longitudinal and transverse effective dispersion coefficients can be used for the quantification of effective spreading and mixing in the context of the groundwater remediation based on hydraulic manipulation and for the effective modeling of reactive transport in heterogeneous media in general.  相似文献   

Characterization of a landslide-triggered debris flow at a rainforest-covered mountain region in Brazil     

Cabral  Victor Carvalho  Reis  Fábio Augusto Gomes Vieira  D’Affonseca  Fernando Mazo  Lucía  Ana  dos Santos Corrêa  Claudia Vanessa  Veloso  Vinicius  Gramani  Marcelo Fischer  Ogura  Agostinho Tadashi  Lazaretti  Andrea Fregolente  Vemado  Felipe  Pereira Filho  Augusto José  dos Santos  Claudia Cristina  Lopes  Eymar Silva Sampaio  Rabaco  Lis Maria Reoni  do Carmo Giordano  Lucilia  Zarfl  Christiane 《Natural Hazards》2021,108(3):3021-3043

Natural Hazards - Debris flows represent great hazard to humans due to their high destructive power. Understanding their hydrogeomorphic dynamics is fundamental in hazard assessment studies,...  相似文献   

A qualitative risk assessment for the impacts of climate change on nationally and internationally important geoheritage sites in Scotland     

Rachel M.L. Wignall  John E. Gordon  Vanessa Brazier  Colin C.J. MacFadyen  Nick S. Everett 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):120-134

Climate change is a significant concern for nature conservation in the 21?st century. One of the goals of the 2014 Scottish Climate Change Adaptation Programme is to identify the consequences of climate change for protected areas and to put in place adaptation or mitigation measures. As a contribution to the process, this paper develops a methodology to identify the relative level of risk to nationally and internationally important geological and geomorphological sites in Scotland from the impacts of climate change. The methodology is based on existing understanding of the likely responses of different types of geosite to specific aspects of climate change, such as changes in rainfall, rising sea levels or increased storminess, and is applied to assess the likelihood of damaging impacts on groups of similar geoheritage features in sites with similar characteristics. The results indicate that 80 (8.8%) of the ～900 nationally and internationally important geoheritage sites in Scotland are at ‘high’ risk from climate change. These include active soft-sediment coastal and fluvial features, finite Quaternary sediment exposures and landforms in coastal and river locations, active periglacial features, sites with palaeoenvironmental records, finite or restricted rock exposures and fossils. Using this risk-based assessment, development of indicative geoheritage climate-change actions have been prioritised for these sites. Depending on the characteristics of the sites, management options may range from ‘do nothing’ to rescue excavations and posterity recording. Monitoring is an essential part of the management process to trigger evidence-based interventions.  相似文献   

Review of tufa deposition and palaeohydrological conditions in the White Peak,Derbyshire, UK: implications for Quaternary landscape evolution     

Vanessa J. Banks  Peter F. Jones  David J. Lowe  Jonathan R. Lee  Jeremy Rushton  Michael A. Ellis 《Proceedings of the Geologists' Association. Geologists' Association》2012,123(1):117-129

This review considers the geological and geomorphological context of tufa barrages that occupy buried valley settings in the Wye catchment, Derbyshire. It describes the potential relationship of the tufa with locations of hypothesised river captures and inception horizon-guided groundwater flow paths. Tufa barrage development is associated with steps in the bedrock, which may be related to knick-point recession during river capture. Broad estimates of valley incision have been calculated from previously dated deposits. These support current interpretations of particularly significant effective base-level lowering during the Anglian and Devensian stages of the Quaternary and have the potential to add to the knowledge of regional uplift histories.  相似文献