Pb-Pb age of sedimentary phosphorite reworking in Lower Riphean carbonate sediments,the Satka Formation of Southern Urals     

G. V. Ovchinnikova  A. B. Kuznetsov  I. M. Vasil’eva  I. M. Gorokhov  M. T. Krupenin  A. V. Maslov  T. L. Turchenko 《Stratigraphy and Geological Correlation》2008,16(2):138-142

The mineral composition and U-Pb and Rb-Sr systematics of phosphorites from the Satka Formation of Lower Riphean carbonates, the Burzyan Group of Southern Urals, are studied. Phosphorites occurring as small lenses between stromatolite layers are composed largely of fluorapatite with admixture of detrital quartz, feldspars, illite, and chlorite. Phosphorite samples have been subjected to stepwise dissolution in 1 N (fraction L-1) and 2 N (fraction L-2) HCl. As is established, the maximum apatite content is characteristic of fraction L-1, while fraction L-2 is enriched in products of dolomite and sulfide dissolution and in elements leached from siliciclastic components. The Sr content in the Satka apatites (280–560 ppm) is substantially lower as compared with that in unaltered marine apatite. The ⁸⁷Sr/⁸⁶Sr “initial ratio in the phosphorites studied (0.71705–0.72484) and host dolomites from the lower part of the Satka Formation is significantly higher than in the Early Riphean seawater that indicates a reset of the Rb-Sr original systems in sediments. The Pb-Pb age of 1340 ± 30 Ma (MSWD = 6.4) estimated based on 7 data points characterizing fractions L-1 and L-2 is younger than the formation time of overlying Burzyan sediments, being consistent, within the error range, with date of the Mashak rifting event recorded at the Early-Middle Riphean boundary. The comparative U-Pb characteristics of two soluble fractions (L-1 and L-2) and silicate residue of phosphorites show that epigenetic redistribution of Pb and U was characteristic of the phosphorite horizon only. The initial Pb isotope composition and μ (²³⁸U/²⁰⁴Pb) estimated according to model by Stacey and Kramers for the early diagenetic fluids in carbonate and phosphate sediments of the Satka Formation suggest that they were in isotopic equilibrium with erosion products of the Taratash crystalline complex.  相似文献   

Planktonic foraminifers in the southern Bering Sea: Changes in composition and productivity during the Late Pleistocene-Holocene     

M. P. Chekhovskaya  I. A. Basov  A. G. Matul  T. A. Khusid  S. A. Gorbarenko 《Stratigraphy and Geological Correlation》2008,16(3):328-342

Taxonomic composition and distribution of planktonic foraminifers are studied in section of Core GC-11 that penetrated through Upper Quaternary sediments of the Bowers Ridge western slope, the southern Bering Sea. As is shown, structure of foraminiferal assemblage and productivity have varied substantially during the last 32000 calendar years in response to changes in surface water temperatures and water mass circulation in the northern part of the Pacific, the Bering Sea included. The productivity was maximal during deglaciation epoch, being notably lower in the Holocene and minimal at the glaciation time.  相似文献   

The hydrochemistry of a semi-arid pan basin case study: Sua Pan,Makgadikgadi, Botswana     

Frank D. Eckardt  Robert G. Bryant  Graham McCulloch  Baruch Spiro  Warren W. Wood 《Applied Geochemistry》2008

This study presents results on the fluid and salt chemistry for the Makgadikgadi, a substantial continental basin in the semi-arid Kalahari. The aims of the study are to improve understanding of the hydrology of such a system and to identify the sources of the solutes and the controls on their cycling within pans. Sampling took place against the backdrop of unusually severe flooding as well as significant anthropogenic extraction of subsurface brines. This paper examines in particular the relationship between the chemistry of soil leachates, fresh stream water, salty lake water, surface salts and subsurface brines at Sua Pan, Botswana with the aim of improving the understanding of the system’s hydrology. Occasionally during the short wet season (December–March) surface water enters the saline environment and precipitates mostly calcite and halite, as well as dolomite and traces of other salts associated with the desiccation of the lake. The hypersaline subsurface brine (up to TDS 190,000 mg/L) is homogenous with minor variations due to pumping by BotAsh mine (Botswana Ash (Pty) Ltd.), which extracts 2400 m³ of brine/h from a depth of 38 m. Notable is the decrease in TDS as the pumping rate increases which may be indicative of subsurface recharge by less saline water. Isotope chemistry for Sr (⁸⁷Sr/⁸⁶Sr average 0.722087) and S (δ³⁴S average 34.35) suggests subsurface brines have been subject to a lithological contribution of undetermined origin. Recharge of the subsurface brine from surface water including the Nata River appears to be negligible.  相似文献   

National-scale estimation of potentially harmful element ambient background concentrations in topsoil using parent material classified soil:stream–sediment relationships     

