Headwaters drive streamflow and lowland tracer export in a large-scale humid tropical catchment     

Christian Birkel  Alicia Correa-Barahona  Marco Martinez-Martinez  Sebastian Granados-Bolaños  Nelson Venegas-Cordero  Kenneth Gutiérrez-García  Sara Blanco-Ramírez  Rafael Quesada-Mora  Vanessa Solano-Rivera  Jasson Mussio-Mora  Andres Chavarría-Palma  Katherine Vargas-Arias  Georgianne W. Moore  Ana Maria Durán-Quesada  Javier Vasquez-Morera  Chris Soulsby  Dörthe Tetzlaff  Edgar Espinoza-Cisneros  Ricardo Sánchez-Murillo 《水文研究》2020,34(18):3824-3841

Headwaters are generally assumed to contribute the majority of water to downstream users, but how much water, of what quality and where it is generated are rarely known in the humid tropics. Here, using monthly monitoring in the data scarce (2,370 km²) San Carlos catchment in northeastern Costa Rica, we determined runoff-area relationships linked to geochemical and isotope tracers. We established 46 monitoring sites covering the full range of climatic, land use and geological gradients in the catchment. Regression and cluster analysis revealed unique spatial patterns and hydrologically functional landscape units. These units were used for seasonal and annual Bayesian tracer mixing models to assess spatial water source contributions to the outlet. Generally, the Bayesian mixing analysis showed that the chemical and isotopic imprint at the outlet is throughout the year dominated by the adjacent lowland catchments (68%) with much less tracer influence from the headwaters. However, the headwater catchments contributed the bulk of water and tracers to the outlet during the dry season (>50%) despite covering less than half of the total catchment area. Additionally, flow volumes seemed to be linearly scaled by area maintaining a link between the headwaters and the outlet particularly during high flows of the rainy season. Stable isotopes indicated mean recharge elevations above the mean catchment altitude, which further supports that headwaters were the primary source of downstream water. Our spatially detailed “snap-shot” sampling enabled a viable alternative source of large-scale hydrological process knowledge in the humid tropics with limited data availability.  相似文献   

Assessment and control of organic and other contaminants associated with the Stardust sample return from comet 81P/Wild 2     

Scott A. SANDFORD  Saša BAJT  Simon J. CLEMETT  George D. CODY  George COOPER  Bradley T. DEGREGORIO  Vanessa De VERA  Jason P. DWORKIN  Jamie E. ELSILA  George J. FLYNN  Daniel P. GLAVIN  Antonio LANZIROTTI  Thomas LIMERO  Mildred P. MARTIN  Christopher J. SNEAD  Maegan K. SPENCER  Thomas STEPHAN  Andrew WESTPHAL  Sue WIRICK  Richard N. ZARE  Michael E. ZOLENSKY 《Meteoritics & planetary science》2010,45(3):406-433

Abstract– Numerous potential sources of organic contaminants could have greatly complicated the interpretation of the organic portions of the samples returned from comet 81P/Wild 2 by the Stardust spacecraft. Measures were taken to control and assess potential organic (and other) contaminants during the design, construction, and flight of the spacecraft, and during and after recovery of the sample return capsule. Studies of controls and the returned samples suggest that many of these potential sources did not contribute any significant material to the collectors. In particular, contamination from soils at the recovery site and materials associated with the ablation of the heatshield do not appear to be significant problems. The largest source of concern is associated with the C present in the original aerogel. The relative abundance of this carbon can vary between aerogel tiles and even within individual tiles. This C was fortunately not distributed among a complex mixture of organics, but was instead largely present in a few simple forms (mostly as Si‐CH₃ groups). In most cases, the signature of returned cometary organics can be readily distinguished from contaminants through their different compositions, nonterrestrial isotopic ratios, and/or association with other cometary materials. However, some conversion of the carbon indigenous to the flight aerogel appears to have happened during particle impact, and some open issues remain regarding how this C may be processed into new forms during the hypervelocity impact collection of the comet dust.  相似文献   

Prediction of the long-term performance of abandoned lead zinc mine tailings in a Welsh catchment     

Barbara Palumbo-Roe  Ben Klinck  Vanessa Banks  San Quigley 《Journal of Geochemical Exploration》2009,100(2-3):169-181

