Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

The effects of topographically-controlled thermal tides in the martian upper atmosphere as seen by the MGS accelerometer     

Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32

Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献   

试论新世纪地理信息科学的发展   总被引：1，自引：0，他引：1  

黄雪樵  陈昱 《地球信息科学学报》2002,4(2):32-37

本文重点分析了当前国内外地理信息科学的形成与发展趋势和地理信息科学不断发展的历程 ,提出近期发展的前沿 ,以及当前地理信息产业化面临的一些重要问题。最后提出对地理信息科学发展的意见。  相似文献   

Radial velocity searches for other planetary systems:Current status and future prospects     

W. D. Cochran  A. P. Hatzes 《Astrophysics and Space Science》1996,241(1):43-60

Measurement of variations in the radial velocities of stars due to the reflex orbital motion of the star around the planetary-system barycenter constitutes a powerful method of searching for substellar or planetary mass companions. After several years of patient data acquisition, radial-velocity searches for planetary systems around other stars are now beginning to bear fruit. In late 1995 and early 1996, three candidate systems were announced with Jovian-mass planets around solar-type stars. The current paradigm for low-mass star formation suggests that planetary systems should be able to form in the circumstellar disks surrounding young stellar objects. These newly discovered systems, and other discoveries which will soon follow them, will test critically our understanding of the processes of star- and planet-formation. We review the techniques used in these radial-velocity searches and their results to date. We then discuss planned improvements in the surveys, and the prospects for the next 20 years.  相似文献   

AN ILLUSTRATIVE STUDY ON LOCAL LANDSCAPEAND ITS LONG-TERM CHANGES BASED ON IKONOS AND HISTORICAL AERIAL PHOTO   总被引：2，自引：0，他引：2  

RUANRen-zong ErieCELLISt 《中国地理科学(英文版)》2004,14(2):162-169

Nowadays, the research works on landscape at fine scales using high-resolution images are uncommon.This research is based on the analysis of the combination of remote sensing data (1KONOS imagery acquired in 2002 and historical aerial photo taken in 1942). In the paper, the ecotopes in Qiujiadou and Xishao villages in Yixing City of Jiangsu Province in 1942 and 2002 were compared and landscape changes as well as the causes of the considerable changes were analyzed. It was found that the ecotope changes were at greater level in some aspects such as water surface and perennial vegetation coverage etc. This study at fine scale is globally significant for the rural areas, especially for the subsistence agricultural land, which occupies larger percentage in the earth. And it analyzes the structure of landscape based on a new landscape classification system--stratifications method.  相似文献   

Palaeointensity In the Pelagic Realm: Marine Sediment Data Compared With Archaeomagnetic and Lake Sediment Records     

C. G. Constable  L. Tauxe† 《Geophysical Journal International》1987,90(1):43-59

Summary. Four box cores collected from the Ontong—Java plateau during the Eurydice expedition have been used to make relative geomagnetic palaeo-intensity measurements. Rock magnetic measurements on the sediments show that they are characterized by a uniform magnetic mineralogy, and that they are suitable for relative intensity estimates. These are obtained by normalizing the NRM by an ARM imparted in a low DC bias field. the palaeoceanographic event known as the preservation spike is used to establish a crude time-scale for the record so that it may be compared with other data from the same region, and also with global palaeointensity estimates. the marine sediment data are quite similar to Australian intensity data from lake sediments and archaeomagnetic sources, but as might be expected exhibit some obvious differences from the global record.  相似文献   

Identifying young gamma-ray burst fossils     

Enrico Ramirez-Ruiz † 《Monthly notices of the Royal Astronomical Society》2004,349(3):L38-L42

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Pulsar Wind Nebulae in Egret Error Boxes     

Mallory S. E. Roberts  Crystal L. Brogan  Bryan M. Gaensler  Jason W. T. Hessels  C.-Y. Ng  Roger W. Romani 《Astrophysics and Space Science》2005,297(1-4):93-100

A remarkable number of pulsar wind nebulae (PWN) are coincident with EGRET γ-ray sources. X-ray and radio imaging studies of unidentified EGRET sources have resulted in the discovery of at least six new pulsar wind nebulae (PWN). Stationary PWN (SPWN) appear to be associated with steady EGRET sources with hard spectra, typical for γ-ray pulsars. Their toroidal morphologies can help determine the geometry of the pulsar which is useful for constraining models of pulsed γ-ray emission. Rapidly moving PWN (RPWN) with more cometary morphologies seem to be associated with variable EGRET sources in regions where the ambient medium is dense compared to what is typical for the ISM.  相似文献   

Self-regulated black hole accretion, the M–σ relation and the growth of bulges in galaxies     

Mitchell C. Begelman †  Biman B. Nath ‡ 《Monthly notices of the Royal Astronomical Society》2005,361(4):1387-1392

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The monopole moment of the three-point correlation function of the two-degree Field Galaxy Redshift Survey     

Jun Pan  István Szapudi 《Monthly notices of the Royal Astronomical Society》2005,362(4):1363-1370

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