J.D. Appleton  B.G. Rawlins  I. Thornton 《Applied Geochemistry》2008

Regulatory authorities require estimates of ambient background concentrations (ABCs) of potentially harmful elements (PHEs) in topsoil; such data are currently not available in many countries. High resolution soil geochemical data exist for only part of England and Wales, whilst stream sediment data cover the entire landscape. A novel methodology is presented for estimating soil equivalent ABCs for PHEs from high-resolution (HR) stream sediment geochemical data grouped by common parent materials (PM), using arsenic (As) as an example. Geometric mean (GM) values for local PM groups are used to investigate different approaches for transforming sediment to soil equivalent concentrations. Holdout validation is used to assess: (i) the optimum number of samples for calculating local GM values, and (ii) the optimum scale at which to group data when using linear regression analysis to estimate GM soil ABCs from local sediment geochemical values. Holdout validation showed that the smallest differences were generally observed when five observations were used to calculate the GM and that these should be grouped over the smallest possible area in order to encompass soils over PMs with elevated GM As concentrations. Geometric mean ABCs are estimated and mapped for As in mineral soil across all of England and Wales within delineations of PM polygons. Errors for the estimation of soil equivalent GM As ABCs based on sediment data for an independent validation set were of a similar magnitude to those from holdout validation applied to the original data suggesting the approach is robust. The estimates of soil equivalent ABCs suggest that As exceeds the regulatory threshold used in risk assessments for residential land use (20 mg kg⁻¹) across 16% of the landscape of England and Wales. The applicability of the method for cognate landscapes, and potential refinements is discussed.  相似文献   

Calibration of regional palaeohydrogeology and sensitivity analysis using hydrochemistry data in site investigations     

F.M.I. Hunter  L.J. Hartley  A. Hoch  C.P. Jackson  R. McCarthy  N. Marsic  B. Gylling 《Applied Geochemistry》2008

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Integration and magnitude homogenization of the Egyptian earthquake catalogue   总被引：2，自引：0，他引：2  

H. M. Hussein  K. M. Abou Elenean  I. A. Marzouk  A. Peresan  I. M. Korrat  E. Abu El-Nader  G. F. Panza  M. N. El-Gabry 《Natural Hazards》2008,47(3):525-546

The aim of the present work is to compile and update a catalogue of the instrumentally recorded earthquakes in Egypt, with uniform and homogeneous source parameters as required for the analysis of seismicity and seismic hazard assessment. This in turn requires a detailed analysis and comparison of the properties of different available sources, including the distribution of events with time, the magnitude completeness, and the scaling relations between different kinds of magnitude reported by different agencies. The observational data cover the time interval 1900–2004 and an area between 22°–33.5° N and 25°–36° E. The linear regressions between various magnitude types have been evaluated for different magnitude ranges. Using the best linear relationship determined for each available pair of magnitudes, as well as those identified between the magnitudes and the seismic moment, we convert the different magnitude types into moment magnitudes M _W, through a multi-step conversion process. Analysis of the catalogue completeness, based on the M _W thus estimated, allows us to identify two different time intervals with homogeneous properties. The first one (1900–1984) appears to be complete for M _W ≥ 4.5, while the second one (1985–2004) can be considered complete for magnitudes M _W ≥ 3.  相似文献   

A new occurrence of sapphirine-bearing granulite from Podur, Andhra Pradesh, India     

I. N. Sharma  D. Prakash 《Mineralogy and Petrology》2008,92(3-4):415-425

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Society news     

Dr. I. Sunagawa 《Mineralium Deposita》1969,4(4):418-418

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The Origin of Associated Basic and Acid Rocks in the Lebombo--Nuanetsi Igneous Province, Southern Africa, as implied by Strontium Isotopes     

MANTON  W. I. 《Journal of Petrology》1968,9(1):23-39

Whole rock Rb–Sr measurements were made on associatedbasic and acid intrusives and extrusives from the northern andsouthern ends of the Lebombo monocline with a view to determineif the acid rocks came from the mantle or from the crust. Inthe south, in Swaziland (now called Ngwame) and Zululand, rhyolitesand granophyres (age 202 14 m.y.) have an initial Si⁸⁷–Sr⁸⁶ratio of 0.7042 0.0005; in the north, in the Nuanetsi syncline,rhyolites (age 206 13 m.y.) and granites from ring complexes(age 177 7 m.y.) have initial ratios of 0.7081 0.0008 and0.7085 0.0007, respectively. The initial ratios of the basicrocks, basalts and gabbros, vary in both areas and have a rangefrom 0.7042 to 0.7125 which can be explained by crustal contamination.The low initial ratios and isotopic homogeneity of the acidmagmas over long distances (160 km) in Swaziland and Zululandare interpreted as implying that they were derived from themantle.  相似文献   

Filter apparatus for studying the sun's short-wave emission     

A.I. Efremov  A.L. Podmoshenskii  M.A. Ivanov  V.N. Nikiforov  O.N. Efimov 《Planetary and Space Science》1962,9(12):987-992

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