In this study we investigated the sulphidic mine tailings from Frongoch and Grogwynion, two abandoned lead zinc mines in mid-Wales, UK. Despite falling within the same ore field the mine waste characterisation has identified differences in the tailings from the two sites. Bulk concentrations range from 10 to 52 g kg^− 1 for Pb, 1.1 to 2.9 g kg^− 1 for Zn in Grogwynion and from 1.0 to 130 g kg^− 1 for Pb, 11 to 110 g kg^− 1 for Zn in Frongoch. An experimental (European standard leaching tests TS 14429 and TS 14405) and geochemical modelling approach was used to study the leaching composition as a function of pH and liquid/solid ratio. There was little correlation between the tailings bulk metal concentrations and the leachate composition, but variations in Pb and Zn concentrations were found to be consistent with control of dissolved Pb and Zn by secondary minerals and the mechanisms of dissolution/precipitation/sorption involving them. Specifically, the Grogwynion mine tailings with near-neutral pH have predominantly lead and zinc carbonates controlling Pb and Zn solubility in the leachates, whereas the Pb and Zn concentrations in Frongoch leachates are best modelled with a surface complexation model for metal sorption to oxyhydroxides. The different speciation results in a greater sensitivity of Grogwynion tailings to acidification with a potential release of Pb in solution up to 10 times higher than in Frongoch, despite similar bulk Pb concentrations. At acid pH, Zn is similarly dissolved to a greater extent in Grogwynion than in Frongoch tailings. There was no evidence of sulphide oxidation during the batch and column leaching tests and the suitability of using these European leaching standards for the characterisation of sulphidic mine waste materials for waste management purposes has been considered.  相似文献   

Evaluation of stable iodine status of the areas affected by the Chernobyl accident in an epidemiological study in Belarus and the Russian Federation     

Elena Korobova  Yadviga Anoshko  Ausrele Kesminiene  Aleksander Kouvyline  Sergei Romanov  Vanessa Tenet  Eero Suonio  Elisabeth Cardis 《Journal of Geochemical Exploration》2010

Variation of the stable iodine supply was evaluated in the soils of around more than 700 settlements in the regions (oblasts) of Belarus and the Russian Federation contaminated after the Chernobyl accident. It involved the use of regional information on iodine content in different types of soil cover, biogeochemical criteria of iodine deficiency in food chains, and the available soil maps.  相似文献   

Shellfish from Todos os Santos Bay, Bahia, Brazil: treat or threat?     

de Souza MM  Windmöller CC  Hatje V 《Marine pollution bulletin》2011,62(10):2254-2263

This study determined the concentrations of major and trace elements in shellfish (oysters, clams and mussels) and conducted an assessment of the health risks due to the consumption of contaminated seafood. Samples were collected at 34 sites along Todos os Santos Bay, Brazil. The elements were determined by ICP OES and Hg by Direct Mercury Analysis. Relatively high concentrations of trace elements (As, Zn, Se and Cu) were found in seafood tissues. Potential daily intake of As, Co, Se, Zn and Cu associated to shellfish consumption suggested relevant non-carcinogenic risk for all studied locations. Copper was the element that posed the greatest non-carcinogenic risk, while Pb posed the highest carcinogenic risk. Health risks for humans were greatest from the consumption of mussels. Contaminated shellfish offer the greatest risk for children, subsistence fishers and subsistence shellfish consumers.  相似文献   

Unsupervised fuzzy classification and object-based image analysis of multibeam data to map deep water substrates, Cook Strait, New Zealand   总被引：1，自引：0，他引：1  

Vanessa Lucieer  Geoffroy Lamarche 《Continental Shelf Research》2011,31(11):1236-1247

A comprehensive 32 kHz multibeam bathymetry and backscatter survey of Cook Strait, New Zealand (∼8500 km²), is used to generate a regional substrate classification map over a wide range of water depths, seafloor substrates and geological landforms using an automated mapping method based on the textural image analysis of backscatter data. Full processing of the backscatter is required in order to obtain an image with a strongly attenuated specular reflection. Image segmentation of the merged backscatter and bathymetry layers is constrained using shape, compactness, and texture measures. The number of classes and their spatial distribution are statistically identified by employing an unsupervised fuzzy-c-means (FCM) clustering algorithm to sediment samples, independent of the backscatter data. Classification is achieved from the overlay of the FCM result onto a segmented image and attributing segments with the FCM class. Four classes are identified and uncertainty in class attribution is quantified by a confusion index layer. Validation of the classification map is done by comparing the results with the sediment and structural maps. Backscatter (BS) strength angular profiles are used to show acoustic class separation. The method takes us one step further in combining multibeam data with physical seabed data in a complementary analysis to seek correlations between datasets using object-based image analysis and unsupervised classification. Texture within these identified classes is then examined for correlation with typical backscatter angular responses for mud, sand and gravel. The results show a first order correlation between each of the classes and both the sedimentary properties and the geomorphological map.  相似文献   

The Witputs diamictite in southern Namibia and associated rocks: constraints for a global glaciation?     

Udo Zimmermann  Jennifer Tait  Quentin G. Crowley  Vanessa Pashley  Gijs Straathof 《International Journal of Earth Sciences》2011,100(2-3):511-526

The Witputs section of the Gariep Belt (S Namibia) comprises a sequence of clastic and chemical sediments, which have been interpreted as representative of a Late Neoproterozoic global or near-global ice age event, and recent biostratigraphic work in the upper rocks of the Witputs suggest a Late Ediacaran age. To further characterise this sequence and provide additional age constraints, a detailed sedimentological and detrital zircon study has been carried out. The petrographic, sedimentological and geochemical characteristics of the Witputs diamictite determined in this study are homogenous and indicative of debris flow or palaeo-valley infill sediments, deposited in an oxic environment with no glaciogenic evidence. This homogeneity is also reflected in the detrital zircon age spectra with most ages falling between 1.0 and 1.3?Ga, representing the local geology, with the youngest grain at 1030.2?±?10.9 (2??) (n?=?92?<10% discordance), despite the fact that mid and Late Neoproterozoic volcanic activity is known in the local region. The overlying carbonate rocks, often considered to be ??cap carbonates??, show high Mn (up to 60% MnO), with base metal precipitation (Zn, V, Co), and are recrystallised. Their ??¹³C_VPDB isotope ratios are homogeneous at around-3. Major and trace element ratios reach values which indicate that C?CO isotopes may be disturbed and might not reflect primary global seawater composition, thus questioning their use for global correlation and comparison with composite chemostratigraphic curves. The contact to the overlying Late Ediacaran Sanddrif Member is not exposed, and the rocks dip in a different direction than the underlying carbonate rocks. The c. 40-m-thick section is characterised by rapid lithology changes including shales, calcareous sandstones and wackes, fine-grained conglomerates and rare clean quartz-rich sandstones, all of which have strikingly similar detrital zircon populations, and the youngest zircon is dated at 1082.8?±?10?Ma (2?? errors, from 72 grains with <10% discordance). Acritarchs earlier found in the Sanddrif Member, however, indicate a post-570?Ma depositional age. If the diamictites are glacio-marine deposits, then an interesting conclusion is that the clastic sediments can display a very immature geochemical signature, indicating a localised provenance, with derivation purely from the local basement rocks, which is also reflected in the detrital zircon populations. However, we would hesitate to assign a glacial origin to the deposits as no glacial indicators, other than a diamictitic texture, were observed. Clearly, far more work on the detailed mapping and sedimentology of the Neoproterozoic Gariep Belt deposits is required, particularly as many are currently used for global correlation. Age constraints derived from extensive detrital zircon work can only constrain the deposits as being post 1.03?Ma with the detritus being purely locally derived.  相似文献   

Rainfall-related debris flows in Carhuacocha Valley, Cordillera Huayhuash, Peru     

Zbyn��k Engel  Julius ?es��k  Vanessa Rios Escobar 《Landslides》2011,8(3):269-278

Continuous heavy rainfall hit northern Peru in the second half of the 2008/2009 summer season. From the end of January to the beginning of March, the Cordillera Huayhuash experienced abnormally high precipitations that exceeded 270?mm. The antecedent rainfall, aggravated with a severe rainstorm of 20?mm on March 7 triggered a large debris flow in the upper Carhuacocha Valley early in the morning on March 8. The debris flow interrupted drainage from the upper part of the valley damming a lake in the narrow depression between the trough slope and the lateral moraine. As a result of the drainage interruption, water percolated through the moraine dam of Cangrajanca Lake where a secondary mass movement occurred in its inner slope. In September 2009, we mapped the debris flow and related landforms and estimated the total area and volume of both mass movements using geodetic measurements. About 104,000?m³ of sediments was moved from the trough slope towards the moraine from which 534,000?m³ flowed to Cangrajanca Lake subsequently. We analysed the rainfall conditions that triggered the debris flow using rainfall data from the nearby stations. We also compared the precipitation preceding the event with the rainfall thresholds for debris flow initiation.  相似文献   

Choosing Between Two Kind of Sampling Patterns Using Geostatistical Simulation: Regularly Spaced or at High Uncertainty Locations?     

Vanessa Cerqueira Koppe  João Felipe Coimbra Leite Costa  Rodrigo de Lemos Peroni  Jair Carlos Koppe 《Natural Resources Research》2011,20(2):131-142

Data from a mineral deposit are commonly obtained by core drilling. This kind of sampling involves high costs, limiting the number of drill holes. Additional holes should be located to bring the maximum benefit. The benefit can be evaluated by various ways and must take into account the goals of sampling. This article presents a case study where the deposit has been sampled and the new drillings must be added to reduce the uncertainty about a transfer function, Net Present Value (NPV) of the mining project. There are basically two ways to choose locations where new drillings should be placed for cases where the aim of sampling is to reduce uncertainty about a global function: the addition of new drillings outlining a quasi regular grid with previously collected drillings or the addition of new drillings on the locations of high uncertainty about the attribute of interest (or the attribute that is considered most influential in the transfer function). The performances of these patterns on reducing the uncertainty measured by the function selected are compared. The results point out that the most efficient pattern relates to the distribution (histogram) of the uncertainty about the attribute of interest. Thus, the choice of which sampling pattern should be adopted varies depending on data distribution and its influence on the transfer function.  相似文献   

Hägerstrand meets big data: time-geography in the age of mobility analytics     

Brum-Bastos  Vanessa  Páez  Antonio 《Journal of Geographical Systems》2023,25(3):327-336

Journal of Geographical Systems -  相似文献